The Relationship between Growth Speed and Ambient Humidity in Convective Self-assembly

2010 ◽  
Vol 1273 ◽  
Author(s):  
Hans D. Robinson ◽  
Kai Chen ◽  
Stefan V. Stoianov

AbstractWe present a variation of a standard convective self-assembly technique, where the drying meniscus is restricted by a straight-edge located approximately 100 μm above the substrate adjacent to the drying zone. We find this technique to yield films at roughly twice the growth rate compared to the standard technique. We attribute this to differing local evaporation rates in the two cases. We also investigate how the crystal growth rate depends on ambient relative humidity and find a clear linear dependency, which we attribute to the length of the drying zone being constant over a wide range of humidities.

2011 ◽  
Vol 10 (04n05) ◽  
pp. 1113-1118
Author(s):  
M. HARIDAS ◽  
J. K. BASU

Arrays of quantum dots and hybrid arrays of semiconducting quantum dots and metallic nanoparticles have wide range of potential applications from nanophotonics to quantum information processing. Creating such arrays with well-defined morphology and order over a large area is a challenge. We present a reliable method for constructing such arrays using simple self assembly technique. The reliability of the method is verified using AFM. The emission properties of such system are studied using high resolution imaging techniques and we have given the possible explanation for the observed phenomena.


1984 ◽  
Vol 30 (2) ◽  
pp. 192-203 ◽  
Author(s):  
W. LaJean Chaffin

The mean size and percentage of budded and unbudded cells of Candida albicans grown in batch culture over a wide range of doubling times have been measured. Cell volume decreased with increased doubling time and a nonlinear approach to an asymptotic minimum was observed. When cells were separated by age according to bud scars, each age showed a similar decrease. During each cell division cycle, size increased slowly during both budded and unbudded periods so that each generation was significantly larger than the preceeding. There was no difference in size between the parent portion of budded cells and unbudded cells of the same age. Time-lapse photomicroscopy of cells growing on solid medium showed that cells divide asymmetrically with larger parents having a shorter subsequent cycle time than the smaller daughter, although the time utilized for bud formation was similar. When cells were shifted from a medium supporting a low growth rate and small size to a medium supporting a faster growth rate and larger size, both budded and unbudded cells increased significantly in size. As the doubling time increased, both the budded and unbudded portions of parental and daughter cycles increased.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Stéphane Chabaud ◽  
Stéphane Bolduc

Many pathologies of skin, especially ageing and cancer, involve modifications in the matrix alignment. Such tissue reorganization could have impact on cell behaviour and/or more global biological processes. Tissue engineering provides accurate study model by mimicking the skin and it allows the construction of versatile tridimensional models using human cells. It also avoids the use of animals, which gave sometimes nontranslatable results. Among the various techniques existing, the self-assembly method allows production of a near native skin, free of exogenous material. After cultivating human dermal fibroblasts in the presence of ascorbate during two weeks, a reseeding of these cells takes place after elevation of the resulting stroma on a permeable ring and culture pursued for another two weeks. This protocol induces a clear realignment of matrix fibres and cells parallel to the horizon. The thickness of this stretched reconstructed tissue is reduced compared to the stroma produced by the standard technique. Cell count is also reduced. In conclusion, a new, easy, and inexpensive method to produce aligned tissue free of exogenous material could be used for fundamental research applications in dermatology.


2004 ◽  
Vol 76 (7-8) ◽  
pp. 1337-1343 ◽  
Author(s):  
C.-Y. Chao ◽  
X. Li ◽  
C. K. Ober

Hydrogen-bonded side-chain liquid-crystalline block copolymers (SCLCBCPs) containing block segments with proton donors were combined with functionalized mesogenic pendent groups. Studies of a wide range of mesogen and polymer combinations were carried out to study the relationship between morphology and mesophase behavior. The thermal behaviors of the resulting self-assembled microstructures were also examined. A model of the assembly process leading to mesogenic group organization corresponding to different compositions was proposed.


