Modelling and Simulation of Double Chamber Microbial Fuel Cell: Cell Voltage, Power Density and Temperature Variation with Process Parameters

Green ◽  
2013 ◽  
Vol 3 (3-4) ◽  
Author(s):  
Ravi Shankar ◽  
Prasenjit Mondal ◽  
Shri Chand
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Recent Literature ◽  
Cell Voltage ◽  
Membrane Thickness ◽  
The Difference ◽  
State Models ◽  
Model Equations ◽  
Double Chamber

AbstractIn the present paper steady state models of a double chamber glucose glutamic acid microbial fuel cell (GGA-MFC) under continuous operation have been developed and solved using Matlab 2007 software. The experimental data reported in a recent literature has been used for the validation of the models. The present models give prediction on the cell voltage and cell power density with 19–44% errors, which is less (up to 20%) than the errors on the prediction of cell voltage made in some recent literature for the same MFC where the effects of the difference in pH and ionic conductivity between anodic and cathodic solutions on cell voltage were not incorporated in model equations. It also describes the changes in anodic and cathodic chamber temperature due to the increase in substrate concentration and cell current density. Temperature profile across the membrane thickness has also been studied.

scholarly journals Pengaruh pH dan Metabolisme Bakteri Escherichia coli dalam Reaktor Microbial Fuel Cell Terhadap Reduksi Kromium Heksavalen

2019 ◽  
Vol 2 (2) ◽  
pp. 83
Author(s):  
Prapti Ira Kumalasari ◽  
Junety Monde ◽  
Zefanya Bernadi Yusuf ◽  
Rini Rini
Keyword(s):  
Escherichia Coli ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Ph Optimum ◽  
Double Chamber

<p class="PageNumber1">Kalimantan merupakan pulau yang terkenal akan sektor  pertambangan salah satunya di daerah delta Mahakam, yang dalam proses eksploitasinya berpotensi menghasilkan limbah logam berat, seperti logam berat Cr<sup>6+</sup>. Pencemaran logam Cr<sup>6+</sup> cukup sulit untuk terurai dilingkungan dan bersifat karsinogenik, karena dengan konsentrasi kecil saja dapat menimbulkan tingkat keracunan yang sangat tinggi pada makhluk hidup, sehingga pengolahan terhadap limbah tersebut sangat penting. <em>Microbial Fuel Cell</em> merupakan suatu metode yang dapat membantu proses pengolahan limbah dengan cara mereduksi Cr<sup>6+</sup> menjadi Cr<sup>3+</sup> dengan katalisis mikrobiologis. Penelitian ini menggunakan metode reaktor <em>double-chamber</em> yaitu terdapat ruang anoda yang berisi bakteri anaerob dan <em>basic anolyte</em>, sedangkan pada ruang katoda terdapat kalium dikromat dengan konsentrasi 18 mg/L dan variasi pH 3, 4 dan 5 yang dilakukan selama 10 hari. Kondisi pH optimum pada proses reduksi terjadi pada pH 4 dengan besar persen penurunan sekitar 98%. Dan produksi listrik tertinggi pada hari ke-2 pada variasi pH 3 dengan nilai power density sebesar sebesar 11, 06 mW/m<sup>2</sup>.</p>

scholarly journals Effect of substrate type and concentration on the performance of a double chamber microbial fuel cell

2019 ◽  
Vol 81 (7) ◽  
pp. 1336-1344 ◽  
Author(s):  
Zia Ullah ◽  
Sheikh Zeshan
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Ohmic Losses ◽  
Different Types ◽  
Double Chamber

Abstract The microbial fuel cell (MFC) provides new opportunities for energy generation and wastewater treatment through conversion of organic matter into electricity by electrogenic bacteria. This study investigates the effect of different types and concentrations of substrates on the performance of a double chamber microbial fuel cell (DCMFC). Three mediator-less laboratory-scale DCMFCs were used in this study, which were equipped with graphite electrode and cation exchange membrane. The MFCs were fed with three different types of substrates (glucose, acetate and sucrose) at a chemical oxygen demand (COD) concentration of 1,000 mg/L. The selected substrate (acetate) was studied for three different concentrations of 500, 2,000 and 3,000 mg/L of COD. Results demonstrated that acetate was the best substrate among the three different substrates with maximum power density and COD removal of 91 mW/m2 and 77%, respectively. Concentration of 2,000 mg/L was the best concentration in terms of performance with maximum power density and COD removal of 114 mW/m2 and 79%, respectively. The polarization curve shows that ohmic losses were dominant in DCMFCs established for all three substrates and concentrations.

