Surface Finishing of Single-Crystal SiC and GaN Wafers Using a Magnetic Tool in H2O2Solution

2019 ◽  
Vol 13 (2) ◽  
pp. 230-236 ◽  
Author(s):  
Akihisa Kubota ◽  

To remove the microroughness and subsurface damage on the SiC and GaN surface efficiently, a surface finishing technique using a magnetic tool holding iron particles in a hydrogen peroxide solution is developed. This technique utilizes OH radicals generated from the iron catalytic particles in a hydrogen peroxide solution, and can be used to preferentially remove the topmost convex part on the surface, resulting in an atomically smooth surface. We employed this polishing technique to finish the surfaces of 2-inch SiC and 2-inch GaN wafers. The surface roughness before and after finishing was measured by scanning white light interferometric microscopy and atomic force microscopy. In addition, the material removal rate was calculated by weight loss due to the finishing process. The results show that the surface roughness on the SiC and GaN wafers is markedly improved. Moreover, the surface waviness and flatness of these wafers before and after finishing did not deteriorate. Atomic force microscope images indicate that an atomically flat SiC surface with a roughness value below 0.1 nm RMS and a GaN surface with atomic step and terrace structures were achieved. Our proposed finishing technique is effective in improving the surface microroughness of SiC and GaN wafers.

2021 ◽  
Vol 32 (4) ◽  
pp. 19-30
Author(s):  
Nayara Rodrigues Nascimento Oliveira Tavares ◽  
Alexia da Mata Galvão ◽  
Lia Dietrich ◽  
Roberta Furtado Carvalho ◽  
Robinson Sabino Silva ◽  
...  

Abstract: This study investigated the bleaching effectiveness and the physicochemical effects on enamel of violet light and ozone, associate or not to hydrogen peroxide, compared to 35%-hydrogen peroxide. Enamel-dentin blocks from human molars were randomly allocated to receive one of the following bleaching protocols (n=15): (HP) 35%-hydrogen peroxide, (VL) violet light, (OZ) ozone, the association between hydrogen peroxide with ozone (OZ+HP) or violet light (VL+HP). All protocols were performed in two sessions with a 48h interval. Color (spectrophotometer) and mineral composition (Raman spectroscopy) were measured before and after the bleaching. Color changes were calculated by ΔEab, ΔE00, and whitening index (WI). The surface roughness was measured with an atomic force microscope. Data were analyzed by One-way or Two-way repeated measure ANOVA followed by the Tukey’s test (α = 0.05). The lowest color change values (either measured by WI, ΔEab, or ΔE00) were observed for VL and OZ used with no HP. Violet light associate with HP was unable to improve the color changes observed for the peroxide alone, in combination with OZ and HP, the highest color changes were verified. Regardless of bleaching protocol, the bleached enamel presented higher contents of PO4 and CO3 -2 than those observed at baseline. All bleaching protocols resulted in similar enamel surface roughness. Both the VL and the OZ caused reduced effects on the enamel color change when used alone. The ozone therapy improved the bleaching effect in the group that received the association of HP.


Author(s):  
H. Kinney ◽  
M.L. Occelli ◽  
S.A.C. Gould

For this study we have used a contact mode atomic force microscope (AFM) to study to topography of fluidized cracking catalysts (FCC), before and after contamination with 5% vanadium. We selected the AFM because of its ability to well characterize the surface roughness of materials down to the atomic level. It is believed that the cracking in the FCCs occurs mainly on the catalysts top 10-15 μm suggesting that the surface corrugation could play a key role in the FCCs microactivity properties. To test this hypothesis, we chose vanadium as a contaminate because this metal is capable of irreversibly destroying the FCC crystallinity as well as it microporous structure. In addition, we wanted to examine the extent to which steaming affects the vanadium contaminated FCC. Using the AFM, we measured the surface roughness of FCCs, before and after contamination and after steaming.We obtained our FCC (GRZ-1) from Davison. The FCC is generated so that it contains and estimated 35% rare earth exchaged zeolite Y, 50% kaolin and 15% binder.


