scholarly journals The mechanical response of micron-sized molecular crystals

MRS Advances ◽  
2021 ◽  
Vol 6 (27) ◽  
pp. 674-681
Author(s):  
Christopher M. Barr ◽  
Marcia Cooper ◽  
Jeremy Lechman ◽  
Daniel C. Bufford
Keyword(s):  
Molecular Crystal ◽  
Experimental Approach ◽  
Mechanical Response ◽  
Particle Interactions ◽  
Simultaneous Imaging ◽  
Particle Level ◽  
Compaction Processes ◽  
Individual Particles ◽  
Selection Of

AbstractMicrostructures and corresponding properties of compacted powders ultimately depend on the mechanical response of individual particles. In principle, computational simulations can predict the results of powder compaction processes, but the selection of appropriate models for both particle–particle interactions and particle deformations across all relevant length scales remain nontrivial tasks, especially in material systems lacking detailed mechanical property information. The work presented here addresses these issues by conducting uniaxial compressions in situ inside of a scanning electron microscope to characterize the mechanical response of individual micron-sized particles of a molecular crystal, hexanitrohexaazaisowurtzitane (CL-20). This experimental approach enabled the collection of quantitative force and displacement data alongside simultaneous imaging to capture morphology changes. The results reveal information about elastic deformation, yield, plastic deformation, creep, and fracture phenomena. Accordingly, this work demonstrates a generalizable approach for assessing the mechanical response of individual micron-sized molecular crystal particles and utilizing those responses in particle-level models. Graphic abstract

scholarly journals Development of a Nanoindenter for In Situ Transmission Electron Microscopy

2001 ◽  
Vol 7 (6) ◽  
pp. 507-517 ◽  
Author(s):  
Eric A. Stach ◽  
Tony Freeman ◽  
Andrew M. Minor ◽  
Doug K. Owen ◽  
John Cumings ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Mechanical Response ◽  
Dislocation Motion ◽  
Scanning Tunneling ◽  
Nanometer Scale ◽  
Simultaneous Imaging ◽  
Technical Requirements ◽  
Transmission Electron

AbstractIn situ transmission electron microscopy is an established experimental technique that permits direct observation of the dynamics and mechanisms of dislocation motion and deformation behavior. In this article, we detail the development of a novel specimen goniometer that allows real-time observations of the mechanical response of materials to indentation loads. The technology of the scanning tunneling microscope is adopted to allow nanometer-scale positioning of a sharp, conductive diamond tip onto the edge of an electron-transparent sample. This allows application of loads to nanometer-scale material volumes coupled with simultaneous imaging of the material’s response. The emphasis in this report is qualitative and technique oriented, with particular attention given to sample geometry and other technical requirements. Examples of the deformation of aluminum and titanium carbide as well as the fracture of silicon will be presented.

In situ nanoscale visualization of solvent effects on molecular crystal surfaces

CrystEngComm ◽  
2021 ◽  
Author(s):  
Mikkel Herzberg ◽  
Anders Støttrup Larsen ◽  
Tue Hassenkam ◽  
Anders Østergaard Madsen ◽  
Jukka Rantanen
Keyword(s):  
Solid Solution ◽  
Solvent Effects ◽  
Molecular Crystal ◽  
Rational Design ◽  
Molecular Level ◽  
Molecular Crystals ◽  
Crystal Surfaces ◽  
Solution Interface ◽  
Atomic Force

Solvents can dramatically affect molecular crystals. Obtaining favorable properties for these crystals requires rational design based on molecular level understanding of the solid-solution interface. Here we show how atomic force...

scholarly journals Discrete element analysis of the punching behaviour of a secured drapery system: from laboratory characterization to idealized in situ conditions

2021 ◽  
Author(s):  
Antonio Pol ◽  
Fabio Gabrieli ◽  
Lorenzo Brezzi
Keyword(s):  
Mechanical Response ◽  
Steel Wire ◽  
Discrete Element ◽  
Wire Mesh ◽  
Steel Plates ◽  
Loading Conditions ◽  
Element Analysis ◽  
In Situ Conditions ◽  
Wire Meshes

