On the interface quality of MIS structures fabricated from Atomic Layer Deposition of HfO2, Ta2O5 and Nb2O5−Ta2O5−Nb2O5 dielectric thin films

2003 ◽  
Vol 786 ◽  
Author(s):  
S. Dueñas ◽  
H. Castán ◽  
H. García ◽  
J. Barbolla ◽  
K. Kukli ◽  
...  

ABSTRACTA study of metal-insulator-semiconductor (MIS) structures based on atomic layer deposited HfO2, Ta2O5 and Nb2O5−Ta2O5−Nb2O5 thin films is presented. Our attention was focussed on interface quality and defect density in the dielectric. Interface states as well as defects inside the insulator bulk were measured by using capacitance-voltage (C-V), deep level transient spectroscopy (DLTS) and conductance transient (G-t) techniques. Nb2O5−Ta2O5−Nb2O5 based capacitors exhibit the highest interface state density, whereas the minimum is obtained for HfO2. Conductance transients are not observed in Al/HfO2/SiO2/Si stacks, thus indicating that disordered induced gap states (DIGS) are not present in these structures. We also observed that post-metallization annealing in forming gas diminishes the trap interface density at the expense of increasing DIGS in the Al/HfO2/Si cases.

2018 ◽  
Vol 924 ◽  
pp. 289-292
Author(s):  
Yuji Yamagishi ◽  
Yasuo Cho

We demonstrate our new local deep level spectroscopy system improved for more accurate analysis of trap states at SiO2/4H-SiC interfaces. Full waveforms of the local capacitance transient with the amplitude of attofarads and the time scale of microseconds were obtained and quantitatively analyzed. The local energy distribution of interface state density in the energy range of EC − Eit = 0.31–0.38 eV was obtained. Two-dimensional mapping of the interface states showed inhomogeneous contrasts with the lateral spatial scale of several hundreds of nanometers, suggesting that the physical origin of the trap states at SiO2/SiC interfaces is likely to be microscopically clustered.


1991 ◽  
Vol 69 (9) ◽  
pp. 6521-6525 ◽  
Author(s):  
N. C. Halder ◽  
H. W. Kim ◽  
K. M. D’Souza ◽  
D. E. Barnes ◽  
S. E. Hartson ◽  
...  

2019 ◽  
Vol 963 ◽  
pp. 469-472 ◽  
Author(s):  
Teruaki Kumazawa ◽  
Mitsuo Okamoto ◽  
Miwako Iijima ◽  
Yohei Iwahashi ◽  
Shinji Fujikake ◽  
...  

The SiO2/SiC interface quality has a significant effect on the performance of 4H-SiC MOS devices. The introduction of nitrogen to the SiO2/SiC interface is a well-known method for reducing the interface state density (Dit). In this study, we introduced nitrogen to the SiO2/SiC interface by forming SiNx films using atomic layer deposition (ALD) and thus improved the interface quality. O2 annealing with a SiNx interface layer of optimal thickness enhanced the field effect mobility.


2016 ◽  
Vol 858 ◽  
pp. 689-692 ◽  
Author(s):  
Yu Cheng Wang ◽  
Yu Ming Zhang ◽  
Ren Xu Jia

SiO2 with varying thickness (0, 4.45, and 8.05 nm) were grown on n type 4H-SiC epilayer by thermal oxidation and La2O3 were stacked on them using atomic layer deposition (ALD). The La2O3/SiO2/4H-SiC metal-oxide-semiconductor (MOS) capacitors were analyzed by X-ray photoelectron spectroscopy (XPS) and capacitance-voltage (C-V) measurements. C-V curves show that introducing an ultrathin SiO2 can reduce the effect of lattice mismatch of La2O3/4H-SiC structure and then improve interface property. However, the interface quality is reduced as SiO2 was grown thicker. XPS data show that more carbon cluster remains at the interfacial between SiO2 and 4H-SiC as the oxidation time increases.


2004 ◽  
Vol 808 ◽  
Author(s):  
M. Zeman ◽  
V. Nádazdy ◽  
J.W. Metselaar

ABSTRACTComputer simulations of single-junction hydrogenated amorphous silicon (a-Si:H) solar cells with different thickness of the intrinsic layer were carried out in order to study the role of charge gap states in their light-induced degradation. It is demonstrated that it is the decrease of positively charged states above midgap, Dh, and the increase of neutral states around midgap,Dz, and negatively charged states below midgap, De in the intrinsic layer that result in a drop of performance of the solar cells due to light soaking. These changes in the gap states are in accordance with our recent experimental results from the charge deep-level transient spectroscopy on undoped a-Si:H. The experimentally observed changes in the dark and illuminated J-V curves and spectral response could not be simulated with the same set of input parameters by only increasing the defect-state density in the intrinsic layer.


1991 ◽  
Vol 240 ◽  
Author(s):  
Z. Q. Shi ◽  
R. L. Wallace ◽  
W. A. Anderson

ABSTRACTThe barrier height of a Pd/n-InP diode was found to be increased from 0.48 to 0.96eV with the substrate temperature decreased from 300 to 77K during metal deposition. The leakage current density was reduced by more than six order of magnitude. It is obvious that the interface Fermi-level position lies well outside the variance associated with Fermi-level pinning. The barrier height for the Au/n-GaAs diode was found to be increased by about 0.25 eV with low temperature deposition and the leakage current reduced by more than five orders of magnitude. The mechanism responsible for the ultrahigh barrier height obtained at low substrate temperature was investigated by Raman spectroscopy, current voltage temperature measurement, deep level transient spectroscopy, and electroreflectance technique. The metal-insulator-semiconductor (MIS)-like structure formed at low substrate temperature and the reduction of interface state density may be the main reason for the dramatic enhancement of Schottky barrier height.


2013 ◽  
Vol 740-742 ◽  
pp. 477-480 ◽  
Author(s):  
Tetsuo Hatakeyama ◽  
T. Shimizu ◽  
T. Suzuki ◽  
Y. Nakabayashi ◽  
Hajime Okumura ◽  
...  

Constant-capacitance deep-level-transient spectroscopy (CCDLTS) characterization of traps (or states) in SiO2/SiC interfaces on the C-face was carried out to clarify the cause of low-channel mobility of SiC MOSFETs. CCDLTS measurements showed that the interface-state density (Dit) near the conduction band of SiO2/SiC interfaces fabricated using N2O oxidation was much higher than that of SiO2/SiC interfaces fabricated using wet oxidation. The high density of interface states near the conduction band is likely to be the main cause of the low mobility of MOSFETs fabricated using N2O oxidation.


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