The Effects of Near Surface and Bulk Microstructure on Lithium Intercalation of Disordered, “Hard” Carbons

1997 ◽  
Vol 496 ◽  
Author(s):  
William R. Even ◽  
Lawrence W. Peng ◽  
Nancy Yang ◽  
Ronald Guidotti ◽  
Thomas Headley

ABSTRACTDisordered carbons were synthesized at 700°C from methacrylonitrile-divinylbenzene precursors. The disorder, even at the free surface, was confirmed with TAM. These powdered carbons were subjected to rapid surface heating by a pulsed infrared laser. While the bulk structure remained essentially unchanged, there was substantial surface reconstruction to a depth of 0.25μm after heating (5.9 W average power at 10Hz, 10 ns pulse width, 1064nm wavelength). The surface ordering appears similar to the bulk microstructure of carbons isothermally annealed at 2,200°C (i.e., turbostratic). Improvements were observed in first cycle irreversible loss, rate capability, and coulombic efficiencies of the reconstructed carbons, relative to the untreated carbon.

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 826
Author(s):  
Muhammad Waqas Qureshi ◽  
Xinxin Ma ◽  
Guangze Tang ◽  
Bin Miao ◽  
Junbo Niu

The high-power impulse magnetron sputtering (HiPIMS) technique is widely used owing to the high degree of ionization and the ability to synthesize high-quality coatings with a dense structure and smooth morphology. However, limited efforts have been made in the deposition of MAX phase coatings through HiPIMS compared with direct current magnetron sputtering (DCMS), and tailoring of the coatings’ properties by process parameters such as pulse width and frequency is lacking. In this study, the Cr2AlC MAX phase coatings are deposited through HiPIMS on network structured TiBw/Ti6Al4V composite. A comparative study was made to investigate the effect of average power by varying frequency (1.2–1.6 kHz) and pulse width (20–60 μs) on the deposition rate, microstructure, crystal orientation, and current waveforms of Cr2AlC MAX phase coatings. X-ray diffraction (XRD), scanning electron microscopy (SEM), and atomic force microscopy (AFM) were used to characterize the deposited coatings. The influence of pulse width was more profound than the frequency in increasing the average power of HiPIMS. The XRD results showed that ex situ annealing converted amorphous Cr-Al-C coatings into polycrystalline Cr2AlC MAX phase. It was noticed that the deposition rate, gas temperature, and roughness of Cr2AlC coatings depend on the average power, and the deposition rate increased from 16.5 to 56.3 nm/min. Moreover, the Cr2AlC MAX phase coatings produced by HiPIMS exhibits the improved hardness and modulus of 19.7 GPa and 286 GPa, with excellent fracture toughness and wear resistance because of dense and column-free morphology as the main characteristic.


Author(s):  
Yangyu Liu ◽  
Xue Cao ◽  
AnHua Xian ◽  
Guangmiao Liu ◽  
Wei zhou ◽  
...  

Abstract We demonstrate stable continuous-wave mode-locking (CWML) pulses around 1645nm by employing the home-made Er:YAG ceramic. By using a fiber laser and semiconductor saturable absorber mirror (SESAM) with modulation depth of 1.2%, we get ML pulses with the output average power up to 815 mW, the pulse width shortened as ~4 ps, and the peak power of 1.8 kW. With the SESAM of modulation depth of 2.4%, the second-order harmonic ML pulses were also obtained. As far as we know, this is the first report of CWML from Er3+-doped ceramics and also the shortest pulse duration in Er3+-doped solid-state oscillators.


1990 ◽  
Vol 80 (6B) ◽  
pp. 2032-2052 ◽  
Author(s):  
D. C. Jepsen ◽  
B. L. N. Kennett

