An Incomplete-Dissociation Model for Diffusion and Ionic Conduction in Pure Molten Salts
1983 ◽
Vol 38
(5)
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pp. 516-519
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Keyword(s):
The Self
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Diffusion and ionic conduction in pure 1:1 molten salts is described by an incomplete-dissociation model comprising neutral diatomic molecules and monoatomic ions. The internal mobility b+- and the self-diffusion coefficients D+ and D- are given in terms of the six interparticle friction coefficients and the degree of dissociation. By an approximation it is possible to derive from experimental D+ and D- values an apparent degree of dissociation which ranges from 0.93 for NaCl to 0.51 for TlCl and decreases with temperature.
1994 ◽
Vol 49
(3-4)
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pp. 258-264
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1992 ◽
Vol 47
(10)
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pp. 1047-1050
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2008 ◽
Vol 139
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pp. 101-106
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