Proof-of-the-Concept of Spent Mushrooms Compost Torrefaction - Preliminary Studies of Process Kinetics and the Influence of Temperature and Duration on Calorific Value of the Biochar

Poland is the 3rdproducer of mushrooms in the world. Mushroom production in Poland accounts for nearly 25% of the total production in the EU, and it is still growing. One type of waste generated during mushroom production is mushroom spent compost (MSC), with a 5:1 (MSC: mushrooms) production rate. We investigated valorizing the MSC to produce fuel via torrefaction (‘roasting’, a.k.a. low-temperature pyrolysis). Specifically, we developed models for the MSC torrefaction kinetics using thermogravimetric analyses (TGA) and the effects of torrefaction temperature (200~300 °C) and process duration time (20~60 min) on the resulting biochar (fuel) properties. The estimated activation energy value of MSC torrefaction was 22.3 kJ.mol-1. The highest higher heating value(HHV) = 17.9 MJ.kg-1d.m. was found for 280 °C (60 min torrefaction time). The temperature of torrefaction significantly (p<0.05) increased the HHVfor constant process duration. The torrefaction duration time significantly (p<0.05) increased the HHVfor 220 °C and decreased HHVfor 300 °C. The highest mass yield 98.5% was found for 220 °C (60 min), while the highest energy yield was found for 280 °C (60 min). In addition, estimations of the value (€132.3·Mg-1d.m. or 27.7 €·Mg-1w.m) and quantity of resulting biochar (from torrefied MSC with 65.3% moisture content) were made based on the 280°C (60 min) torrefaction variant, assuming the price of commercially available coal fuel. We have shown a concept for an alternative utilization of abundant biowaste (MSC). The initial economic evaluation showed that MSC torrefaction might be profitable. This research provides a basis for alternative use of an abundant biowaste and can help charting improved, sustainable mushroom production.

Download Full-text

The effect of thermal pre-treatment on cassava rhizome properties for utilizing as green fuel in gasification

E3S Web of Conferences ◽

10.1051/e3sconf/202018101002 ◽

2020 ◽

Vol 181 ◽

pp. 01002

Author(s):

Punchaluck Sirinwaranon ◽

Duangduen Atong ◽

Viboon Sricharoenchaikul

Keyword(s):

Solid Fuel ◽

Petrochemical Industry ◽

Calorific Value ◽

Energy Yield ◽

Fuel Quality ◽

Heating Value ◽

Gasification Process ◽

Optimum Energy ◽

Pre Treatment ◽

Green Fuel

Cassava rhizome (CR) was torrefied to provide superior solid fuel quality for further gasification process. The torrefaction was carried out in the absence of oxygen at 220, 240, 260, and 280°C with a fixed residence time. Solid fuel after torrefaction has a higher calorific value from that of reduced volatile matters. The optimum energy yield of torrefied CR is 88.16% at 260°C. The heating value of 20.86 MJ/kg for a torrefied product can be achieved compared to 15.37 MJ/kg for untreated CR. The subsequent gasification of torrefied CR at temperature of 800°C yielded the highest gas product of 65 wt.%. The carbon and hydrogen conversions into CO and H2 were 14.28% and 29.95%, respectively. Synthesis gas (syngas) from the conversion maintained the H2/CO ratio of around 2–2.50, which is suitable for the Fischer–Tropsch process or can be used as the feedstock for petrochemical industry.

Download Full-text

Oxytree Pruned Biomass Torrefaction: Mathematical Models of the Influence of Temperature and Residence Time on Fuel Properties Improvement

Materials ◽

10.3390/ma12142228 ◽

2019 ◽

Vol 12 (14) ◽

pp. 2228 ◽

Cited By ~ 9

Author(s):

Kacper Świechowski ◽

Marek Liszewski ◽

Przemysław Bąbelewski ◽

Jacek Koziel ◽

Andrzej Białowiec

Keyword(s):

Residence Time ◽

Fuel Properties ◽

Heating Value ◽

Biomass Residues ◽

Coal Fuel ◽

Lower Heating Value ◽

Torrefied Biomass ◽

Akaike Criterion ◽

Economic Analyses ◽

Low Temperature Pyrolysis

Biowaste generated in the process of Oxytree cultivation and logging represents a potential source of energy. Torrefaction (a.k.a. low-temperature pyrolysis) is one of the methods proposed for the valorization of woody biomass. Still, energy is required for the torrefaction process during which the raw biomass becomes torrefied biomass with fuel properties similar to those of lignite coal. In this work, models describing the influence of torrefaction temperature and residence time on the resulting fuel properties (mass and energy yields, energy densification ratio, organic matter and ash content, combustible parts, lower and higher heating values, CHONS content, H:C and O:C ratios) were proposed according to the Akaike criterion. The degree of the models’ parameters matching the raw data expressed as the determination coefficient (R2) ranged from 0.52 to 0.92. Each model parameter was statistically significant (p < 0.05). Estimations of the value and quantity of the produced torrefied biomass from 1 Mg of biomass residues were made based on two models and a set of simple assumptions. The value of torrefied biomass (€123.4·Mg−1) was estimated based on the price of commercially available coal fuel and its lower heating value (LHV) for biomass moisture content of 50%, torrefaction for 20 min at 200 °C. This research could be useful to inform techno-economic analyses and decision-making process pertaining to the valorization of pruned biomass residues.

