Design strategies for oxy-combustion power plant captured CO2 purification

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ikenna J. Okeke ◽  
Tia Ghantous ◽  
Thomas A. Adams

Abstract This study presents a novel design and techno-economic analysis of processes for the purification of captured CO2 from the flue gas of an oxy-combustion power plant fueled by petroleum coke. Four candidate process designs were analyzed in terms of GHG emissions, thermal efficiency, pipeline CO2 purity, CO2 capture rate, levelized costs of electricity, and cost of CO2 avoided. The candidates were a classic process with flue-gas water removal via condensation, flue-gas water removal via condensation followed by flue-gas oxygen removal through cryogenic distillation, flue-gas water removal followed by catalytic conversion of oxygen in the flue gas to water via reaction with hydrogen, and oxy-combustion in a slightly oxygen-deprived environment with flue-gas water removal and no need for flue gas oxygen removal. The former two were studied in prior works and the latter two concepts are new to this work. The eco-technoeconomic analysis results indicated trade-offs between the four options in terms of cost, efficiency, lifecycle greenhouse gas emissions, costs of CO2 avoided, technical readiness, and captured CO2 quality. The slightly oxygen-deprived process has the lowest costs of CO2 avoided, but requires tolerance of a small amount of H2, CO, and light hydrocarbons in the captured CO2 which may or may not be feasible depending on the CO2 end use. If infeasible, the catalytic de-oxygenation process is the next best choice. Overall, this work is the first study to perform eco-technoeconomic analyses of different techniques for O2 removal from CO2 captured from an oxy-combustion power plant.

2011 ◽  
Vol 133 (1) ◽  
Author(s):  
Jian Ma ◽  
Oliver Hemmers

The concept of cofiring (algal biomass burned together with coal or natural gas in existing utility power boilers) includes the utilization of CO2 from power plant for algal biomass culture and oxycombustion of using oxygen generated by biomass to enhance the combustion efficiency. As it reduces CO2 emission by recycling it and uses less fossil fuel, there are concomitant benefits of reduced greenhouse gas (GHG) emissions. The by-products (oxygen) of microalgal biomass can be mixed with air or recycled flue gas prior to combustion, which will have the benefits of lower nitrogen oxide concentration in flue gas, higher efficiency of combustion, and not too high temperature (avoided by available construction materials) resulting from coal combustion in pure oxygen. A technoeconomic analysis of microalgae cofiring process for fossil fuel-fired power plants is studied. A process with closed photobioreactor and artificial illumination is evaluated for microalgae cultivation, due to its simplicity with less influence from climate variations. The results from this process would contribute to further estimation of process performance and investment. Two case studies show that there are average savings about $0.264 million/MW/yr and $0.203 million/MW/yr for coal-fired and natural gas-fired power plants, respectively. These cost savings are economically attractive and demonstrate the promise of microalgae technology for reducing GHG emission from fossil fuel-fired power plants.


Atmosphere ◽  
2021 ◽  
Vol 12 (3) ◽  
pp. 324
Author(s):  
Joana Monjardino ◽  
Luís Dias ◽  
Patrícia Fortes ◽  
Hugo Tente ◽  
Francisco Ferreira ◽  
...  

Air pollution and climate change are closely interlinked, once both share common emission sources, which mainly arise from fuel combustion and industrial processes. Climate mitigation actions bring co-benefits on air quality and human health. However, specific solutions can provide negative trade-offs for one side. The Portuguese Carbon Neutrality Roadmap was developed to assess conceivable cost-effective pathways to achieve zero net carbon emissions by 2050. Assessing its impacts, on air pollutant emissions, is the main focus of the present work. The bottom-up linear optimization energy system the integrated MARKAL-EFOM system (TIMES) model was selected as a modeling tool for the decarbonization scenarios assessment. The estimation of air pollutant emissions was performed exogenously to the TIMES model. Results show that reaching net zero greenhouse gas (GHG) emissions is possible, and technologically feasible, in Portugal, by 2050. The crucial and most cost-effective vector for decarbonizing the national economy is the end-use energy consumption electrification, renewable based, across all end-use sectors. Decarbonization efforts were found to have strong co-benefits for reducing air pollutant emissions in Portugal. Transport and power generation are the sectors with the greatest potential to reduce GHG emissions, providing likewise the most significant reductions of air pollutant emissions. Despite the overall positive effects, there are antagonistic effects, such as the use of biomass, mainly in industry and residential sectors, which translates into increases in particulate matter emissions. This is relevant for medium term projections, since results show that, by 2030, PM2.5 emissions are unlikely to meet the emission reduction commitments set at the European level, if no additional control measures are considered.


2015 ◽  
Author(s):  
Jing Bian ◽  
Siyu Sun ◽  
Kun Xia ◽  
Liqiang Duan ◽  
Umberto Desideri ◽  
...  

In this paper the coal-fired power plant with CO2 capture by integrating MCFCs system and the integrated coal gasification with CO2 capture by integrating MCFCs combined cycle system are compared with each other in different ways. The effects of the key parameters of MCFC on the performance of two systems, such as CO2 utilization factor, fuel utilization factor and the current density of MCFC, have been analyzed and compared. Aspen Plus soft is used to develop the system models and the key parameters of MCFC are calculated, analyzed and optimized. The flue gas of the coal-fired power plant (CFPP) or the Integrated Gasification Combined Cycle (IGCC) system is used as the reactant gas of MCFC cathode side, reacting with fuel in the anode side and producing power. The anode exhaust gas burns with pure oxygen in the afterburner. The CO2 in the flue gas is further concentrated and captured with the lower energy consumption. The results show that, the efficiency of the coal-fired power plant integrating MCFCs system is about 45.75% when the CO2 capture rate is 88.07%, and the efficiency of the IGCC system integrating MCFCs is about 47.31% when the CO2 capture rate is 88.14%. Achievements in this paper will provide the valuable reference for CO2 capture of coal-fired power plant and IGCC with low energy penalty.


