Structure property relationships in core-shell BaTiO3–LiF ceramics

1993 ◽  
Vol 8 (4) ◽  
pp. 871-879 ◽  
Author(s):  
C.A. Randall ◽  
S.F. Wang ◽  
D. Laubscher ◽  
J.P. Dougherty ◽  
W. Huebner

A sintering, microstructural development and dielectric property study of BaTiO3–LiF ceramics was performed to assess the potential application of low-fired multilayer capacitors. Not only does LiF allow for sintering below 1000 °C, it also allows for the manipulation of dielectric properties and interfaces within BaTiO3–LiF ceramics. Using mixing laws, a model of the dielectric properties of the core-shell microstructures is presented that agrees well with the observed experimental data.

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Guangfeng Wu ◽  
Yue Tao ◽  
Hong Kang ◽  
Huixuan Zhang

AbstractThe stability of core-shell particles (CSPs) with butyl acrylate (BA) as the core and methyl methacrylate (MMA)/glycidyl methacrylate (GMA) mixture in various compositions as the shell was investigated by turbidity measurements. The experiments demonstrate that lower amount addition of GMA could not improve the latex stability. When the amount of GMA exceeded 2% of the total reactants, it began to improve the stability of the latex. With the increasing content of GMA, the latex became more and more stable. On the other hand, experimental data also show that the stability was improved by increasing the concentration of sodium dodecyl sulfate (SDS).


2014 ◽  
Vol 6 (3) ◽  
pp. 1227-1232
Author(s):  
Peter Ekuma Agbo

Thin film of the form TiO2/MnO2 was deposited using the chemical bath method. The deposited thin films were annealed at temperatures of in order to investigate the effect of annealing temperature on the refractive index and dielectric property. To do this the films were characterized using UV-Spectrophotometer and XRD analysis was also carriedout to study the structural nature of the deposited film. Our results reaveled that annealing has profound effect on theindex of refraction and the dielectric properties.  


Langmuir ◽  
2009 ◽  
Vol 25 (18) ◽  
pp. 11021-11031 ◽  
Author(s):  
Elisabetta Canetta ◽  
Jeanne Marchal ◽  
Chun-Hong Lei ◽  
Fanny Deplace ◽  
Alexander M. König ◽  
...  

2010 ◽  
Vol 150-151 ◽  
pp. 745-748 ◽  
Author(s):  
Qian Xu ◽  
Shao Guo Wen ◽  
Hong Bo Liu ◽  
Ji Hu Wang ◽  
Yan Shen

The core-shell acrylic emulsion was synthesized,with P(MMA/BA) as core,and with P(2-EHA/MBA/HPA) as shell. The influence of the mass ratio of core/shell on mechanical properties was investigated in detail. The high elongation at break proved that the emulsion may have a potential application in coating industry, afforded by HPA as functional monomer. However, when the amount of HPA exceeds 1.5 wt. % to the total monomers, the emulsion will become unstable and precipitation occurs.


2021 ◽  
Author(s):  
Won Jin Choi ◽  
Keiichi Yano ◽  
Minjeong Cha ◽  
Felippe Colombari ◽  
Yichun Wang ◽  
...  

Abstract Chiral phonons are concerted mirror-symmetric movements of atomic groups connected by covalent and intermolecular bonds. Finding chiral phonons in biocrystals is fundamentally and technologically important because these lattice vibrations should be highly specific to their short- and long-range organizations. Based on theoretical and experimental data they might be expected but not identified or utilized. Here we show that terahertz chiroptical spectroscopy enables registration and attribution of chiral phonons in microcrystals of numerous amino acids and dipeptides. Theoretical analysis and computer simulations confirm that sharp mirror-symmetric bands observed for left and right enantiomers originate from collective vibrations of biomolecules interconnected by hydrogen bonds into helical chains. Structure-property relationships for strong phonons with rotatory components in biocrystals were also identified. Bladder stones and health supplements display strong spectral signatures of chiral phonons indicating their immediate importance for biomedicine.


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