Abstract Both phased array techniques for single-component sensors and vectorial analysis of three-component recordings can provide estimates of the azimuth and slowness of seismic phases. However, a combination of these approaches provides a more powerful tool to estimate the propagation characteristics of different seismic phases at regional distances. Conventional approaches to the analysis of three-component seismic records endeavor to exploit the apparent angles of propagation in horizontal and vertical planes as well as the polarization of the waves. The basic assumption is that for a given time window there is a dominant wavetype (e.g., a P wave) traveling in a particular direction arriving at the seismic station. By testing a range of characteristics of the three-component records, a set of rules can be established for classifying much of the seismogram in terms of wavetype and direction. It is, however, difficult to recognize SH waves in the presence of other wavetypes. Problems also arise when more than one signal (in either wavetype or direction) arrive in the same window. The stability and robustness of the classification scheme is much improved when records from an array of three-component sensors are combined. For a set of three-component instruments forming part of a larger array, it is possible to estimate the slowness and azimuth of arrivals from the main array and then extract the relative proportions of the current P-, SV-, and SH-wave contributions to the seismogram. This form of wavetype decomposition depends on a model of near-surface propagation. A convenient choice for hard-rock sites is to include just the effect of the free surface, which generates a frequency-independent operation on the three-component seismograms and which is not very sensitive to surface velocities. This approach generates good estimates of the character of the S wavefield, because the phase distortion of SV induced by the free surface can be removed. The method has been successfully applied to regional seismograms recorded at the medium aperture Warramunga array in northern Australia, and the two small arrays NORESS and ARCESS in Norway, which were designed for studies of regional phases. The new wavefield decomposition scheme provides results in which the relative proportions of P, SV, and SH waves as a function of time can be compared without the distortion imposed by free surface amplification. Such information can provide a useful adjunct to existing measures of signal character used in source discrimination.


1975 ◽  
Vol 97 (4) ◽  
pp. 270-277 ◽  
Author(s):  
W. G. Gibbons ◽  
W. R. Andrews ◽  
G. A. Clarke

A testing program has been run using off-centered-cracked (OCC) plate specimens to demonstrate the fracture characteristics of tunnel defects in specimens with various ligament lengths between the near surface crack tip and a free surface. Measured strain values and the fracture results compared favorably with theory up to the limits of the analyses. An empirical equation which calculates the near surface stress intensity provides extended calculational capabilities. In addition, fatigue crack growth and fracture velocities plus fracture toughness were measured for a Cr-Mo-V steel.


2011 ◽  
Vol 48 (11) ◽  
pp. 111403
Author(s):  
李欣荣 Li Xinrong ◽  
孙琦 Sun Qi

2007 ◽  
Vol 329 ◽  
pp. 557-562
Author(s):  
Hiroshi Matsuura ◽  
Yasuhiro Kunieda ◽  
Nobuhito Yoshihara ◽  
Tsunemoto Kuriyagawa

A Nd:YAG crystal having a special structure achieved laser operation with an extinction ratio of over 20 dB, a CW (continuous wave) average power of 6 W, a pulse width of 50 ns, and repetition rates in the range 1 kHz – 10 kHz for an output wavelength of 1064 nm for effectively cooling the crystal for the case of laser dressing. The birefringence induced by the stress applied to the crystal results in the production of elliptical polarization before the Brewster-window and thus decreases the laser efficiency. In this paper, we analyzed the relationship between the distortion and the birefringence in a Nd:YAG crystal and the resulting effect on the laser power.


2019 ◽  
Vol 534 ◽  
pp. 31-36 ◽  
Author(s):  
Frederik Lipfert ◽  
Michael Kerscher ◽  
Stefan Mattauch ◽  
Henrich Frielinghaus

1973 ◽  
Vol 36 (4) ◽  
pp. 730-733 ◽  
Author(s):  
J. E. Madigan ◽  
J. W. Evans
Keyword(s):  

1974 ◽  
Vol 25 (2) ◽  
pp. 363 ◽  
Author(s):  
FB Roseby ◽  
RA Leng

The effect of infection with Trichostrongylus colubriformis on the rates of production, excrehon and recycling of urea was studied in 24 Merino lambs. The production rate of urea was estimated as the irreversible loss rate of [14C]urea given as a single injection. The feed intake of all sheep was maintained at 540 g/day throughout the experiment. Parasitized sheep had a higher plasma urea concentration than their paired controls 15–35 days after they were infected. This was associated with an increase in the rate of irreversible loss and the rate of urinary excretion of urea. The additional urea lost in urine is apparently produced from ammonia released from amino acids in the tissues or in the digestive tract. ______________________ *Part I, Aust. J. Agric. Res., 24: 947 (1973).


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