2021 ◽  
Vol 12 (3) ◽  
pp. 93
Author(s):  
Daniel Arturo Maciel Fuentes ◽  
Eduardo Gutiérrez González

In recent decades, urban air pollution has increased considerably in Mexico City, leading to harmful effects on the ecosystem. To reduce pollutant emissions, new sustainable technologies have been adopted in the transport sector. To date, no studies have conducted a technoeconomic analysis of the environmental impact of electric vehicles (EVs) in regard to taxis in Mexico. To address this gap in the research, this study aimed to perform a cost-environmental impact assessment of electric taxi introduction in Mexico City using the life-cycle cost (LCC) methodology and the greenhouse gas (GHG) emissions assessment. Furthermore, a sensitivity analysis was performed to identify parameters with the greatest influence on the LCC. The LCC of EVs was found to be larger than that of internal combustion vehicles (ICVs); the acquisition cost was identified as the greatest contributor to the total LCC, followed by the maintenance cost. Worldwide, mixed results have been reported due to differences in the use of local parameters and values. To promote EVs, it is necessary to reduce either acquisition costs or battery costs. The environmental analysis showed that there is only a slight reduction in GHG emissions with electric taxi introduction. Nevertheless, cleaner renewable energy sources must be adopted and considered in order to achieve a much greater reduction and take full advantage of the benefits of EVs.


ACS Omega ◽  
2020 ◽  
Vol 5 (50) ◽  
pp. 32551-32563
Author(s):  
Peiyuan Pan ◽  
Weijian Zhou ◽  
Heng Chen ◽  
Naiqiang Zhang
Keyword(s):  

Soil Research ◽  
2017 ◽  
Vol 55 (3) ◽  
pp. 201 ◽  
Author(s):  
A. R. Melland ◽  
D. L. Antille ◽  
Y. P. Dang

Occasional strategic tillage (ST) of long-term no-tillage (NT) soil to help control weeds may increase the risk of water, erosion and nutrient losses in runoff and of greenhouse gas (GHG) emissions compared with NT soil. The present study examined the short-term effect of ST on runoff and GHG emissions in NT soils under controlled-traffic farming regimes. A rainfall simulator was used to generate runoff from heavy rainfall (70mmh–1) on small plots of NT and ST on a Vertosol, Dermosol and Sodosol. Nitrous oxide (N2O), carbon dioxide (CO2) and methane (CH4) fluxes from the Vertosol and Sodosol were measured before and after the rain using passive chambers. On the Sodosol and Dermosol there was 30% and 70% more runoff, respectively, from ST plots than from NT plots, however, volumes were similar between tillage treatments on the Vertosol. Erosion was highest after ST on the Sodosol (8.3tha–1 suspended sediment) and there were no treatment differences on the other soils. Total nitrogen (N) loads in runoff followed a similar pattern, with 10.2kgha–1 in runoff from the ST treatment on the Sodosol. Total phosphorus loads were higher after ST than NT on both the Sodosol (3.1 and 0.9kgha–1, respectively) and the Dermosol (1.0 and 0.3kgha–1, respectively). Dissolved nutrient forms comprised less than 13% of total losses. Nitrous oxide emissions were low from both NT and ST in these low-input systems. However, ST decreased CH4 absorption from both soils and almost doubled CO2 emissions from the Sodosol. Strategic tillage may increase the susceptibility of Sodosols and Dermosols to water, sediment and nutrient losses in runoff after heavy rainfall. The trade-offs between weed control, erosion and GHG emissions should be considered as part of any tillage strategy.


Author(s):  
Akili D. Khawaji ◽  
Jong-Mihn Wie

The most popular method of controlling sulfur dioxide (SO2) emissions in a steam turbine power plant is a flue gas desulfurization (FGD) process that uses lime/limestone scrubbing. Another relatively newer FGD technology is to use seawater as a scrubbing medium to absorb SO2 by utilizing the alkalinity present in seawater. This seawater scrubbing FGD process is viable and attractive when a sufficient quantity of seawater is available as a spent cooling water within reasonable proximity to the FGD scrubber. In this process the SO2 gas in the flue gas is absorbed by seawater in an absorber and subsequently oxidized to sulfate by additional seawater. The benefits of the seawater FGD process over the lime/limestone process and other processes are; 1) The process does not require reagents for scrubbing as only seawater and air are needed, thereby reducing the plant operating cost significantly, and 2) No solid waste and sludge are generated, eliminating waste disposal, resulting in substantial cost savings and increasing plant operating reliability. This paper reviews the thermodynamic aspects of the SO2 and seawater system, basic process principles and chemistry, major unit operations consisting of absorption, oxidation and neutralization, plant operation and performance, cost estimates for a typical seawater FGD plant, and pertinent environmental issues and impacts. In addition, the paper presents the major design features of a seawater FGD scrubber for the 130 MW oil fired steam turbine power plant that is under construction in Madinat Yanbu Al-Sinaiyah, Saudi Arabia. The scrubber with the power plant designed for burning heavy fuel oil containing 4% sulfur by weight, is designed to reduce the SO2 level in flue gas to 425 ng/J from 1,957 ng/J.


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