Download Full-text

Oxytree Pruned Biomass Torrefaction - Mathematical Models of the Influence of Temperature and Residence Time on Fuel Properties Improvement

10.20944/preprints201906.0126.v1 ◽

2019 ◽

Author(s):

Kacper Świechowski ◽

Marek Liszewski ◽

Przemysław Bąbelewski ◽

Jacek A. Koziel ◽

Andrzej Białowiec

Keyword(s):

Residence Time ◽

Fuel Properties ◽

Heating Value ◽

Biomass Residues ◽

Coal Fuel ◽

Lower Heating Value ◽

Akaike Criterion ◽

Economic Analyses ◽

Low Temperature Pyrolysis ◽

Lower Heating

Biowaste generated in the process of Oxytree cultivation and logging represents a potential source of energy. Torrefaction (a.k.a. low-temperature pyrolysis) is one of the methods proposed for the valorization of woody biomass. Still, energy is required for the torrefaction process during which the raw biomass becomes biochar with fuel properties similar to lignite coal. In this work, models describing the influence of torrefaction temperature and residence time on the resulting fuel properties (mass and energy yields, energy densification ratio, organic matter and ash content, combustible parts, lower and higher heating values, CHONS content, H:C and O:C ratios) were proposed according to the Akaike criterion. The degree of the models’ parameters matching the raw data expressed as the determination coefficient (R2) ranged from 0.52 to 0.92. Each model parameter was statistically significant (p<0.05). Estimations of the value and quantity of the produced biochar from 1 Mg of biomass residues were made based on two models and a set of simple assumptions. The value of torrefied biochar (€123.4·Mg-1) was estimated based on the price of commercially available coal fuel and its lower heating value (LHV) for biomass moisture content of 50%, torrefaction for 20 min at 200 °C. This research could be useful to inform techno-economic analyses and decision-making process pertaining to the valorization of pruned biomass residues.

Download Full-text

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

Risalah Fisika ◽

10.35895/rf.v4i1.166 ◽

2020 ◽

Vol 4 (1) ◽

pp. 1-7

Author(s):

Made Dirgantara ◽

Karelius Karelius ◽

Marselin Devi Ariyanti, Sry Ayu K. Tamba

Keyword(s):

Renewable Energy ◽

Natural Gas ◽

Key Words ◽

Critical Analysis ◽

Fossil Fuels ◽

Calorific Value ◽

Proximate Analysis ◽

Heating Value ◽

Bomb Calorimeter ◽

Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate

Download Full-text

Production of fuels on the basis of sewage sludge through conditioning using high calorific value fractions

Water Practice & Technology ◽

10.2166/wpt.2008.011 ◽

2008 ◽

Vol 3 (1) ◽

Author(s):

Karl-Georg Schmelz ◽

Anja Reipa ◽

Hartmut Meyer

Keyword(s):

Sewage Sludge ◽

Wastewater Treatment Plants ◽

Treatment Plant ◽

Calorific Value ◽

Fluidised Bed ◽

Sludge Treatment ◽

Heating Value ◽

Fine Coal ◽

Used Cars ◽

Plastic Components

Emschergenossenschaft and Lippeverband operate 59 wastewater treatment plants which produce approx. 100,000 Mg TS of sewage sludge each year. Using sludge pressure pipelines, about 60 % of this sludge are transported to the central sludge treatment plant in Bottrop. The digested sludges are conditioned using fine coal and polymers and are dewatered using membrane filters. By adding coal, the heating value of the sludge is raised which enables autothermal combustion of the dewatered sludges in fluidised bed furnaces at the central sludge treatment plant. In order to replace coal, a fossil fuel, as conditioning agent, experiments were conducted using alternative materials with high heating values. The addition of shredder fluff agglomerates proved to be particularly successful. Shredder fluff agglomerates are a residue from the recycling of used cars and are generated in a multistage process (e.g. Volkswagen-SiCon Process) by separating the light shredder fraction (plastic components etc.) from the total shredder fluff. The fibrous material is outstandingly suitable for improving the dewaterability and for sufficiently raising the heating value of the dewatered sludge in order to enable autothermal combustion. Since first experiments showed very positive results, a full-scale long-term test-run will take place in 2007.

