BIOGAS PRODUCTION IN THE CONCENTRATED DISTILLERY WASTEWATER TREATMENT

Author(s):  
N. Golub ◽  
M. Potapova ◽  
M. Shinkarchuk ◽  
O. Kozlovets

The paper deals with the waste disposal problem of the alcohol industry caused by the widespread use of alcohol as biofuels. In the technology for the production of alcohol from cereal crops, a distillery spent wash (DSW) is formed (per 1 dm3 of alcohol – 10–20 dm3 DSW), which refers to highly concentrated wastewater, the COD value reaches 40 g O2/dm3. Since the existing physical and chemical methods of its processing are not cost-effective, the researchers develop the processing technologies for its utilization, for example, an anaerobic digestion. Apart from the purification of highly concentrated wastewater, the advantage of this method is the production of biogas and highquality fertilizer. The problems of biotechnology for biogas production from the distillery spent wash are its high acidity–pH 3.7–5.0 (the optimum pH value for the methanogenesis process is 6.8–7.4) and low nitrogen content, the lack of which inhibits the development of the association of microorganisms. In order to solve these problems, additional raw materials of various origins (chemical compounds, spent anaerobic sludge, waste from livestock farms, etc.) are used. The purpose of this work is to determine the appropriate ratio of the fermentable mixture components: cosubstrate, distillery spent wash and wastewater of the plant for co-fermentation to produce an energy carrier (biogas) and effective wastewater treatment of the distillery. In order to ensure the optimal pH for methanogenesis, poultry manure has been used as a co-substrate. The co-fermentation process of DSW with manure has been carried out at dry matter ratios of 1:1, 1:3, 1:5, 1:7 respectively. It is found that when the concentration of manure in the mixture is insufficient (DSW/manure – 1:1, 1:3), the pH value decreases during fermentation which negatively affects methane formation; when the concentration of manure in the mixture is increased (DSW/manure – 1:5, 1:7), the process is characterized by a high yield of biogas and methane content. The maximum output of biogas with a methane concentration of 70 ± 2% is observed at the ratio of components on a dry matter “wastewater: DSW: manure” – 0,2:1:7 respectively. The COD reduction reaches a 70% when using co-fermentation with the combination of components “wastewater: DSW: manure” (0,3:1:5) respectively.

2013 ◽  
Vol 68 (8) ◽  
pp. 1739-1744 ◽  
Author(s):  
P. Jenicek ◽  
J. Kutil ◽  
O. Benes ◽  
V. Todt ◽  
J. Zabranska ◽  
...  

The anaerobic digestion of primary and waste activated sludge generates biogas that can be converted into energy to power the operation of a sewage wastewater treatment plant (WWTP). But can the biogas generated by anaerobic sludge digestion ever completely satisfy the electricity requirements of a WWTP with ‘standard’ energy consumption (i.e. industrial pollution not treated, no external organic substrate added)? With this question in mind, we optimized biogas production at Prague's Central Wastewater Treatment Plant in the following ways: enhanced primary sludge separation; thickened waste activated sludge; implemented a lysate centrifuge; increased operational temperature; improved digester mixing. With these optimizations, biogas production increased significantly to 12.5 m3 per population equivalent per year. In turn, this led to an equally significant increase in specific energy production from approximately 15 to 23.5 kWh per population equivalent per year. We compared these full-scale results with those obtained from WWTPs that are already energy self-sufficient, but have exceptionally low energy consumption. Both our results and our analysis suggest that, with the correct optimization of anaerobic digestion technology, even WWTPs with ‘standard’ energy consumption can either attain or come close to attaining energy self-sufficiency.


2019 ◽  
Vol 8 (3) ◽  
pp. 1826-1829

In the process of treating wastewaters from different industries by using anaerobic reactor, initially the start-up process is the first step to stabilize the reactor. The aim of this research is to conduct the start-up process and to evaluate the characterization of synthetic organic wastewater using Hybrid up flow Anaerobic Sludge Blanket reactor (HUASBR) with the effective volume of 20L. Initially the reactor was processed with synthetic organic wastewater with COD of 3200 mg/l. The processes were continuously operated with hydraulic retention time of 24 hours for 48 days. The results obtained after the process of stabilization were, COD removal is 87.8%, VFA was Stable for the operating condition, Biogas production was increased as 13.2 l/d during the maximum removal of COD and the pH value of outlet is ranging from 5.5-7.9.