2012 ◽  
Vol 576 ◽  
pp. 3-6 ◽  
Author(s):  
R. Bhuvenesh ◽  
M.S. Abdul Manan ◽  
M.H. Norizaman

Manufacturing companies define the qualities of thermal removing process based on the dimension and physical appearance of the cutting material surface. Therefore, the roughness of the surface area of the cutting material and the rate of the material being removed during the manual plasma arc cutting process was importantly considered. Plasma arc cutter Selco Genesis 90 was used to cut the specimens made from Standard AISI 1017 Steel manually based on the selected parameters setting. Two different thicknesses of specimens with 3mm and 6mm were used. The material removal rate (MRR) was measured by determining the weight of the specimens before and after the cutting process. The surface roughness (SR) analysis was conducted to determine the average roughness (Ra) value. Taguchi method was utilized as an experimental layout to obtain MRR and Ra values. The results reveal that for the case of manual plasma arc cutting machining, the SR values are inversely proportional to the MRR values. The quality of the surface roughness depends on the dross peak that occurred during the cutting process.


2010 ◽  
Vol 25 (4) ◽  
pp. 708-710 ◽  
Author(s):  
Atsushi Ogura ◽  
Daisuke Kosemura ◽  
Shingo Kinoshita

4H-silicon carbide (SiC) wafers were annealed at 1300 and 1600 °C for 30 min and 60 min in a conventional and purified Ar atmosphere. The surface roughness before and after annealing was evaluated by atomic force microscopy. The surface roughness before annealing was approximately 2.37 nm in root mean square. The roughness, after annealing for 30 min at 1300 and 1600 °C in a conventional Ar furnace, was increased to 4.53 and 14.9 nm, respectively. The roughness, after annealing for 60 min, was 5.01 and 19.1 nm, respectively. In this study, the G3 grade Ar gas (99.999%) was supplied in the conventional furnace tube. When the Ar gas was purified to an impurity concentration of less than 1 ppb, and it was supplied in the leak-tight furnace tube, the roughness after 30-min annealing improved 4.27 and 6.93 nm at 1300 and 1600 °C, respectively. The roughness after 60-min annealing was also reduced to 3.54 and 9.28 nm, respectively. We assume that a significant reduction of H2O concentration in the annealing atmosphere might play an important role in suppressing surface roughening of SiC during high-temperature annealing.


2009 ◽  
Vol 610-613 ◽  
pp. 175-178 ◽  
Author(s):  
Namsrai Javkhlantugs ◽  
Enkhbaatar Ankhbayar ◽  
Khishigjargal Tegshjargal ◽  
Damdin Enkhjargal ◽  
Chimed Ganzorig

The morphological surface change of untreated and treated fibers of the Mongolian goat cashmere was investigated by atomic force microscopy (AFM) at ambient conditions. The cuticle scale heights of the Mongolian goat cashmere fibers were measured by the AFM for the fibers before and after treatment. The experimental results showed that the difference between the fine structure of the cuticle and surface roughness of untreated and treated fibers. We found that the surface morphological change of the cashmere fibers was strongly degraded after the bleaching process.


Author(s):  
Weiwei Liu ◽  
Qian Lyu ◽  
Liming Lei ◽  
Yanhao Hou ◽  
Lei Shi

Through the simulation of abrasive flow in the inner cavity of the superalloy pre-spinning nozzle made by additive manufacturing, the special abrasive polishing tool is optimized and the surface polishing technology of the inner cavity of typical structure test pieceis studied. Through comparison of the surface morphology before and after polishing, it can be concluded that the abrasive flow has a considerable removal effect on the powder sticking effect, spheroidizing effect, step effect, slag hanging phenomenon and residual support on the surface of parts, but it has a limited effect on the surface pit of the substrate. After polishing, the surface roughness of the inner cavity of parts decreasea from Ra 3.1397 μm to Ra 0.5805 μm, and the surface roughness of blade position decreases from Ra 4.8473 μm to Ra 0.3606 μm. Through the range analysis, it is found that the effect intensity of the processing parameters on the surface roughness of the parts is in order of the processing time, processing pressure and abrasive particle size.