Download Full-text

Energy efficiency of multivariate cultivation techniques in pasture forage production

Кормопроизводство ◽

10.25685/krm.2021.17.50.001 ◽

2021 ◽

pp. 3-6

Author(s):

К.Н. Привалова ◽

Р.Р. Каримов

Keyword(s):

Energy Efficiency ◽

Production Process ◽

Large Scale ◽

Exchange Energy ◽

Production Costs ◽

Energy Yield ◽

Total Production ◽

Forage Production ◽

Machinery Construction ◽

Natural Factors

Исследования по определению энергетической эффективности пастбищных систем со злаковыми и бобово-злаковыми травостоями проведены в Федеральном научном центре кормопроизводства и агроэкологии им. В. Р. Вильямса. В статье приведены результаты агроэнергетической оценки многовариантных пастбищных систем со злаковыми травостоями, созданными в 1946 году. Даны количественные показатели по сбору обменной энергии, совокупным затратам на её производство, окупаемости затрат в зависимости от системы ведения пастбищ. Изучена эффективность совокупных затрат в виде овеществлённого труда (на семена, удобрения, сельскохозяйственные машины, средства огораживания загонов и прочее) и живого труда (работы трактористов, пастухов и строителей и др.). Обоснована высокая агроэнергетическая эффективность изучаемых пастбищных систем благодаря мобилизации в продукционный процесс природных факторов, долевое участие которых в структуре производства обменной энергии составило 69–84%. Природные факторы, участвующие в продукционном процессе луговых агроэкосистем, характеризуются большим разнообразием. Это не только использование солнечной энергии и азотфиксация бобовыми травами, но и долголетие травостоев, самовозобновление фитоценозов, дерновообразовательный процесс (повышение плодородия почвы), получение дешёвого корма и улучшение здоровья животных при летнем выпасе. Роль возобновляемых природных факторов выявлена на основе балансового метода, принятого в экономике (по разнице сбора обменной энергии и антропогенных затрат). Благодаря ведущей роли природных факторов в структуре произведённой продукции агроэнергетический коэффициент окупаемости совокупных затрат антропогенной энергии (АК) за счёт сбора обменной энергии достигал 3–6 раз в среднем за 45 лет. Разработанные в результате долголетних исследований многовариантные энергосберегающие пастбищные системы обосновывают возможность рекомендовать их производству с учётом применения различного уровня энергозатрат. Ключевые слова: культурные пастбища, системы ведения, долголетние травостои, сбор обменной энергии, совокупные антропогенные затраты, окупаемость затрат. The investigation was conducted at the Federal Williams Research Center of Fodder Production and Agroecology and was aimed at testing energy efficiency of gramineous and legume-gramineous swards. This article presents the results obtained on pasture ecosystems with gramineous planted in 1946. Exchange energy yield, total production costs and economic effectiveness were analyzed. Total production costs comprised costs for seeds, fertilizers, machinery, construction materials, labor, etc. Introduction of natural factors into the production process resulted in higher energy efficiency. Their share amounted to 69–84% in the final exchange energy yield. There are a lot of natural factors that affect grass productivity such as solar energy, nitrogen-fixation, sward longevity and regeneration, soil fertility, low-cost feed production, and livestock health. The value of natural factors was determined according to the balance method (by the difference between exchange energy yield and anthropogenic costs). Since environmental factors had a leading role in the production process, the return rate raised by 3–6 times for 45 years due to exchange energy increase. Therefore, pasture ecosystems developed can be recommended for a large-scale forage production.

Download Full-text

Elementary analysis and energetic potential of the municipal sewage sludges from the Gdańsk and Kościerzyna WWTPs

E3S Web of Conferences ◽

10.1051/e3sconf/20182600004 ◽

2018 ◽

Vol 26 ◽

pp. 00004

Author(s):

Arkadiusz Ostojski

Keyword(s):

Sewage Sludge ◽

Water Content ◽

Calorific Value ◽

High Water ◽

Municipal Sewage ◽

Municipal Sewage Sludge ◽

High Water Content ◽

Sewage Sludges ◽

Heating Value ◽

Elementary Analysis

This paper aims to present municipal sewage sludge (MSS) elementary analysis and energetic potential based on measurement of heat of combustion (higher heating value HHV) and calculation of calorific values (lower heating value LHV). The analysis takes into the consideration water content in sewage sludge, at different utilization stages, in wastewater treatment plants in Gdańsk Wschód and Kościerzyna – Pomeranian Voivodeship. The study yielded the following results (in % dry matter): ash 19÷31 %, C - 31÷36 %, H - 5÷6 %, N - 4÷6 %, O - 28÷32 %, S – 1 %. Calorific value of stabilized sludges in Gdańsk was on average 13.8÷15 MJ/kg. In case of sludges not undergoing digestion from Kościerzyna WWTP, the calorific value was at the level of 17.5 MJ/kg. Thus, sewage sludges are good energy carriers. High water content though is the problem, as it lowers the useful effect of heat. There is no alternative for thermal sewage sludge neutralization, which is in conformity with valid Polish National Waste Management Plan (KPGO 2022).

