Effect of photonic processing of rutile thin films with cadmium sulfide quantum dots on the formation of conditions for the separation of nonequilibrium charge carriers

2020 ◽  
Vol 835 ◽  
pp. 374-383
Author(s):  
Zeinab Abdel Hamid ◽  
H.B. Hassan ◽  
Manal A. Hassan ◽  
M. Hussein Mourad ◽  
S. Anwar

This work deals with the deposited cadmium sulfide (CdS) quantum dots thin films on transparent conductive fluorine-doped tin oxide (FTO) substrates prepared by successive ionic layer adsorption and reaction technique (SILAR). QD deposition based on SILAR is easy, cheap and effective method which improves the surface quality and performance of QD-based devices. The effect of the number of cycles of SILAR on the morphology and size of the quantum dots has been investigated. SILAR technique was adopted for the deposition of CdS on anatase TiO2 and the three main factors contributing to the performance of QDs processed by SILAR, namely the number of cycles used, the concentration of the precursor solution, and the reaction dipping time, are discussed. The structural, morphological and optical properties were studied using X-ray diffraction (XRD), Field emission scanning electron microscope (FESEM), Raman spectra analysis and UV-Vis NIR analysis, respectively. The particle size of CdS was calculated from XRD pattern using Debye Scherrer’s equation and the calculated particle size was 4.5-9.5 nm. Using CdSQDs, quantum dot sensitized solar cells (QDSSC) were fabricated on FTO substrates as being a transparent conductive oxide. Optical absorption property proved that the band gap energy value was about 2.44 eV. The result delivered from J-V curve revealed that the overall energy conversion efficiency increased with increasing the deposition cycles giving the best efficiency of 2.73 % at 7 cycles.


2008 ◽  
Vol 42 (3) ◽  
pp. 291-297 ◽  
Author(s):  
A. S. Shkolnik ◽  
A. V. Savelyev ◽  
L. Ya. Karachinsky ◽  
N. Yu. Gordeev ◽  
R. P. Seisyan ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4439
Author(s):  
Shui-Yang Lien ◽  
Yu-Hao Chen ◽  
Wen-Ray Chen ◽  
Chuan-Hsi Liu ◽  
Chien-Jung Huang

In this study, adding CsPbI3 quantum dots to organic perovskite methylamine lead triiodide (CH3NH3PbI3) to form a doped perovskite film filmed by different temperatures was found to effectively reduce the formation of unsaturated metal Pb. Doping a small amount of CsPbI3 quantum dots could enhance thermal stability and improve surface defects. The electron mobility of the doped film was 2.5 times higher than the pristine film. This was a major breakthrough for inorganic quantum dot doped organic perovskite thin films.


Author(s):  
Jorge Reyes-Esparza ◽  
Janet Sánchez-Quevedo ◽  
Antonieta Gómez-Solís ◽  
Patricia Rodríguez-Fragoso ◽  
Gerardo González De la Cruz ◽  
...  

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