2015 ◽  
Vol 21 (2) ◽  
pp. 229-237 ◽  
Author(s):  
Nazila Tehrani ◽  
Ghasem Najafpour ◽  
Mostafa Rahimnejad ◽  
Hossein Attar

Among various wastewater treatment technologies, biological wastewater treatment appears to be the most promising method. A pilot scale of hybrid anaerobic bioreactor was fabricated and used for the whey wastewater treatment. The top and bottom of the hybrid bioreactor known as up flow anaerobic sludge fixed film (UASFF); was a combination of up flow anaerobic sludge blanket (UASB) and up flow anaerobic fixed film reactor (UAFF), respectively. The effects of operating parameters such as temperature and hydraulic retention time (HRT) on chemical oxygen demand (COD) removal and biogas production in the hybrid bioreactor were investigated. Treatability of the samples at various HRTs of 12, 24, 36 and 48 hours was evaluated in the fabricated bioreactor. The desired conditions for COD removal such as HRT of 48 hours and operation temperature of 40 ?C were obtained. The maximum COD removal and biogas production were 80% and 2.40 (L/d), respectively. Kinetic models of Riccati, Monod and Verhalst were also evaluated for the living microorganisms in the treatment process. Among the above models, Riccati model was the best growth model fitted with the experimental data with R2 of about 0.99.


2020 ◽  
Vol 8 (2) ◽  
pp. 277 ◽  
Author(s):  
Pantakan Puengrang ◽  
Benjaphon Suraraksa ◽  
Peerada Prommeenate ◽  
Nimaradee Boonapatcharoen ◽  
Supapon Cheevadhanarak ◽  
...  

Anaerobic digestion (AD) has been used for wastewater treatment and production of renewable energy or biogas. Propionate accumulation is one of the important problems leading to an unstable system and low methane production. Revealing propionate-degrading microbiome is necessary to gain a better knowledge for alleviation of the problem. Herein, we systematically investigated the propionate-degrading cultures enriched from various anaerobic sludge sources of agro-industrial wastewater treatment plants using 16S rRNA gene sequencing. Different microbial profiles were shown even though the methanogenic activities of all cultures were similar. Interestingly, non-classical propionate-degrading key players Smithella, Syntrophomonas, and Methanosaeta were observed as common prevalent taxa in our enriched cultures. Moreover, different hydrogenotrophic methanogens were found specifically to the different sludge sources. The enriched culture of high salinity sludge showed a distinct microbial profile compared to the others, containing mainly Thermovirga, Anaerolinaceae, Methanosaeta, Syntrophobactor, and Methanospirillum. Our microbiome analysis revealed different propionate-degrading community profiles via mainly the Smithella pathway and offers inside information for microbiome manipulation in AD systems to increase biogas production corresponding to their specific microbial communities.


2005 ◽  
Vol 51 (1) ◽  
pp. 137-144 ◽  
Author(s):  
R. Moletta

Anaerobic digestion is widely used for wastewater treatment, especially in the food industries. Generally after the anaerobic treatment there is an aerobic post-treatment in order to return the treated water to nature. Several technologies are applied for winery wastewater treatment. They are using free cells or flocs (anaerobic contact digesters, anaerobic sequencing batch reactors and anaerobic lagoons), anaerobic granules (Upflow Anaerobic Sludge Blanket – UASB), or biofilms on fixed support (anaerobic filter) or on mobile support as with the fluidised bed. Some technologies include two strategies, e.g. a sludge bed with anaerobic filter as in the hybrid digester.With winery wastewaters (as for vinasses from distilleries) the removal yield for anaerobic digestion is very high, up to 90–95% COD removal. The organic loads are between 5 and 15 kgCOD/m3 of digester/day. The biogas production is between 400 and 600 L per kg COD removed with 60 to 70% methane content. For anaerobic and aerobic post-treatment of vinasses in the Cognac region, REVICO company has 99.7% COD removal and the cost is 0.52 Euro/m3 of vinasses.


