The effect of extraction condition on gel spun super denier PVA fiber structure and properties

e-Polymers ◽  
2009 ◽  
Vol 9 (1) ◽  
Author(s):  
Xia Yumin ◽  
Wang Zhixin ◽  
Tang Huigong
Keyword(s):  
Mechanical Properties ◽  
Structure And Properties ◽  
Fiber Structure ◽  
Extraction Condition ◽  
Gel Spinning ◽  
Solvent Content ◽  
Optimum Parameters ◽  
Pva Fiber

AbstractThis paper is directed towards PVA monofilament with good mechanical properties and super denier, which was produced with the gel spinning technique, first used by K. YAMAURA, used to strengthen the concrete. The structure and properties of PVA fiber were affected especially by extraction conditions, including the temperature, the solvent content and the duration of the extraction, all of which were studied and the optimum parameters were selected.

Influence of Solvent Content on Properties of UHMWPA6 Fibers Prepared by Gel-Spinning Method

2014 ◽  
Vol 941-944 ◽  
pp. 1264-1268
Author(s):  
Hui Min Zhang ◽  
Li Zhang ◽  
Qing Xiu Jia
Keyword(s):  
Mechanical Property ◽  
Thermal Property ◽  
Relative Viscosity ◽  
Polyamide 6 ◽  
Structure And Properties ◽  
Fiber Structure ◽  
Gel Spinning ◽  
Solvent Content ◽  
Complex Agent ◽  
Influence Of Solvent

Polyamide 6 (PA6) gels were prepared by dissolving PA6 powder with relative viscosity 25.85 in formic acid using CaCl2 as complex agent. Concentration of the polymer was 18 (w/v) %. And then, polyamide 6 (PA6) fibers were obtained through gel-spinning. In this study, the effects of solvent content on fiber structure and properties were investigated. The results showed that with the increasing of solvent content, significant changes occurred in the crystalline structure and thermal property of fibers. The optimum solvent content of fibers with the highest mechanical property in this study was 9.4%.

The Application of New Type Melt-Spinning PVA Fiber in ECC

2014 ◽  
Vol 629-630 ◽  
pp. 435-442
Author(s):  
Zhi Qian Yang ◽  
De Gen Xu ◽  
Jian Zhong Liu ◽  
Lin Li ◽  
Hua Xin Zhou ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Strain Hardening ◽  
Melt Spinning ◽  
Large Diameter ◽  
Wet Spinning ◽  
Gel Spinning ◽  
Surface Sizing ◽  
New Type ◽  
Pva Fiber ◽  
Test Result

This article prepared a new type PVA fiber with large diameter by plasticizing melt spinning method, which instead of traditional wet-spinning or gel-spinning method. The mechanical properties and microstructure of fiber were characterized by tensile instrument respectively and SEM. Then, the PVA fiber was used in cementitious composites after surface sizing. The test result shown that: the melt-spinning PVA fiber could achieve stress-strain hardening in ECC system, and appeared multi-cracking phenomenon, the flexural deflection and strength is not worse than the Japan Kurary PVA fiber. Finally, the PVA has an advantage in price.

Structure and properties of compact articles from high-alloyed iron powder with adding of boron nitride

2020 ◽  
pp. 39-48
Author(s):  
B. O. Bolshakov ◽  
◽  
R. F. Galiakbarov ◽  
A. M. Smyslov ◽  
◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Boron Nitride ◽  
Grain Boundary ◽  
Bending Strength ◽  
Physical And Mechanical Properties ◽  
Operating Conditions ◽  
Structure And Properties ◽  
Steam Turbines ◽  
Friction Forces ◽  
Wide Range

The results of the research of structure and properties of a composite compact from 13 Cr – 2 Мо and BN powders depending on the concentration of boron nitride are provided. It is shown that adding boron nitride in an amount of more than 2% by weight of the charge mixture leads to the formation of extended grain boundary porosity and finely dispersed BN layers in the structure, which provides a high level of wearing properties of the material. The effect of boron nitride concentration on physical and mechanical properties is determined. It was found that the introduction of a small amount of BN (up to 2 % by weight) into the compacts leads to an increase in plasticity, bending strength, and toughness by reducing the friction forces between the metal powder particles during pressing and a more complete grain boundary diffusion process during sintering. The formation of a regulated structure-phase composition of powder compacts of 13 Cr – 2 Mо – BN when the content of boron nitride changes in them allows us to provide the specified physical and mechanical properties in a wide range. The obtained results of studies of the physical and mechanical characteristics of the developed material allow us to reasonably choose the necessary composition of the powder compact for sealing structures of the flow part of steam turbines, depending on their operating conditions.

