scholarly journals Characterization and Comparative Analysis of Corrosion Resistance of 4 High Manganese Steels Models in Aqueous Solution of NaCl

2019 ◽  
Vol 22 (suppl 1) ◽  
Author(s):  
Mauro Andres Cerra Florez ◽  
Marcos Natan da Silva Lima ◽  
Walney Silva Araújo ◽  
Marcelo José Gomes da Silva
Author(s):  
Mauro Andres Cerra Florez ◽  
Jorge Luiz Cardoso ◽  
Hamilton Ferreira Gomes de Abreu ◽  
Walney Silva Araújo ◽  
Marcelo José Gomes da Silva

Abstract The present study aims to establish a comparison of corrosion resistance between four (non-commercial) high manganese steel models in relation to 9% nickel steel in an aqueous solution of H2SO4. High manganese steels have emerged as an alternative material for the manufacture of equipment for the storage and transportation of liquefied petroleum gas due to their mechanical properties and mainly for the lower cost compared to 9% nickel steel. The electrochemical techniques used were open circuit potential, linear polarization and electrochemical impedance spectroscopy. The results obtained by these techniques have helped to understand the phenomena that produce a lower corrosion resistance of high manganese steels when compared to 9% nickel steel in aqueous solutions.


CORROSION ◽  
1970 ◽  
Vol 26 (12) ◽  
pp. 511-528 ◽  
Author(s):  
MICHAEL HENTHORNE

Abstract The influence of manganese (0.3 to 2.4%), sulfur (0.01 to 0.4%), sulfide composition, and heat treatment on the corrosion resistance of 13% chromium, 17% chromium and 18% chromium-9% nickel steels has been investigated. Corrosion in acid solutions, high humidity, and salt spray is dependent upon sulfide composition which in turn is determined by the manganese to sulfur ratio in the steel. Low manganese resulfurized stainless steels which contain chromium rich sulfides are inherently more corrosion resistant than high manganese steels containing manganese rich sulfides. The influence of heat treatment on the corrosion resistance of resulfurized steels is similar to that for residual sulfur grades. Sulfide composition also controls the behavior of these steels during nitric acid passivation treatments. Highly oxidizing solutions must be used to avoid attack during these treatments particularly for steels with high manganese to sulfur ratios. These solutions do not dissolve the commonly used tool steels (particles of which might be imbedded in the surface of a machined part) but can improve subsequent corrosion resistance by removing deleterious manganese rich sulfides. These improvements are most marked in the high manganese 13% chromium alloys. Passivation treatments can increase the corrosion susceptibility of cross section areas in low manganese resulfurized stainless steels.


2019 ◽  
Vol 50 (12) ◽  
pp. 5760-5766 ◽  
Author(s):  
Madhumanti Bhattacharyya ◽  
Yves Brechet ◽  
Gary R. Purdy ◽  
Hatem S. Zurob

Metals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 24
Author(s):  
Matías Bordone ◽  
Juan Perez-Ipiña ◽  
Raúl Bolmaro ◽  
Alfredo Artigas ◽  
Alberto Monsalve

This article is focused on the mechanical behavior and its relationship with the microstructural changes observed in two high-manganese steels presenting twinning-induced plasticity (TWIP) and transformation-induced plasticity (TRIP), namely Steel B and Steel C, respectively. Chemical compositions were similar in manganese, but carbon content of Steel B approximately doubles Steel C, which directly impacted on the stacking fault energy (SFE), microstructure and mechanical response of each alloy. Characterization of as-cast condition by optical microscope revealed a fully austenitic microstructure in Steel B and a mixed microstructure in Steel C consisting of austenite grains and thermal-induced (εt) martensite platelets. Same phases were observed after the thermo-mechanical treatment and tensile tests, corroborated by means of X-Ray Diffraction (XRD), which confirms no phase transformation in Steel B and TRIP effect in Steel C, due to the strain-induced γFCC→εHCP transformation that results in an increase in the ε-martensite volume fraction. Higher values of ultimate tensile strength, yield stress, ductility and impact toughness were obtained for Steel B. Significant microstructural changes were revealed in tensile specimens as a consequence of the operating hardening mechanisms. Scanning Electron Microscopy (SEM) observations on the tensile and impact test specimens showed differences in fracture micro-mechanisms.


2018 ◽  
Vol 63 (2) ◽  
pp. 491-499
Author(s):  
Benjamin Wittig ◽  
Manuela Zinke ◽  
Sven Jüttner ◽  
Daniel Keil

Sign in / Sign up

Export Citation Format

Share Document