scholarly journals Pinpoint Loading Examinations of Poly(lactic acid) Biopolymers

2018 ◽  
Vol 11 (4) ◽  
pp. 206-217
Author(s):  
Luca Kotrocz ◽  
Péter Bakonyi
Keyword(s):  
Lactic Acid ◽  
Dynamic Mechanical Analysis ◽  
Room Temperature ◽  
Mechanical Analysis ◽  
Poly Lactic Acid ◽  
Hardness Tests ◽  
Wide Range ◽  
Short And Long Term ◽  
Long Term Behavior

We have made a new mounting unit for Dynamic Mechanical Analysis (DMA) equipment, suitable for measuring microhardness and indentation, and examined its usability on thermoplastic poly(lactic acid) (PLA) material.  We used a Vickers-type microhardness indenter, and examined the dimensions of the indented area and the loading force. This novel unit is suitable for measuring the short and long-term behavior of the material using pinpoint load not only at room temperature (20-23 °C) – like common hardness tests – but at a wide range of temperatures.

Long-term behavior of epoxy/graphene-based composites determined by dynamic mechanical analysis

2015 ◽  
Vol 50 (19) ◽  
pp. 6407-6419 ◽  
Author(s):  
Luís C. O. Silva ◽  
Glaura G. Silva ◽  
Pulickel M. Ajayan ◽  
Bluma G. Soares
Keyword(s):  
Dynamic Mechanical Analysis ◽  
Mechanical Analysis ◽  
Dynamic Mechanical ◽  
Long Term Behavior

scholarly journals Behavioral medicine challenges in the shadow of a global pandemic

2020 ◽  
Author(s):  
Alyssa T Brooks ◽  
Hannah K Allen ◽  
Louise Thornton ◽  
Tracy Trevorrow
Keyword(s):  
Environmental Factors ◽  
Health Behavior ◽  
Health Behaviors ◽  
Natural Experiment ◽  
Direct Effects ◽  
Global Pandemic ◽  
Wide Range ◽  
Future Data ◽  
Short And Long Term

Abstract Health behavior researchers should refocus and retool as it becomes increasingly clear that the challenges of the COVID-19 pandemic surpass the direct effects of COVID-19 and include unique, drastic, and ubiquitous consequences for health behavior. The circumstances of the pandemic have created a natural experiment, allowing researchers focusing on a wide range of health behaviors and populations with the opportunity to use previously collected and future data to study: (a) changes in health behavior prepandemic and postpandemic, (b) health behavior prevalence and needs amidst the pandemic, and (c) the effects of the pandemic on short- and long-term health behavior. Our field is particularly challenged as we attempt to consider biopsychosocial, political, and environmental factors that affect health and health behavior. These realities, while daunting, should call us to action to refocus and retool our research, prevention, and intervention efforts

scholarly journals Relationship between the Stereocomplex Crystallization Behavior and Mechanical Properties of PLLA/PDLA Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1851
Author(s):  
Hye-Seon Park ◽  
Chang-Kook Hong
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Crystallization Behavior ◽  
Mechanical Analysis ◽  
X Ray Diffraction ◽  
Nucleation Agent ◽  
Scanning Calorimetry ◽  
Nucleation Sites ◽  
Wide Range ◽  
Degree Of Crystallization

Poly (l-lactic acid) (PLLA) is a promising biomedical polymer material with a wide range of applications. The diverse enantiomeric forms of PLLA provide great opportunities for thermal and mechanical enhancement through stereocomplex formation. The addition of poly (d-lactic acid) (PDLA) as a nucleation agent and the formation of stereocomplex crystallization (SC) have been proven to be an effective method to improve the crystallization and mechanical properties of the PLLA. In this study, PLLA was blended with different amounts of PDLA through a melt blending process and their properties were calculated. The effect of the PDLA on the crystallization behavior, thermal, and mechanical properties of PLLA were investigated systematically by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), polarized optical microscopy (POM), dynamic mechanical analysis (DMA), and tensile test. Based on our findings, SC formed easily when PDLA content was increased, and acts as nucleation sites. Both SC and homo crystals (HC) were observed in the PLLA/PDLA blends. As the content of PDLA increased, the degree of crystallization increased, and the mechanical strength also increased.

scholarly journals Synthesis and Characterization of Polyphosphazenes Modified with Hydroxyethyl Methacrylate and Lactic Acid

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Evelyn Carolina Martínez Ceballos ◽  
Ricardo Vera Graziano ◽  
Gonzalo Martínez Barrera ◽  
Oscar Olea Mejía
Keyword(s):  
Lactic Acid ◽  
Ring Opening ◽  
Room Temperature ◽  
Block Structure ◽  
Ring Opening Polymerization ◽  
Synthesis And Characterization ◽  
Poly Lactic Acid ◽  
Hydroxyethyl Methacrylate ◽  
H Nmr

Poly(dichlorophosphazene) was prepared by melt ring-opening polymerization of the hexachlorocyclotriphosphazene. Poly[bis(2-hydroxyethyl-methacrylate)-phosphazene] and poly[(2-hydroxyethyl-methacrylate)-graft-poly(lactic-acid)-phosphazene] were obtained by nucleophilic condensation reactions at different concentrations of the substituents. The properties of the synthesized copolymers were assessed by FTIR,1H-NMR and31P-NMR, thermal analysis (DSC-TGA), and electron microscopy (SEM). The copolymers have a block structure and show twoTg's below room temperature. They are stable up to a temperature of 100°C. The type of the substituents attached to the PZ backbone determines the morphology of the polymers.

