Homoepitaxial Growth of GaN Using Seeded Supersonic Molecular Beams

1997 ◽  
Vol 482 ◽  
Author(s):  
E. Chen ◽  
S. Zhang ◽  
A. Michel ◽  
R. F. Davis ◽  
H. H. Lamb

AbstractHomoepitaxial growth of GaN on MOCVD-grown GaN/AlN/6H-SiC substrates was investigated using NH3-seeded supersonic molecular beams and an effusive Ga source. Ga-limited growth is observed at 730 and 770°C for incident Ga fluxes ≤ 1.2×1015 cm−2 s−1 using a 0.25 eV NH3 beam. A Ga incorporation efficiency of 20–25% is observed under these conditions. Increasing NH3 kinetic energy in the 0.25 to 0.61 eV range results in a modest increase in the GaN growth rate which we ascribe to an enhancement in NH3 reactivity. A concomitant increase in surface roughness is observed with increasing GaN growth rate.

2001 ◽  
Vol 494 (1) ◽  
pp. 28-42 ◽  
Author(s):  
A.J. McGinnis ◽  
D. Thomson ◽  
R.F. Davis ◽  
E. Chen ◽  
A. Michel ◽  
...  

1998 ◽  
Vol 512 ◽  
Author(s):  
A. Michel ◽  
E. Chen ◽  
D. Thomson ◽  
O. Nam ◽  
R. F. Davis ◽  
...  

ABSTRACTIn situ cleaning of MOCVD-grown GaN/AlN/6H-SiC substrates using NH3-seeded supersonic molecular beams was investigated. Removal of surface carbon and oxygen contaminants was achieved by heating at 730°C under a hyperthermal NH 3 beam. Oxygen is removed primarily by thermal desorption; however, carbon removal requires an NH3 flux. Atomically smooth surfaces with regular steps are obtained after NH3 beam cleaning. Homoepitaxial growth of smooth, highly textured GaN films was accomplished at 700°C by employing a 0.61-eV NH3 beam and an effusive Ga source.


2011 ◽  
Vol 679-680 ◽  
pp. 115-118 ◽  
Author(s):  
Jawad ul Hassan ◽  
Peder Bergman ◽  
Anne Henry ◽  
Erik Janzén

The effect of different C/Si ratio on the surface morphology has been studied to optimize the on-axis homoepitaxial growth conditions on 4H-SiC substrates to improve the surface roughness of epilayers. The overall surface roughness is found to decrease with decreasing C/Si ratio. An order of magnitude lower surface roughness has been observed using C/Si ratio = 0.8 without disturbing the polytype stability in the epilayer. A high growth rate of 10 µm/h was achieved without introducing 3C inclusions. The epilayers grown at higher growth rate with C/Si ratio = 1 also had improvements in the surface roughness. 100% 4H polytype was maintained in the epilayers grown with C/Si ratio in the range of 1.2 to 0.8 and with high growth rate of 10 µm/h.


RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 37982-37993 ◽  
Author(s):  
Roberta Tatti ◽  
Lucrezia Aversa ◽  
Roberto Verucchi ◽  
Emanuele Cavaliere ◽  
Giovanni Garberoglio ◽  
...  

High kinetic energy impacts between inorganic surfaces and molecular beams seeded by organics represent a fundamental tool in materials science, particularly when they activate chemical–physical processes leading to nanocrystals' growth.


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