Download Full-text

Municipal solid waste higher heating value prediction from ultimate analysis using multiple regression and genetic programming techniques

Waste Management & Research ◽

10.1177/0734242x18816797 ◽

2018 ◽

Vol 37 (6) ◽

pp. 578-589 ◽

Cited By ~ 6

Author(s):

Imane Boumanchar ◽

Younes Chhiti ◽

Fatima Ezzahrae M’hamdi Alaoui ◽

Abdelaziz Sahibed-dine ◽

Fouad Bentiss ◽

...

Keyword(s):

Genetic Programming ◽

Municipal Solid Waste ◽

Solid Waste ◽

Multiple Regression ◽

Calorific Value ◽

Heating Value ◽

Ultimate Analysis ◽

Msw Management ◽

Important Challenge ◽

Programming Techniques

Municipal solid waste (MSW) management presents an important challenge for all countries. In order to exploit them as a source of energy, a knowledge of their calorific value is essential. In fact, it can be experimentally measured by an oxygen bomb calorimeter. This process is, however, expensive. In this light, the purpose of this paper was to develop empirical models for the prediction of MSW higher heating value (HHV) from ultimate analysis. Two methods were used: multiple regression analysis and genetic programming formalism. Both techniques gave good results. Genetic programming, however, provides more accuracy compared to published works in terms of a great correlation coefficient (CC) and a low root mean square error (RMSE).

Download Full-text

Torrefaction of Napier Grass and Oil Palm Petiole Waste Using Drop-type Pyrolysis Reactor

10.21203/rs.3.rs-174954/v1 ◽

2021 ◽

Author(s):

Syazmi Zul Arif Hakimi Saadon ◽

Noridah Osman ◽

Moviin Damodaran ◽

Shan En Liew

Keyword(s):

Residence Time ◽

Oil Palm ◽

Waste Product ◽

Calorific Value ◽

Napier Grass ◽

Effect Of Temperature ◽

Energy Yield ◽

Pyrolysis Reactor ◽

Parameter Ranges ◽

Two Parameters

Abstract Interest in torrefaction has improved along the recent years and it has been studied extensively as a mean of preparing solid fuels. Biomass to be considered as a renewable source of energy must endeavor improvement continuously and where it is more sustainable going forward in which can come from waste product, wild and cultivated plant. The aim of this study is to investigate the effect of temperature and residence time of wild Napier grass and Oil palm petiole from waste. The torrefied samples were derived by pyrolysis reactor mimicking torrefaction procedure. The temperature parameter ranges between 220 and 300 ℃ while residence time parameter is from 10 minutes to 50 minutes of reaction. It was found that as temperature and time increasing, moisture content and amount of O and H atoms decreases as well as both mass and energy yield, but calorific value and the energy density increase along with both two parameters. Between the two parameters, the temperature variation shows more significant changes to the torrefied samples as compared time. The optimized temperature and time are found to be 260 ℃ and 30 minutes, respectively. Remarkably, the usage of pyrolyzer as torrefaction reaction has proved to be a good option since they share similar characteristics while can also produce product with similar properties reflecting torrefaction process.

Download Full-text

Characterization of Refuse Derived Fuel Production from Municipal Solid Waste: The Case Studies in Latvia and Lithuania

Environmental and Climate Technologies ◽

10.2478/rtuect-2020-0090 ◽

2020 ◽

Vol 24 (3) ◽

pp. 112-118

Author(s):

Dace Âriņa ◽

Rūta Bendere ◽

Gintaras Denafas ◽

Jānis Kalnačs ◽

Mait Kriipsalu

Keyword(s):

Municipal Solid Waste ◽

Solid Waste ◽

Calorific Value ◽

Ash Content ◽

Fuel Production ◽

Heating Value ◽

Refuse Derived Fuel ◽

Morphological Composition ◽

The Mean

AbstractThe authors determined the morphological composition of refuse derived fuel (RDF) produced in Latvia and Lithuania by manually sorting. The parameters of RDF (moisture, net calorific value, ash content, carbon, nitrogen, hydrogen, sulphur, chlorine, metals) was determined using the EN standards. Comparing obtained results with data from literature, authors have found that the content of plastic is higher but paper and cardboard is lower than typical values. Results also show that the mean parameters for RDF can be classified with the class codes: Net heating value (3); chlorine (3); mercury (1), and responds to limits stated for 3rd class of solid recovered fuel. It is recommended to separate biological waste at source to lower moisture and ash content and increase heating value for potential fuel production from waste.

Download Full-text