Y1Ba2Cu3O7–x multilayer structures with a thick SiO2 interlayer for multichip modules

1997 ◽  
Vol 12 (11) ◽  
pp. 2947-2951 ◽  
Author(s):  
S. Afonso ◽  
K. Y. Chen ◽  
Q. Xiong ◽  
Y. Q. Tang ◽  
G. J. Salamo ◽  
...  

For high temperature superconducting multichip modules and other related electronic applications, it is necessary to be able to fabricate several Y1Ba2Cu3O7–x (YBCO) layers separated by thick low dielectric constant dielectric layers. In this work, we report the successful fabrication of YBCO/YSZ/SiO2 (1–2 μm)/YSZ/YBCO multilayer structures on single crystal yttria stabilized zirconia (YSZ) substrates. In contrast to previously reported work, the top YBCO layer did not show any cracking. This is due to a technique that allows for stress relief in the SiO2 layer before the second YBCO layer is deposited. The top YBCO layer in our multilayer structure had Tc = 87 K and Jc = 105 A/cm2 (at 77 K), whereas the bottom YBCO layer had Tc = 90 K and Jc = 1.2 × 106 A/cm2 (at 77 K). We also showed that the quality of the bottom YBCO layer was preserved during the fabrication of the multilayer due to the annealing process during which O2 diffused into the YBCO, replacing the O2 lost during the deposition of the top YBCO layer.

Author(s):  
Wolff-Ragnar Kiebach ◽  
Ruth Knibbe ◽  
Kristian B. Frederiksen ◽  
Ming Chen ◽  
Lars Mikkelsen ◽  
...  

The two braze alloys TiCuNi® and Silver-ABA® were tested as possible candidates for seals in SOFC or SOEC stacks. The different Ti amount in the samples allowed an evaluation of Ti as a matrix filler and as an active metal/wetting agent in brazing alloys. The sealing ability towards ferritic steel and yttria-stabilized-zirconia (YSZ) was investigated. After the sealing process steel/braze/YSZ joints were further annealed in oxidizing (Air) or reducing (9% H2 in Ar) atmospheres at 750 °C for 150 h. The boundaries of the braze and the joining partners for as-sealed and annealed samples were examined with SEM/EDS. XRD and EXAFS were used to characterize reaction products after the annealing process. Based on these results and taking before reported data into consideration, the advantages and disadvantages of Ti containing seals and the role of Ti in failure mechanism are discussed. Even if the use of Ti in active brazing alloys has its benefits, the disadvantages caused by Ti and its reaction products strongly suggest the use of Ti free brazes in SOFC/SOEC applications.


2017 ◽  
Vol 4 (3) ◽  
pp. 121-135 ◽  
Author(s):  
Surendra K. Saini ◽  
Avanish K. Dubey ◽  
Piyush Pant ◽  
B. N. Upadhyay ◽  
A. Choubey

2016 ◽  
Vol 19 (4) ◽  
pp. 232-240
Author(s):  
Linh Ba Ngoc Nguyen ◽  
Dung Van Hoang ◽  
Van Thi Thanh Tran

In this study, the co- precipitation method and annealing process were used to prepare the yttria stabilized zirconia ceramics. Data of Raman and XRD showed that an increase of yttria doping leads to an decrease of the ratio between monoclinic and tetragonal phases. Howerver, it existed a critical concentration of yttrium at which the highest value of hardness was about 14.5 GPa and grain sizes of 0.2–0.5 m. An investigation of low temperature degradation indicated that theaging process only occurred in the first 5 hours and then virtually negligible changes.


1995 ◽  
Vol 67 (8) ◽  
pp. 1148-1150 ◽  
Author(s):  
Bertha P. Chang ◽  
Neville Sonnenberg ◽  
Michael J. Cima ◽  
Jonathan Z. Sun ◽  
Lock See Yu‐Jahnes

2012 ◽  
Vol 507 ◽  
pp. 61-66
Author(s):  
J.A. Escribano ◽  
Isabel Gonzalo-Juan ◽  
Antonio Javier Sanchez-Herencia ◽  
Begoña Ferrari

In this study, coatings with irregular nanotopography prepared by electrophoretic deposition (EPD) in electro-polished surfaces are characterized. Films are composed by Yttria Stabilized Zirconia (YSZ) particles, 5-8 nm in size and spherical morphology, synthesized under hydrothermal conditions and re-dispersed in the post reaction medium. Growth behaviour of coatings with time, including array morphology, aggregation origin and activity, are explored by means of atomic force microscopy (AFM) and its different measurement modes. Arrangement of electrically driven particles at the nanoscale can be assessed through the topographic description of films prepared with increasing deposition times. Moreover, topography can be associated to the electrokinetic behaviour of particles and agglomeration degree of the suspension. The evaluation of particle junctions and then the quality of particle cohesion within the film can also be discerned by AFM characterization.


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