scholarly journals Functional Bionanocomposite Fibers of Chitosan Filled with Cellulose Nanofibers Obtained by Gel Spinning

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1563
Author(s):  
Sofia Marquez-Bravo ◽  
Ingo Doench ◽  
Pamela Molina ◽  
Flor Estefany Bentley ◽  
Arnaud Kamdem Tamo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Cellulose Nanofibers ◽  
Microstructural Characterization ◽  
Fiber Formation ◽  
Fiber Direction ◽  
Composite Fibers ◽  
X Ray Diffraction ◽  
Gel Spinning ◽  
X Ray

Extremely high mechanical performance spun bionanocomposite fibers of chitosan (CHI), and cellulose nanofibers (CNFs) were successfully achieved by gel spinning of CHI aqueous viscous formulations filled with CNFs. The microstructural characterization of the fibers by X-ray diffraction revealed the crystallization of the CHI polymer chains into anhydrous chitosan allomorph. The spinning process combining acidic–basic–neutralization–stretching–drying steps allowed obtaining CHI/CNF composite fibers of high crystallinity, with enhanced effect at incorporating the CNFs. Chitosan crystallization seems to be promoted by the presence of cellulose nanofibers, serving as nucleation sites for the growing of CHI crystals. Moreover, the preferential orientation of both CNFs and CHI crystals along the spun fiber direction was revealed in the two-dimensional X-ray diffraction patterns. By increasing the CNF amount up to the optimum concentration of 0.4 wt % in the viscous CHI/CNF collodion, Young’s modulus of the spun fibers significantly increased up to 8 GPa. Similarly, the stress at break and the yield stress drastically increased from 115 to 163 MPa, and from 67 to 119 MPa, respectively, by adding only 0.4 wt % of CNFs into a collodion solution containing 4 wt % of chitosan. The toughness of the CHI-based fibers thereby increased from 5 to 9 MJ.m−3. For higher CNFs contents like 0.5 wt %, the high mechanical performance of the CHI/CNF composite fibers was still observed, but with a slight worsening of the mechanical parameters, which may be related to a minor disruption of the CHI matrix hydrogel network constituting the collodion and gel fiber, as precursor state for the dry fiber formation. Finally, the rheological behavior observed for the different CHI/CNF viscous collodions and the obtained structural, thermal and mechanical properties results revealed an optimum matrix/filler compatibility and interface when adding 0.4 wt % of nanofibrillated cellulose (CNF) into 4 wt % CHI formulations, yielding functional bionanocomposite fibers of outstanding mechanical properties.

scholarly journals Influence of Applied Bias Voltage on the Composition, Structure, and Properties of Ti:Si-Codoped a-C:H Films Prepared by Magnetron Sputtering

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Jinlong Jiang ◽  
Qiong Wang ◽  
Yubao Wang ◽  
Zhang Xia ◽  
Hua Yang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Surface Roughness ◽  
Magnetron Sputtering ◽  
Bias Voltage ◽  
Tribological Properties ◽  
Structure And Properties ◽  
Applied Bias ◽  
Applied Bias Voltage ◽  
Methane Mixture ◽  
Composition Structure

The titanium- and silicon-codoped a-C:H films were prepared at different applied bias voltage by magnetron sputtering TiSi target in argon and methane mixture atmosphere. The influence of the applied bias voltage on the composition, surface morphology, structure, and mechanical properties of the films was investigated by XPS, AFM, Raman, FTIR spectroscopy, and nanoindenter. The tribological properties of the films were characterized on an UMT-2MT tribometer. The results demonstrated that the film became smoother and denser with increasing the applied bias voltage up to −200 V, whereas surface roughness increased due to the enhancement of ion bombardment as the applied bias voltage further increased. The sp3carbon fraction in the films monotonously decreased with increasing the applied bias voltage. The film exhibited moderate hardness and the superior tribological properties at the applied bias voltage of −100 V. The tribological behaviors are correlated to the H/E or H3/E2ratio of the films.

Properties of Flame-Retardant Cellulose Fibers Prepared from Cellulose[Amim]Cl Dope Solution

2011 ◽  
Vol 236-238 ◽  
pp. 1152-1155
Author(s):  
Lei Gao ◽  
Bo Wen Cheng ◽  
Jun Song ◽  
Zeng Geng Guo ◽  
Fei Lu ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Flame Retardants ◽  
Simultaneous Thermal Analysis ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Structure And Properties ◽  
Fiber Structure ◽  
Fiber Degradation ◽  
Dope Solution ◽  
Flame Retardant Properties