2020 ◽  
Author(s):  
Elisa Bonnin ◽  
Howard Spero ◽  
Alexander Gagnon

<p>The Mg/Ca paleotemperature proxy in planktic foraminifera is one of the most widely-used proxies for sea surface temperature. However, this ratio is not constant throughout the test, varying systematically by several fold independent of temperature between faster and slower growing diurnal bands. This phenomenon has yet to be explained mechanistically, however, changing calcification rates may be a contributing factor. Observing the relationship between calcification rate and trace metal incorporation for multiple proxies at the scale of this banding will allow us to better understand the contribution of kinetic effects to heterogeneity. In this study, we examine Me/Ca ratios on a diurnal cycle in Orbulina universa, utilizing a novel approach based on multiple isotopic spikes that allows us to measure Sr/Ca, Li/Ca and Mg/Ca with the precision of isotope dilution while still maintaining the time resolution of microanalytical techniques. Using independently measured growth rates derived from NanoSIMS measurements of diurnal Mg/Ca heterogeneity, we examine the effect of crystal growth rate on foraminiferal Sr/Ca and Li/Ca.  We observe that Sr/Ca ratios in foraminifera are ~3% higher during the night than during the day, which initially appears opposite to the expected signal based on growth rate. However, we also observe a positive correlation between Sr and Mg in foraminiferal calcite, which falls on the same mineralogical line as the Sr/Ca and Mg/Ca of other biogenic and inorganic calcites. We attribute offsets in calcite composition from this mineralogical relationship to kinetics. Interpreted within that framework, day Sr/Ca ratios appear more affected by kinetics than night Sr/Ca ratios, which is consistent with observed calcification rates. The difference between any given data point and the mineralogical line can be explained by kinetic processes, and correlates with oceanographic properties in cultured foraminifera, which could help separate temperature from growth rate effects in the paleorecord.</p>


2014 ◽  
Vol 1621 ◽  
pp. 155-161 ◽  
Author(s):  
Banu Taktak Karaca ◽  
James Meyer ◽  
Sarah VanOosten ◽  
Mark Richter ◽  
Candan Tamerler

ABSTRACTThe self-organization of functional proteins directly onto solid materials is attractive to a wide range of biomaterials and systems that need to accommodate a biological recognition element. In such systems, inorganic binding peptides may be an essential component due to their high affinity and selective binding features onto different types of solid surfaces. This study demonstrates a peptide-enabled self-assembly technique for designing well-defined protein arrays over a metal surface. To illustrate this concept, we designed a fusion protein that simultaneously displays a red fluorescence protein (DsRed-monomer), which is highly selective for copper ions, and a gold binding peptide AuBP. The peptide tag, AuBP, self-directs the organization of DsRed-monomer protein onto a gold surface and forms arrays built upon an efficient control of the organic/inorganic interface at the molecular level. The peptide-assisted design offers a modular approach for fabrication of fluorescent-based protein arrays with copper ion sensing ability.


1987 ◽  
Vol 48 (C1) ◽  
pp. C1-661-C1-662 ◽  
Author(s):  
J. R. PETIT ◽  
P. DUVAL ◽  
C. LORIUS

2008 ◽  
pp. 61-76
Author(s):  
A. Porshakov ◽  
A. Ponomarenko

The role of monetary factor in generating inflationary processes in Russia has stimulated various debates in social and scientific circles for a relatively long time. The authors show that identification of the specificity of relationship between money and inflation requires a complex approach based on statistical modeling and involving a wide range of indicators relevant for the price changes in the economy. As a result a model of inflation for Russia implying the decomposition of inflation dynamics into demand-side and supply-side factors is suggested. The main conclusion drawn is that during the recent years the volume of inflationary pressures in the Russian economy has been determined by the deviation of money supply from money demand, rather than by money supply alone. At the same time, monetary factor has a long-run spread over time impact on inflation.


2012 ◽  
Vol 9 (1) ◽  
pp. 43 ◽  
Author(s):  
Hueyling Tan

Molecular self-assembly is ubiquitous in nature and has emerged as a new approach to produce new materials in chemistry, engineering, nanotechnology, polymer science and materials. Molecular self-assembly has been attracting increasing interest from the scientific community in recent years due to its importance in understanding biology and a variety of diseases at the molecular level. In the last few years, considerable advances have been made in the use ofpeptides as building blocks to produce biological materials for wide range of applications, including fabricating novel supra-molecular structures and scaffolding for tissue repair. The study ofbiological self-assembly systems represents a significant advancement in molecular engineering and is a rapidly growing scientific and engineering field that crosses the boundaries ofexisting disciplines. Many self-assembling systems are rangefrom bi- andtri-block copolymers to DNA structures as well as simple and complex proteins andpeptides. The ultimate goal is to harness molecular self-assembly such that design andcontrol ofbottom-up processes is achieved thereby enabling exploitation of structures developed at the meso- and macro-scopic scale for the purposes oflife and non-life science applications. Such aspirations can be achievedthrough understanding thefundamental principles behind the selforganisation and self-synthesis processes exhibited by biological systems.


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