Editorial

2009 ◽  
Vol 11 (1) ◽  
pp. 1-14 ◽  
Author(s):  
Manasi Kumar ◽  
Erica Burman
Keyword(s):  
Millennium Development Goals ◽  
Health Management ◽  
The Political ◽  
Special Issue ◽  
Wide Range ◽  
Critical Approaches ◽  
Development Goals ◽  
Short And Long Term ◽  
Primary Focus

We welcome readers to the first special issue (11.1) of the Journal of Health Management. We hope the readers find the articles and various reviews enriching and provocative, both in terms of the range of ideas and critical approaches addressed. The key theme of this double issue concerns the political limits of mega-development projects such as the Millennium Development Goals (MDGs). The primary focus of the articles collected here is to provide an insightful, constructive and in-depth critique of the United Nations (UN) MDGs along with critical deliberations on their short- and long-term implications not only for health management but also for a wide range of issues around development and social change.

Engineering microenvironment of biodegradable polyester systems for drug stability and release control

2021 ◽  
Author(s):  
Nisar Ul Khaliq ◽  
Dhawal Chobisa ◽  
Coralie A Richard ◽  
Monica R Swinney ◽  
Yoon Yeo
Keyword(s):  
Lactic Acid ◽  
Glycolic Acid ◽  
Release Kinetics ◽  
Drug Stability ◽  
Poly Lactic Acid ◽  
Polymeric Systems ◽  
Us Fda ◽  
History Of Use ◽  
Release Control

Polymeric systems made of poly(lactic acid) or poly(lactic-co-glycolic acid) are widely used for long-term delivery of small and large molecules. The advantages of poly(lactic acid)/poly(lactic-co-glycolic acid) systems include biodegradability, safety and a long history of use in US FDA-approved products. However, as drugs delivered by the polymeric systems and their applications become more diverse, the significance of microenvironment change of degrading systems on long-term drug stability and release kinetics has gained renewed attention. In this review, we discuss various issues experienced with acidifying microenvironment of biodegradable polymer systems and approaches to overcome the detrimental effects of polymer degradation on drug stability and release control.

scholarly journals Morphology, Thermal, Mechanical Properties and Rheological Behavior of Biodegradable Poly(butylene succinate)/poly(lactic acid) In-Situ Submicrofibrillar Composites

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2422 ◽  
Author(s):  
Zhiwen Zhu ◽  
Hezhi He ◽  
Bin Xue ◽  
Zhiming Zhan ◽  
Guozhen Wang ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Cold Drawing ◽  
Mechanical Analysis ◽  
Poly Lactic Acid ◽  
Fiber Morphology ◽  
Molding Process ◽  
Butylene Succinate ◽  
Low Frequencies ◽  
Biodegradable Poly

In this study, biodegradable poly(butylene succinate)/poly(lactic acid) (PBS/PLA) in-situ submicrofibrillar composites with various PLA content were successfully produced by a triple-screw extruder followed by a hot stretching−cold drawing−compression molding process. This study aimed to investigate the effects of dispersed PLA submicro-fibrils on the thermal, mechanical and rheological properties of PBS/PLA composites. Morphological observations demonstrated that the PLA phases are fibrillated to submicro-fibrils in the PBS/PLA composites, and all the PLA submicro-fibrils produced seem to have a uniform diameter of about 200nm. As rheological measurements revealed, at low frequencies, the storage modulus (G’) of PBS/PLA composites has been increased by more than four orders of magnitude with the inclusion of high concentrations (15 wt % and 20 wt %) of PLA submicro-fibrils, which indicates a significant improvement in the elastic responses of PBS melt. Dynamic Mechanical Analysis (DMA) results showed that the glass transition temperature (Tg) of PBS phase slightly shifted to the higher temperature after the inclusion of PLA. DSC experiments proved that fiber morphology of PLA has obvious heterogeneous nucleation effect on the crystallization of PBS. The tensile properties of the PBS/PLA in-situ submicrofibrillar composites are also improved compared to neat PBS.

scholarly journals Ubiquitous C IV 1550 Variability in B and Be Stars

1987 ◽  
Vol 92 ◽  
pp. 286-288 ◽  
Author(s):  
G. Sonneborn ◽  
M.P. Garhart ◽  
C.A. Grady
Keyword(s):  
Time Scale ◽  
High Dispersion ◽  
Be Stars ◽  
Line Profiles ◽  
Standard Star ◽  
B Stars ◽  
Short And Long Term ◽  
Resonance Transitions ◽  
Long Term Behavior

Studies of line profile variability of the ultraviolet 1550 Angstrom resonance transitions of C IV in Be stars (Sonneborn et al. 1986; Grady, et al. 1986a,b) have prompted an investigation into the short- and long-term behavior of the C IV lines in other types of B stars. We present examples of two well-studied Be stars, Omega Orionis and 66 Ophiuchi, and two non-Be stars, Beta Cephei and the standard star Zeta Cassiopeiae. Zeta Cas is also known to be a 53 Per variable (see Cox 1983). The IUE SWP high-dispersion spectra of Beta Cep and Zeta Cas have been obtained from the IUE archives. It has been known for some years that the C IV line profiles in Beta Cep vary in a time scale of several days (Fishel and Sparks, 1980). However, it came as a surprise to discover C IV variability in Zeta Cas. Available data allow us to set an upper limit of several months for the time scale of Zeta Cas C IV variability. The principal difference between the C IV variability in Be and non-Be stars appears to be the magnitude and velocity range of the effect.

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