This paper has studied the structure and flame-retardant properties of flame-retardant cellulose fiber with DDPSN as flame retardant. The flame retardants was uniformly dispersed in the cellulose /[Amim]Cl Solution to obtain the good spinnable dope, then the dope was wet-spun. Effects of the flame-retardant contention the fiber structure and properties were investigated. The surface of the flame-retardant cellulose fiber was observed using field emission scanning electron microscope (FESEM). Besides, through the Simultaneous thermal analysis, it has been shown that, with the increase of fame retardant, the degree of fame resistance was obviously improved. The flame retardant acted greatly in condensed phase during the fiber degradation and remained mainly in residues after degradation, the experiments show that the flame-retardant properties of flame-retardant cellulose fiber with 20wt% DDPSN was obvious.

scholarly journals Effect of different PVA and steel fiber length and content on mechanical properties of CaCO3 whisker reinforced cementitious composites

2019 ◽  
Vol 69 (336) ◽  
pp. 200 ◽  
Author(s):  
M. Cao ◽  
C. Xie ◽  
L. Li ◽  
M. Khan
Keyword(s):  
Mechanical Properties ◽  
Crack Resistance ◽  
Fiber Length ◽  
Large Deflection ◽  
Steel Fiber ◽  
Flexural Behavior ◽  
Cementitious Composites ◽  
Hybrid Fiber ◽  
Pva Fiber ◽  
Fiber Reinforced Cementitious Composites

In this paper, calcium carbonate (CaCO3) whisker as a fiber reinforcement is mixed with steel and PVA fiber to form a multiscale hybrid fiber reinforced cementitious composites (MHFRCC). ASTM standard and post-crack strength techniques are performed to evaluate the mechanical properties of MHFRCC. The 1.25 % long steel fiber, 0.55 % short PVA fiber and 2.0 % CaCO3 whisker specimens showed the best flexural behavior before L/600 deflection. However, 1.5 % long steel fiber, 0.4 % long PVA fiber and 1.0 % CaCO3 whisker specimens presented better crack resistance after L/600 deflection. It is revealed that flexural parameters increase as comprehensive reinforcing index increase. The result showed that the CaCO3 whisker and short PVA fiber provided crack resistance effect at micro-scale and mainly play a dominate role in inhibiting micro-cracking. However, long steel fiber and long PVA fiber showed a better bridging effect of macro cracks at a large deflection.

Influence of Polyacrylate on the Compatibility in P(MMA/EA)/PU Semi-IPNs

2012 ◽  
Vol 627 ◽  
pp. 873-877
Author(s):  
Xiao Xia Jian ◽  
Le Qin Xiao ◽  
Wei Liang Zhou ◽  
Hai Qin Ding
Keyword(s):  
Mechanical Properties ◽  
Thermal Analysis ◽  
Polymer Networks ◽  
Thermoplastic Elastomer ◽  
Ethyl Acrylate ◽  
Interpenetrating Polymer Networks ◽  
Structure And Properties ◽  
Infrared Spectrometer ◽  
Nuclear Magnetic Resonance Spectrometry ◽  
Magnetic Resonance Spectrometry

The Semi-Interpenetrating Polymer Networks(Semi-IPNs) of poly(methyl methyacrylate/ethyl acrylate)(P(MMA/EA)) and polyurethane thermoplastic elastomer (PU) were synthesized by PU and copolymer of methyl methacrylate and ethyl acrylate to improve the compatibility of polymethyl methacrylate(PMMA) and PU Semi-IPNs . The structure and properties were investigated by Fourier transform infrared spectrometer, Solid nuclear magnetic resonance spectrometry, Dynamic mechanical thermal analysis and Mechanical properties. The tensile stress of (P(MMA/EA)/PU)( P(MMA/EA):PU=3:7) can get to 9.6MPa, the additional physical crosslinks and entanglement for Semi-IPNs are the reasons.

Regularities of the formation of the phase composition, structure and properties of the БрНХК 2.5-0.7-0.6 alloy during thermal and aerothermoacoustic treatments

2021 ◽  
pp. 71-75
Author(s):  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Phase Composition ◽  
Aging Treatment ◽  
Structure And Properties ◽  
Additional Increase ◽  
Composition Structure ◽  
Aerothermoacoustic Treatment

The influence of thermal and aerothermoacoustic treatments on the structure and mechanical properties of БрНХК bronze is considered. An increase in the strength and elasticity of the alloy is established by optimizing the thermal and aerothermoacoustic modes. The influence of the pre-aging treatment, the aging and aerothermoacoustic modes on the structure, the possibility of an additional increase in the mechanical properties of wire from БрНХК after aerothermoacoustic treatment are shown. Keywords: bronze, heat treatment, aerothermoacoustic treatment, microstructure, mechanical properties. [email protected]

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