In-Plane Asymmetries on the Ge(111)-c(2×8) Surface Mapped with the Scanning Tunneling Microscope

1992 ◽  
Vol 295 ◽  
Author(s):  
P. Molinàs-Mata ◽  
J. Zegenhagen ◽  
M. Böhringer ◽  
N. Takeuchi ◽  
A. Selloni
Keyword(s):  
Local Density ◽  
Experimental Studies ◽  
Surface States ◽  
Small Sample ◽  
Constant Current ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Low Energy Electron ◽  
Tunneling Currents ◽  
Insight Into

AbstractWe report on new experimental studies of the Ge(111)-c(2×8) reconstruction performed with low-energy electron diffraction. (LEED) and scanning tunneling microscopy (STM). Weak quarter-order reflections are present in the c(2 × 8) LEED pattern in agreement with previous observations and results of ab initio calculations. In order to gain insight into the predicted splitting of dangling bond states, we compare constant current topographs (CCT's) performed at high-tunneling currents (40.nA) with first-principles calculations of the local density of states (LDOS) 1Å above the surface adatoms and obtain good qualitative agreement. We finally discuss to what extent the STM CCT's at high tunneling currents (small sample-tip distances (STD)) are sensitive to surface states outside the Г point.

Spectroscopic Characterization of Nanoscale Modification of Passivated Si(100) Surface by STM

1994 ◽  
Vol 332 ◽  
Author(s):  
F. PÉRez-Murano ◽  
N. Barniol ◽  
X. Aymerich
Keyword(s):  
Local Density ◽  
Surface States ◽  
Spectroscopic Characterization ◽  
Constant Current ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Band Bending ◽  
Sample Spacing ◽  
Current Voltage

ABSTRACTThe electrochemical modification of H-passivated Si(100) surface is produced and characterized by Scanning Tunneling Microscopy and Spectroscopy (STM/STS) operating in air. In order to better understand this nanometer scale modification, we have characterized spectroscopically the modified region. From the current-voltage (I/V) curves, dI/dV versus V curves and tip to sample spacing versus voltage (s/V) curves (at constant current) we have concluded that the modification induces a local electrochemical change on the surface, which in turn produces both, a decrease of the local density of surface states and a variation of the band bending in the silicon surface.

Scanning tunneling microscopy of polymers: A status report

1989 ◽  
Vol 47 ◽  
pp. 330-331
Author(s):  
P.E. Russell ◽  
I.H. Musselman
Keyword(s):  
High Resolution ◽  
Scanning Tunneling Microscopy ◽  
Sample Surface ◽  
Atomic Scale ◽  
Constant Current ◽  
Scanning Tunneling ◽  
Status Report ◽  
Tunneling Microscopy ◽  
Research Issues ◽  
Wide Range

Scanning tunneling microscopy (STM) has evolved rapidly in the past few years. Major developments have occurred in instrumentation, theory, and in a wide range of applications. In this paper, an overview of the application of STM and related techniques to polymers will be given, followed by a discussion of current research issues and prospects for future developments. The application of STM to polymers can be conveniently divided into the following subject areas: atomic scale imaging of uncoated polymer structures; topographic imaging and metrology of man-made polymer structures; and modification of polymer structures. Since many polymers are poor electrical conductors and hence unsuitable for use as a tunneling electrode, the related atomic force microscopy (AFM) technique which is capable of imaging both conductors and insulators has also been applied to polymers.The STM is well known for its high resolution capabilities in the x, y and z axes (Å in x andy and sub-Å in z). In addition to high resolution capabilities, the STM technique provides true three dimensional information in the constant current mode. In this mode, the STM tip is held at a fixed tunneling current (and a fixed bias voltage) and hence a fixed height above the sample surface while scanning across the sample surface.

Surface Structures of Phosphorus and Indium on Si(111)

1998 ◽  
Vol 05 (01) ◽  
pp. 69-76
Author(s):  
F. P. Netzer ◽  
L. Vitali ◽  
J. Kraft ◽  
M. G. Ramesy
Keyword(s):  
Elevated Temperature ◽  
Room Temperature ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Low Energy Electron Diffraction ◽  
Diffusion Limited ◽  
Lower Terrace ◽  
Surface Reconstructions ◽  
Low Energy Electron ◽  
Stm Images

The interaction of vapor phase P2 with the [Formula: see text] monolayer surface at room temperature and elevated temperature has been monitored by scanning tunneling microscopy (STM) and spectroscopy (STS) in conjunction with Auger electron spectroscopy and low-energy electron diffraction (LEED). The surface rection can be readily followed by STM because of the very different contrast of the reacted areas in the STM images. The reaction develops around overlayer defects at room temperature and appears to be diffusion-limited, whereas at 300°C the reaction is initiated at the step edges, from which the reaction front progresses onto the lower terrace areas. At elevated temperature several ordered surface reconstructions, showing different STS fingerprints, are detected on the P–In/Si(111) surfaces, which are associated tentatively with P- and Si-terminated structures and an ordered InP phase.

