scholarly journals Calcium Carbonate Scale Formation, Prediction and Treatment (Case Study Gumry Oilfield-PDOC)

Author(s):  
A. Saifelnasr ◽  
M. Bakheit ◽  
K. Kamal ◽  
A. Lila

In this study the predictions and probabilities of calcium carbonate scale formation and corrosion occurrence inside Gumry Field Process Facilities (GFPF) and produced water injection process units (PWTP) was carried out. This was done calculating the Langelier Saturation Index (LSI), Ryznar Stability Index (RSI), Puckorius Scaling Index (PSI). The samples results for LSI index and PSI index were compared and found that all samples under threaten of calcium carbonate scale. The samples results for RSI index and found that all samples under formation of heavy calcium carbonate scale. Special excel computer program was designed to calculate the (LSI, RSI, PSI). The scale was cleaned and removed by 10% diluted hydrochloric acid and commercial scale inhibitor.

Author(s):  
L. Moriconi ◽  
T. Nascimento ◽  
B.G. B. de Souza ◽  
J.B.R. Loureiro

2019 ◽  
Vol 145 (9) ◽  
pp. 04019052 ◽  
Author(s):  
Bishow N. Shaha ◽  
Daniel E. Meeroff ◽  
Kevin Kohn ◽  
Timothy G. Townsend ◽  
John D. Schert ◽  
...  

2015 ◽  
Vol 16 (2) ◽  
pp. 445-452 ◽  
Author(s):  
Tadeusz Siwiec ◽  
Magdalena M. Michel ◽  
Lidia Reczek ◽  
Piotr Nowak

A high concentration of aggressive carbon dioxide disturbs many technological processes in water treatment. It also causes the development of corrosion in steel and concrete. De-acidification of groundwater by means of air bubbles alters pH and the concentration of aggressive carbon dioxide. This was investigated for the variables of air flow (Q = 20–50 L h−1) and height of water layer (H = 25–75 cm) as well as aeration time (t = 0–20 min). The obtained three-parameter models showed good correlation with the experimental results, except in a few cases where r2 was bigger than 0.9. Furthermore, they allow for prediction of an increase of pH and a decrease in concentration of aggressive carbon dioxide in aerated water. The effectiveness of de-acidification of groundwater was evaluated using indices of water stability (Langelier Saturation Index, Precipitation Index, Ryznar Stability Index, Aggressiveness Index and Index of Aggressiveness). Although as a result of aeration an increase of pH over 7 was observed, the non-corrosive values of the indices were not reached. This was due to a very low alkalinity of water, which was 0.7 meq L−1.


2010 ◽  
Vol 5 (No. 2) ◽  
pp. 58-68
Author(s):  
S. Kužel ◽  
L. Kolář ◽  
J. Gergel ◽  
J. Peterka ◽  
J. Borová-Batt

: In average samples of three sandy-loamy acid Cambisols from a South Bohemian area labile organic matters were determined by the permangate method modified by the dichromate method, and the rate constant of their biochemical oxidation was determined in hot water extracts of the samples. The need of liming was determined by means of 2 methods. In soil solutions of these samples, all values necessary to evaluate their calcium carbonate equilibriums were determined. The soil samples were enriched with 3% of dry matter of two organic materials, farmyard manure and meadow clover meal, and were incubated at 25&deg;C for 180 days under wetting above 50% of their retention water capacity, and after this procedure all analyses were repeated. Both methods were found to increase the need of liming in all three soils: the more labile the organic matter in 3% addition, the higher the need. The meadow clover matter was more labile than the farmyard manure matter. All three methods for the study of soil carbon lability yielded similar results while the potassium permanganate method was more sensitive than the dichromate one. Increases were observed in equilibrium [Cr(H<sub>2</sub>CO<sub>3</sub>* )] and in Langelier saturation index I<sub>s</sub>. This means that soil liming cannot be considered only as an adjustment to the soil acidity and supply of calcium to plants to meet their requirements, but also as a replacement of the spontaneous adjustment to calcium carbonate equilibrium of soil water, for which through mineralisation of labile organic matters in conditions of our experiment about 220 kg CaCO<sub>3</sub> per hectare of land were consumed on condition that it was not necessary to re-establish it. The process of Ca-compound consumption to establish the calcium carbonate equilibrium is controlled exclusively by the degree of mineralising organic matters lability while the influence of soil properties is only marginal. The same results were provided by the comparison of calcium carbonate equilibriums in nine &Scaron;umava brooks of the total watershed area 78 564 km<sup>2</sup> with the degree of lability of organic matters in their sediments in 1986, 2001 and 2004. A reduction in the intensity of agricultural production in 1986&ndash;2004 resulted in an increase in the stability of organic matters in the sediments, in a decrease in I<sub>s</sub>, and in a lower corrosivity of brooks water towards CaCO<sup>3</sup>. However, the quality of soils and their potential soil fertility decreased due to the loss of labile organic matters.


Geothermics ◽  
1989 ◽  
Vol 18 (1-2) ◽  
pp. 83-88 ◽  
Author(s):  
Evangelos Dalas ◽  
Petros G. Koutsoukos

Water ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 3428
Author(s):  
Chanbasha Basheer ◽  
Amjad A. Shaikh ◽  
Eid M. Al-Mutairi ◽  
Mokhtar Noor El Deen ◽  
Khurram Karim Qureshi

In this study, ultrasonication-assisted calcium carbonate scale inhibition was investigated compared with a commercial antiscalant ATMP (amino tris(methyl phosphonic acid)). The effects of varying ultrasound amplitude, pH, and inhibition duration were evaluated. The inhibition of calcium carbonate scale formation was measured based on the concentration of calcium in the solution after subjecting to different conditions. Scale deposits were also characterized using scanning electron microscopy and X-ray diffraction spectroscopy. Inhibition of scale formation was supported at a pH of 7 for an ultrasound amplitude of 150 W. A 94% calcium carbonate inhibition was recorded when the experiment was carried out with ultrasonication. The use of 5 mg/L ATMP achieved a 90% calcium carbonate inhibition of ATMP. The result of the characterization revealed that the morphology of the crystals was unaffected by ultrasonic irradiation. Sample treatment was performed with two different membranes to evaluate the calcium carbonate deposition, and data reveals that, at identical conditions, ultrasonication provides less deposition when compared to the control experiments.


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