AbstractIn this work, the mechanical response of a steel wire mesh panel against a punching load is studied starting from laboratory test conditions and extending the results to field applications. Wire meshes anchored with bolts and steel plates are extensively used in rockfall protection and slope stabilization. Their performances are evaluated through laboratory tests, but the mechanical constraints, the geometry and the loading conditions may strongly differ from the in situ conditions leading to incorrect estimations of the strength of the mesh. In this work, the discrete element method is used to simulate a wire mesh. After validation of the numerical mesh model against experimental data, the punching behaviour of an anchored mesh panel is investigated in order to obtain a more realistic characterization of the mesh mechanical response in field conditions. The dimension of the punching element, its position, the anchor plate size and the anchor spacing are varied, providing analytical relationships able to predict the panel response in different loading conditions. Furthermore, the mesh panel aspect ratio is analysed showing the existence of an optimal value. The results of this study can provide useful information to practitioners for designing secured drapery systems, as well as for the assessment of their safety conditions.

scholarly journals Crystalline shielding mitigates structural rearrangement and localizes memory in jammed systems under oscillatory shear

2021 ◽  
Vol 7 (20) ◽  
pp. eabe3392
Author(s):  
Erin G. Teich ◽  
K. Lawrence Galloway ◽  
Paulo E. Arratia ◽  
Danielle S. Bassett
Keyword(s):  
Local Structure ◽  
Disordered Systems ◽  
Amorphous Materials ◽  
Structural Rearrangement ◽  
Oscillatory Shear ◽  
Disordered Materials ◽  
Rheological Measurements ◽  
Particle Level ◽  
Individual Particles

The nature of yield in amorphous materials under stress has yet to be fully elucidated. In particular, understanding how microscopic rearrangement gives rise to macroscopic structural and rheological signatures in disordered systems is vital for the prediction and characterization of yield and the study of how memory is stored in disordered materials. Here, we investigate the evolution of local structural homogeneity on an individual particle level in amorphous jammed two-dimensional (athermal) systems under oscillatory shear and relate this evolution to rearrangement, memory, and macroscale rheological measurements. We define the structural metric crystalline shielding, and show that it is predictive of rearrangement propensity and structural volatility of individual particles under shear. We use this metric to identify localized regions of the system in which the material’s memory of its preparation is preserved. Our results contribute to a growing understanding of how local structure relates to dynamic response and memory in disordered systems.

Evaluating the Mechanical Behavior of 316 Stainless Steel at the Microscale Using Finite Element Modelling and In-Situ Neutron Scattering

2010 ◽  
Author(s):  
Dong-Feng Li ◽  
Noel P. O’Dowd ◽  
Catrin M. Davies ◽  
Shu-Yan Zhang
Keyword(s):  
Finite Element ◽  
Stainless Steel ◽  
Finite Element Modelling ◽  
Mechanical Response ◽  
Fe Model ◽  
Lattice Strains ◽  
Crystallographic Slip ◽  
In Situ Neutron Diffraction ◽  
Elastic Lattice

In this study, the deformation behavior of an austenitic stainless steel is investigated at the microscale by means of in-situ neutron diffraction (ND) measurements in conjunction with finite-element (FE) simulations. Results are presented in terms of (elastic) lattice strains for selected grain (crystallite) families. The FE model is based on a crystallographic (slip system based) representation of the deformation at the microscale. The present study indicates that combined in-situ ND measurement and micromechanical modelling provides an enhanced understanding of the mechanical response at the microscale in engineering steels.

Role of Interfacial Interactions on Mechanical Properties of Biomimetic Composites for Bone Tissue Engineering

2005 ◽  
Vol 898 ◽  
Author(s):  
Devendra Verma ◽  
Rahul Bhowmik ◽  
Bedabibhas Mohanty ◽  
Dinesh R Katti ◽  
Kalpana S Katti
Keyword(s):  
Mechanical Properties ◽  
Tissue Engineering ◽  
Bone Tissue Engineering ◽  
Bone Tissue ◽  
Mechanical Response ◽  
Density Ratio ◽  
Interfacial Interactions ◽  
Porous Composites ◽  
Properties Of Composites

AbstractInterfaces play an important role in controlling the mechanical properties of composites. Optimum mechanical strength of scaffolds is of prime importance for bone tissue engineering. In the present work, molecular dynamics simulations and experimental studies have been conducted to study effect of interfacial interactions on mechanical properties of composites for bone replacement. In order to mimic biological processes, hydroxyapatite (HAP) is mineralized in presence of polyacrylic acid (PAAc) (in situ HAP). Further, solid and porous composites of in situ HAP with polycaprolactone (PCL) are made. Mechanical tests of composites of in situ HAP with PAAc have shown improved strain recovery, higher modulus/density ratio and also improved mechanical response in simulated body fluid (SBF). Simulation studies indicate potential for calcium bridging between –COO− of PAAc and surface calcium of HAP. This fact is also supported by infrared spectroscopic studies. PAAc modified surfaces of in situ HAP offer means to control the microstructure and mechanical response of porous composites. Nanoindentation experiments indicate that apatite grown on in situ HAP/PCL composites from SBF has improved elastic modulus and hardness. This work gives insight into the interfacial mechanisms responsible for mechanical response as well as bioactivity in biomaterials.