Nitrifying biocathode enables effective electricity generation and sustainable wastewater treatment with microbial fuel cell

2009 ◽  
Vol 59 (9) ◽  
pp. 1803-1808 ◽  
Author(s):  
Hung-Thuan Tran ◽  
Dae-Hee Kim ◽  
Se-Jin Oh ◽  
Kashif Rasool ◽  
Doo-Hyun Park ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Treatment Plant ◽  
Cell Voltage ◽  
Maximum Power ◽  
Maximum Power Density ◽  
Organics Removal ◽  
Sustainable Wastewater Treatment

Simultaneous organics removal and nitrification using a novel nitrifying biocathode microbial fuel cell (MFC) reactor were investigated in this study. Remarkably, the introduction of nitrifying biomass into the cathode chamber caused higher voltage outputs than that of MFC operated with the abiotic cathode. Results showed the maximum power density increased 18% when cathode was run under the biotic condition and fed by nitrifying medium with alkalinity/NH4+-N ratio of 8 (26 against 22 mW/m2). The voltage output was not differentiated when NH4+-N concentration was increased from 50 to 100 mg/L under such alkalinity/NH4+-N ratio. However, interestingly, the cell voltage rose significantly when the alkalinity/NH4+-N ratio was decreased to 6. Consequently, the maximum power density increased 68% in compared with the abiotic cathode MFC (37 against 22 mW/m2). Polarization curves demonstrated that both activation and concentration losses were lowered during the period of nitrifying biocathode operation. Ammonium was totally nitrified and mostly converted to nitrate in all cases of the biotic cathode conditions. High COD removal efficiency (98%) was achieved. In light of the results presented here, the application of nitrifying biocathode is not only able to integrate the nitrogen and carbon removal but also to enhance the power generation in MFC system. Our system can be suggested to open up a new feasible way for upgrading and retrofitting the existing wastewater treatment plant by the use of MFC-based technologies.

scholarly journals Exergy Analysis of Polymer Electrolyte Fuel Cell Systems Using Methanol

2003 ◽  
Author(s):  
Akimitsu Ishihara ◽  
Shigenori Mitsushima ◽  
Nobuyuki Kamiya ◽  
Ken-Ichiro Ota
Keyword(s):  
Fuel Cell ◽  
Polymer Electrolyte ◽  
Steam Reforming ◽  
Waste Heat ◽  
Material Balance ◽  
Cell Voltage ◽  
Exergy Efficiency ◽  
Exergy Loss ◽  
Polymer Electrolyte Fuel Cell ◽  
The Difference

An exergy (available energy) analysis has been conducted on a typical polymer electrolyte fuel cell (PEFC) system using methanol. The material balance and enthalpy balance were calculated for the PEFC system using methanol steam reforming, and the exergy flow was obtained. Based on these results, the exergy loss in each unit was obtained, and the difference between the enthalpy and exergy was discussed. The exergy loss in this system was calculated to be 178kJ/mole MeOH for the steam reforming process of methanol. Although the enthalpy efficiency approached unity as the recovery rate of the waste heat from the cell approached unity, the exergy efficiency remained around 0.45 since the cell’s operating temperature of 80°C is low. It was also found that the cell voltage should exceed 0.82V in order to obtain the exergy efficiency of 0.5 or higher. A direct methanol fuel cell (DMFC) was analyzed using the exergy and compared with the methanol reforming PEFC. In order to obtain the exergy efficiency higher than that of PEFC with steam reforming, the cell voltage of the DMFC should be 0.48V or greater at the current density of 600mA/cm2.

scholarly journals Effect of Nitrite and Nitrate Concentrations on the Performance of AFB-MFC Enriched with High-Strength Synthetic Wastewater

2015 ◽  
Vol 2015 ◽  
pp. 1-6 ◽  
Author(s):  
Jian-sheng Huang ◽  
Ping Yang ◽  
Chong-ming Li ◽  
Yong Guo ◽  
Bo Lai ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Microbial Fuel Cell ◽  
Power Density ◽  
Nitrate Nitrogen ◽  
High Strength ◽  
Synthetic Wastewater ◽  
Flow Mode ◽  
Anode Chamber ◽  
Nitrite Nitrogen ◽  
One Year

In order to study the effect of nitrite and nitrate on the performance of microbial fuel cell, a system combining an anaerobic fluidized bed (AFB) and a microbial fuel cell (MFC) was employed for high-strength nitrogen-containing synthetic wastewater treatment. Before this study, the AFB-MFC had been used to treat high-strength organic wastewater for about one year in a continuous flow mode. The results showed that when the concentrations of nitrite nitrogen and nitrate nitrogen were increased from 1700 mg/L to 4045 mg/L and 545 mg/L to 1427 mg/L, respectively, the nitrite nitrogen and nitrate nitrogen removal efficiencies were both above 99%; the COD removal efficiency went up from 60.00% to 88.95%; the voltage was about 375 ± 15 mV while the power density was at 70 ± 5 mW/m2. However, when the concentrations of nitrite nitrogen and nitrate nitrogen were above 4045 mg/L and 1427 mg/L, respectively, the removal of nitrite nitrogen, nitrate nitrogen, COD, voltage, and power density were decreased to be 86%, 88%, 77%, 180 mV, and 17 mW/m2 when nitrite nitrogen and nitrate nitrogen were increased to 4265 mg/L and 1661 mg/L. In addition, the composition of biogas generated in the anode chamber was analyzed by a gas chromatograph. Nitrogen gas, methane, and carbon dioxide were obtained. The results indicated that denitrification happened in anode chamber.

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