scholarly journals Equalization principles in open subsystems, origins of information descriptors and state-continuity relations

2021 ◽  
pp. 004-021
Author(s):  
Nalewajski Roman F

The electronegativity-equalization at several hypothetical stages of chemical reactions is reexamined and phase-equalization in open substrates is explored. The equivalence of the energy and information reactivity criteria is stressed and local energy concept is shown to determine time-evolutions of wavefunction components. Independent sources of information content in electronic states are identifi ed and the need for resultant entropy-information measures in quantum mechanics, combining information contributions due to the classical (probability) and nonclassical (phase/current) distributions, is reemphasized. Limitations for a simultaneous removal of uncertainties in the position and velocity distributions imposed by the Heisenberg indeterminacy principle, are discussed, continuities of the wavefunction modulus and phase components are examined, the convectional character of the local source of resultant gradient information is stressed, and a latent (“horizontal”) probability currents in the stationary quantum states are discussed.

Entropy ◽  
2021 ◽  
Vol 23 (4) ◽  
pp. 483
Author(s):  
Roman F. Nalewajski

In this article, sources of information in electronic states are reexamined and a need for the resultant measures of the entropy/information content, combining contributions due to probability and phase/current densities, is emphasized. Probability distribution reflects the wavefunction modulus and generates classical contributions to Shannon’s global entropy and Fisher’s gradient information. The phase component of molecular states similarly determines their nonclassical supplements, due to probability “convection”. The local-energy concept is used to examine the phase equalization in the equilibrium, phase-transformed states. Continuity relations for the wavefunction modulus and phase components are reexamined, the convectional character of the local source of the resultant gradient information is stressed, and latent probability currents in the equilibrium (stationary) quantum states are related to the horizontal (“thermodynamic”) phase. The equivalence of the energy and resultant gradient information (kinetic energy) descriptors of chemical processes is stressed. In the grand-ensemble description, the reactivity criteria are defined by the populational derivatives of the system average electronic energy. Their entropic analogs, given by the associated derivatives of the overall gradient information, are shown to provide an equivalent set of reactivity indices for describing the charge transfer phenomena.


2020 ◽  
pp. 106-115
Author(s):  
Roman F. Nalewajski

The need for resultant measures of the Information-Theoretic (IT) content of molecular electronic wavefunctions, combining the information contributions due to the probability and phase/current distributions, is reemphasized. Complementary measures of the state entropy (disorder) and information (order) contents are reexamined, the continuities of wavefunction components are summarized, and the probability acceleration concept is used to determine the current and information sources. The experimental elimination of the state uncertainties is discussed and limitations in this information-acquirement process imposed by the Heisenberg indeterminacy principle are commented upon.


1990 ◽  
Vol 1 (1) ◽  
pp. 55-63 ◽  
Author(s):  
Dominic W. Massaro ◽  
Michael M. Cohen

The research reported in this paper uses novel stimuli to study how speech perception is influenced by information presented to ear and eye. Auditory and visual sources of information (syllables) were synthesized and presented in isolation or in factorial combination. A five-step continuum between the syllables ibal and idal was synthesized along both auditory and visual dimensions, by varying properties of the syllable at its onset. The onsets of the second and third formants were manipulated in the audible speech. For the visible speech, the shape of the lips and the jaw position at the onset of the syllable were manipulated. Subjects’ identification judgments of the test syllables presented on videotape were influenced by both auditory and visual information. The results were used to test between a fuzzy logical model of speech perception (FLMP) and a categorical model of perception (CMP). These tests indicate that evaluation and integration of the two sources of information makes available continuous as opposed to just categorical information. In addition, the integration of the two sources appears to be nonadditive in that the least ambiguous source has the largest impact on the judgment. The two sources of information appear to be evaluated, integrated, and identified as described by the FLMP-an optimal algorithm for combining information from multiple sources. The research provides a theoretical framework for understanding the improvement in speech perception by hearing-impaired listeners when auditory speech is supplemented with other sources of information.


1977 ◽  
Vol 9 (4) ◽  
pp. 395-417 ◽  
Author(s):  
J A Walsh ◽  
M J Webber

The concepts of entropy and of information are increasingly used in spatial analysis. This paper analyses these ideas in order to show how measures of spatial distributions may be constructed from them. First, the information content of messages is examined and related to the notion of uncertainty. Then three information measures, due to Shannon, Brillouin, and Good, are derived and shown to be appropriate in analysing different spatial problems; in particular, the Shannon and Brillouin measures are extensively compared and the effects of sample size on them are investigated. The paper also develops appropriate multivariate analogues of the information measures. Finally, some comments are made on the relations between the concepts of entropy, information, and order.


Author(s):  
George D. Pappas ◽  
Jacqueline Sagen

We have been interested in the use of neural transplants mainly as a local source of neuroactive substances, rather than as a replacement for damaged neural circuities. In particular, we have been exploring the possibilities of reducing pain by transplants of opioid peptide producing cells, and reducing depression by transplants of monoamine-producing cells. For the past several years, work in our laboratory has demonstrated in both acute and chronic pain models that transplantation of adrenal medullary tissue or isolated chromaffin cells into CNS pain modulatory regions can reduce pain sensitivity in rodents. Chromaffin cells were chosen as donor source since they produce high levels of both opioid peptides and catecholamines, substances which independently, and probably synergistically, reduce pain sensitivity when injected locally into the spinal cord. The analgesia produced by these transplants most likely results from the release of both opioid peptides and catecholamines, since it can be blocked or attenuated by opiate or adrenergic antagonists, respectively. Furthermore, CSF levels of met-enkephalin and catecholamines are increased by the transplants.


Author(s):  
E. G. Rightor

Core edge spectroscopy methods are versatile tools for investigating a wide variety of materials. They can be used to probe the electronic states of materials in bulk solids, on surfaces, or in the gas phase. This family of methods involves promoting an inner shell (core) electron to an excited state and recording either the primary excitation or secondary decay of the excited state. The techniques are complimentary and have different strengths and limitations for studying challenging aspects of materials. The need to identify components in polymers or polymer blends at high spatial resolution has driven development, application, and integration of results from several of these methods.


2015 ◽  
Vol 22 (1) ◽  
pp. 13-21 ◽  
Author(s):  
Erinn Finke ◽  
Kathryn Drager ◽  
Elizabeth C. Serpentine

Purpose The purpose of this investigation was to understand the decision-making processes used by parents of children with autism spectrum disorder (ASD) related to communication-based interventions. Method Qualitative interview methodology was used. Data were gathered through interviews. Each parent had a child with ASD who was at least four-years-old; lived with their child with ASD; had a child with ASD without functional speech for communication; and used at least two different communication interventions. Results Parents considered several sources of information for learning about interventions and provided various reasons to initiate and discontinue a communication intervention. Parents also discussed challenges introduced once opinions of the school individualized education program (IEP) team had to be considered. Conclusions Parents of children with ASD primarily use individual decision-making processes to select interventions. This discrepancy speaks to the need for parents and professionals to share a common “language” about interventions and the decision-making process.


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