COMBINED HRLEED AND STM INVESTIGATIONS ON THE INITIAL STAGES OF Cu HETEROEPITAXY Ru(0001)

1997 ◽  
Vol 04 (06) ◽  
pp. 1167-1171 ◽  
Author(s):  
CH. AMMER ◽  
K. MEINEL ◽  
H. WOLTER ◽  
A. BECKMANN ◽  
H. NEDDERMEYER
Keyword(s):  
High Resolution ◽  
Electron Diffraction ◽  
Strain Relaxation ◽  
Local Scale ◽  
Low Energy ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Low Energy Electron Diffraction ◽  
Layer Structures ◽  
Low Energy Electron

Recent scanning tunneling microscopy (STM) observations revealed different layer structures in the heteroepitaxial Cu/Ru(0001) system with increasing film thickness attributed to various stages of strain relaxation. High-resolution low-energy electron diffraction (HRLEED) analysis permits one to derive more exactly both lattice periodicities and lattice rotations. Furthermore, the representative character of local STM results can be proved. However, STM measurements are needed to identify and to assign the satellite spots to coexistent different superstructures which are superposed incoherently in the diffraction pattern. Generally, the integral LEED results confirm the crystallographic data obtained by STM in a local scale.

scholarly journals Mono- and multilayers of molecular spoked carbazole wheels on graphite

2014 ◽  
Vol 10 ◽  
pp. 2783-2788 ◽  
Author(s):  
Stefan-S Jester ◽  
A Vikas Aggarwal ◽  
Daniel Kalle ◽  
Sigurd Höger
Keyword(s):  
Octanoic Acid ◽  
Pyrolytic Graphite ◽  
Self Assembled Monolayers ◽  
Scanning Tunneling ◽  
Tunneling Microscopy ◽  
Chemical Structures ◽  
Rigid Objects ◽  
Assembled Monolayers ◽  
Stm Images ◽  
Insight Into

Self-assembled monolayers of a molecular spoked wheel (a shape-persistent macrocycle with an intraannular spoke/hub system) and its synthetic precursor are investigated by scanning tunneling microscopy (STM) at the liquid/solid interface of 1-octanoic acid and highly oriented pyrolytic graphite. The submolecularly resolved STM images reveal that the molecules indeed behave as more or less rigid objects of certain sizes and shapes – depending on their chemical structures. In addition, the images provide insight into the multilayer growth of the molecular spoked wheels (MSWs), where the first adlayer acts as a template for the commensurate adsorption of molecules in the second layer.

scholarly journals Lateral ordering of PTCDA on the clean and the oxygen pre-covered Cu(100) surface investigated by scanning tunneling microscopy and low energy electron diffraction

2014 ◽  
Vol 10 ◽  
pp. 2055-2064 ◽  
Author(s):  
Stefan Gärtner ◽  
Benjamin Fiedler ◽  
Oliver Bauer ◽  
Antonela Marele ◽  
Moritz M Sokolowski
Keyword(s):  
Electron Diffraction ◽  
Scanning Tunneling Microscopy ◽  
Low Energy ◽  
Energy Electron ◽  
Scanning Tunneling ◽  
Structure Model ◽  
Tunneling Microscopy ◽  
Low Energy Electron Diffraction ◽  
Low Energy Electron ◽  
Lattice Planes

We have investigated the adsorption of perylene-3,4,9,10-tetracarboxylic acid dianhydride (PTCDA) on the clean and on the oxygen pre-covered Cu(100) surface [referred to as (√2 × 2√2)R45° – 2O/Cu(100)] by scanning tunneling microscopy (STM) and low energy electron diffraction (LEED). Our results confirm the (4√2 × 5√2)R45° superstructure of PTCDA/Cu(100) reported by A. Schmidt et al. [J. Phys. Chem. 1995, 99,11770–11779]. However, contrary to Schmidt et al., we have no indication for a dissociation of the PTCDA upon adsorption, and we propose a detailed structure model with two intact PTCDA molecules within the unit cell. Domains of high lateral order are obtained, if the deposition is performed at 400 K. For deposition at room temperature, a significant density of nucleation defects is found pointing to a strong interaction of PTCDA with Cu(100). Quite differently, after preadsorption of oxygen and formation of the (√2 × 2√2)R45° – 2O/Cu(100) superstructure on Cu(100), PTCDA forms an incommensurate monolayer with a structure that corresponds well to that of PTCDA bulk lattice planes.

Density fluctuations as door-opener for diffusion on crowded surfaces

Science ◽  
2019 ◽  
Vol 363 (6428) ◽  
pp. 715-718 ◽  
Author(s):  
Ann-Kathrin Henß ◽  
Sung Sakong ◽  
Philipp K. Messer ◽  
Joachim Wiechers ◽  
Rolf Schuster ◽  
...  
Keyword(s):  
High Speed ◽  
Density Functional ◽  
Local Density ◽  
Variable Temperature ◽  
Industrial Process ◽  
Density Fluctuations ◽  
Scanning Tunneling ◽  
Fast Diffusion ◽  
Tunneling Microscopy ◽  
Adsorption Sites

How particles can move on a catalyst surface that, under the conditions of an industrial process, is highly covered by adsorbates and where most adsorption sites are occupied has remained an open question. We have studied the diffusion of O atoms on a fully CO-covered Ru(0001) surface by means of high-speed/variable-temperature scanning tunneling microscopy combined with density functional theory calculations. Atomically resolved trajectories show a surprisingly fast diffusion of the O atoms, almost as fast as on the clean surface. This finding can be explained by a “door-opening” mechanism in which local density fluctuations in the CO layer intermittently create diffusion pathways on which the O atoms can move with low activation energy.

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