Suitability of Natural Geomedia for Radwaste Storage

1982 ◽  
Vol 15 ◽  
Author(s):  
W. S. Fyfe
Keyword(s):  
Rock Properties ◽  
Fracture Flow ◽  
Time Prediction ◽  
Sedimentary Sequences ◽  
Rock Types ◽  
Direct Observations ◽  
Long Time ◽  
Mining Disturbance ◽  
Selection Of

ABSTRACTSelection of the best rock types for radwaste disposal will depend on their having minimal permeability, maximal flow dispersion, minimal chance of forming new wide aperture fractures, maximal ion retention, and minimal thermal and mining disturbance. While no rock is perfect, thinly bedded complex sedimentary sequences may have good properties, either as repository rocks, or as cover to a repository.Long time prediction of such favorable properties of a rock at a given site may be best modelled from studies of in situ rock properties. Fracture flow, dispersion history, and geological stability can be derived from direct observations of rocks themselves, and can provide the parameters needed for convincing demonstration of repository security for appropriate times.

Magnetised Wave Collapse in Solar System Plasmas

1993 ◽  
Vol 10 (4) ◽  
pp. 283-286 ◽  
Author(s):  
Andrew Melatos ◽  
Peter Robinson
Keyword(s):  
Solar System ◽  
Wave Packets ◽  
Particle Interactions ◽  
Coherent Wave ◽  
Wave Collapse ◽  
Non Linear ◽  
Acceleration Zone ◽  
The Waves ◽  
Linear Plasma

AbstractClumpy, intense wave packets observed in situ in the Jovian and terrestrial electron foreshocks, and in the Earth’s auroral acceleration zone, point to the existence of non-linear plasma turbulence in these regions. In non-linear turbulence, wave packets collapse to short scales and high fields, stopping only when coherent wave-particle interactions efficiently dissipate the energy in the waves. The purpose of this paper is to examine the shortest scales and highest fields achieved during collapse in a strongly magnetised plasma, and identify parts of the solar system where the magnetised aspects of wave collapse are important.

Estimating thermo-osmotic coefficients in clay-rocks: II. In situ experimental approach

2010 ◽  
Vol 342 (1) ◽  
pp. 175-184 ◽  
Author(s):  
J. Trémosa ◽  
J. Gonçalvès ◽  
J.M. Matray ◽  
S. Violette
Keyword(s):  
Experimental Approach ◽  
Osmotic Coefficients ◽  
Clay Rocks

A Theoretical and Experimental Approach to E-pH Diagram for the Niobium-Water System

CORROSION ◽  
10.5006/3871 ◽  
2021 ◽  
Author(s):  
Rodney Santandrea ◽  
Simone BRASIL ◽  
Leila Reznik ◽  
Ladimir Carvalho ◽  
Luiz Miranda
Keyword(s):  
Experimental Approach ◽  
Ph Monitoring ◽  
Aqueous Media ◽  
Water System ◽  
Chemical Species ◽  
Polarization Curves ◽  
Buffer Solutions ◽  
Excellent Corrosion Resistance ◽  
Experimental Diagram ◽  
Selection Of

E-pH diagrams are usually built from thermodynamic databases available in the literature or from specific software. However, depending on the conditions and the chemical species defined for elaborating a diagram, it may present completely different immunity, passivation, and corrosion domains. In order to obtain a result closer to a real system, experimental E-pH diagrams can be built from polarization curves obtained in the evaluated conditions. This work discloses the construction of a diagram for the Nb-H<sub>2</sub>O system at 25°C from theoretical study and the specific selection of chemical species in the solutions through computer simulations. The polarization curves for the construction of the experimental diagram were gathered without the use of buffer solutions and under pH monitoring in the solution bulk throughout all assays. The methodology proposed was considered adequate since, from experimental data, a final result compatible with the classic diagram for the Nb-H<sub>2</sub>O system and the excellent corrosion resistance of niobium in aqueous media were achieved.

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