2002 ◽  
Vol 45 (12) ◽  
pp. 135-142 ◽  
Author(s):  
B. Inanc ◽  
B. Calli ◽  
K. Alp ◽  
F. Ciner ◽  
B. Mertoglu ◽  
...  

This paper describes the wastewater characterization and aerobic/anaerobic treatability (oxygen uptake rate and biogas production measurement) of chemical-synthesis based pharmaceutical industry effluents in a nearby baker's yeast industry treatment plant. Preliminary experiments by the industry had indicated strong anaerobic toxicity. On the other hand, aerobic treatability was also uncertain due to complexity and unknown composition of the wastewater. The work in this study has indicated that the effluents of the pharmaceutical industry can be treated without toxicity in the aerobic stage of the treatment plant. Methanogenic activity tests with anaerobic sludge from the anaerobic treatment stage of the wastewater treatment plant and acetate as substrate have confirmed the strong toxicity, while showing that 30 min aeration or coagulation with an alum dose of 300 mg/l is sufficient for reducing the toxicity almost completely. Powdered activated carbon, lime and ferric chloride (100-1,000 mg/l) had no effect on reduction of the toxicity. Consequently, the pharmaceutical industry was recommended to treat its effluents in the anaerobic stage of the nearby baker's yeast industry wastewater treatment plan at which there will be no VOC emission and toxicity problem, provided that pretreatment is done.


2012 ◽  
Vol 34 (2) ◽  
pp. 114 ◽  
Author(s):  
Trisno Saputra ◽  
Suharjono Triatmojo ◽  
Ambar Pertiwiningrum

<p>he experiment was conducted to determine biogas quality produced from mixture of dairy manure and bagasse with different C/N ratio level, and to know the optimal mixture ratio. There were three group treatments based on C/N<br />ratio level : C/N ratio 22, 30, and 35 with three replications each. Nine units of 20 litre batch-feeding digesters were used during 30 days examination. The main data were BOD, COD, pH and VFA values, total biogas volume, and<br />methane value. C/N ratio of dairy manure and bagasse was 22, 12, and 198. Dry matter mixture was 7%. BOD value was decreased 54.33%, 27.89%, and 42.86%, COD value was decreased 35.85%, 8.29%, and 27.88% and biogas was<br />produced as much as 29.42 litre, 68.51 litre, and 114.73 litre by each treatment with methane values of 24.16%, 27.5%, and 23.38%. VFA value were 27.19 ml mol, 27.86 ml mol, and 30.73 ml mol respectively during operation. BOD and<br />COD value decrease, pH value, biogas temperature, and total biogas volume was different among treatment. The optimal mixture was C/N ratio 30 treatment. The results indicated that bagasse could be used as material mixture in biogas production.</p><p>(Key words : Biogas, Dairy manure, Bagasse, C/N ratio, Methane)<br /><br /></p>


2021 ◽  
Author(s):  
Manoj Wagh ◽  
Pravin Nemade ◽  
Ashok Biradar

Abstract The spent wash generated in the distillation process has very high organic content like biochemical oxygen demand (BOD) and chemical oxygen demand (COD), which are treated to curtail the levels of COD and BOD. Day by day the rules and legislation are stringent and mandatory for disposal of distillery spent wash. Anaerobic treatment is the primary treatment widely adopted to generate biogas. To find out the potential of recalcitrant effluent a case study of the full-scale operating biomethanation plants at Sanjivani, SSK Ltd, Kopargaon, (M.S), India and Spectrum Renewable Energy Pvt. Ltd. (SREL) Warnanagar (M. S.), India was incorporated. Up-flow Anaerobic Sludge Blanket treatment was implemented to generate the biogas. Sanjivani distillery industry, Kopargaon has a COD removal efficiency of 70–72% with specific biogas generation of 0.5 m3/ kg COD removal, and total biogas generated is 38000 Nm3/d. Mechanical Vapour Recompression (MVR) is the cutting-edge technology executed to convert distillery spent wash into useful by-products such as biogas, clean water, and organic manure.


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