2019 ◽  
Vol 13 (04) ◽  
pp. 589-598
Author(s):  
Farhana Omar ◽  
Zuryati Ab-Ghani ◽  
Normastura Abd Rahman ◽  
Mohamad Syahrizal Halim

Abstract Objectives This study evaluates the efficacy and safety of the professionally prescribed and nonprescription over-the-counter (OTC) bleaching agents. Materials and Methods Extracted human upper central incisors were prepared and stained with red wine for 14 days before being subjected to four different bleaching agents: professionally prescribed opalescence PF 15%, VOCO Perfect Bleach 10%, nonprescription OTC Crest 3D Whitestrips, and Whitelight Teeth Whitening System. Colorimetric measurement was performed with Vita Easyshade Handheld Spectrophotometer, enamel surface microhardness measured using Vickers Hardness machine, and surface roughness was evaluated with profilometer, before and after bleaching. Scanning electron microscope (SEM) evaluation and atomic force microscopy were conducted postbleaching. Statistical Analysis The data were analyzed with t-test, two-way ANOVA, one-way ANOVA, and Turkey’s test at a significance level of 5%. Results All bleaching products have the same efficacy to whiten stained enamel. Opalescence PF 15% showed significant increase in the microhardness (92.69 ± 68.316). All groups demonstrated significant increase in surface roughness (p < 0.05). SEM evaluation showed that Opalescence PF 15% resulted in same microscopic appearance as unbleached enamel, while VOCO Perfect Bleach 10%, Whitelight Teeth Whitening System and Crest 3D Whitestrips demonstrated mild to moderate irregularities and accentuated irregularities, respectively. Conclusion Professionally prescribed bleaching agent of Opalescence PF 15% is effective tin whitening the teeth, while the other bleaching products may be effective but also have deleterious effects on the enamel.


1996 ◽  
Vol 448 ◽  
Author(s):  
Woochul Yang ◽  
F.J. Jedema ◽  
H. Ade ◽  
R.J Nemanich

AbstractThe morphologies of nanoscale epitaxial islands of TISi2 are studied. The islands are prepared by deposition of ultrathin Ti (3-20Å) on both smooth and roughened.Si(001) substrates. The island formation is initiated by annealing to 800-1000°C. The roughened substrates are prepared by etching with atomic H produced in a plasma. The morphologies of the substrate before and after island formation are examined by atomic force microscopy (AFM). In particular, the influence of surface-roughness on both the formation of islands and the size distribution of islands is investigated. On a rough substrate islands with a lateral dimension of ~350Å and a vertical dimension of ~25Å were observed with size uniformity of ~20%. Also it was observed that the roughness of the surface reduced the island size and affected the island distribution. The results are discussed in terms of surface energy and the strain field around the islands.


2018 ◽  
Vol 2018 ◽  
pp. 1-9
Author(s):  
Helena Gronwald ◽  
Katarzyna Mitura ◽  
Lukas Volesky ◽  
Pavel Kejzlar ◽  
Michał Szczypiński ◽  
...  

Reduced friction and wear of materials after the use of the carbon nanomaterials including nanodiamonds (NDs) have been confirmed by several studies in material engineering. Mechanical cleaning of the tooth surface by brush bristles should leave as little tissue roughened as possible. Higher surface roughness increases the tissue’s wear and encourages the redeposition of the bacteria and the colouring agents present in the diet. Therefore, we evaluated the tooth tissues’ surface’s morphological changes after brushing them with the NDs suspension. Ten human teeth were brushed with the NDs aqueous suspension. The surfaces were observed using an Atomic Force Microscope (AFM). We found that the nature of the tissue surface became milder and smoother. A number of selected profilometric parameters were compared before and after brushing. We observed that brushing with the suspension of NDs resulted in a significant reduction in the enamel and dentine’s surface roughness both in the range of the average parameters (Ra; p-0,0019) and in the detailed parameters (Rsk; p-0,048 and Rku; p-0,036). We concluded that the NDs used in the oral hygiene applications have a potentially protective effect on the enamel and the dentine’s surfaces.


Author(s):  
Raul E. Riveros ◽  
Jared N. Hann ◽  
Curtis R. Taylor ◽  
Hitomi Yamaguchi

A magnetic field-assisted finishing (MAF) process has been developed to reduce the sidewall surface roughness of the 5–20 μm wide curvilinear pores of microelectromechanical systems micropore X-ray optics to <1 nm Rq. Although the feasibility of this process has been demonstrated on these optics, a clear understanding of the MAF process' material removal mechanisms has not been attained. In an attempt to discover these mechanisms, the MAF process is applied to a flat workpiece, allowing for direct observation and tracking of changes to distinctive surface features before and after MAF. Atomic force microscopy, field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy are used to analyze the surface morphology and composition with respect to finishing time. These observations suggest that the MAF process modified the surface, reducing surface roughness (from 0.8 nm to 0.6 nm Rz on silicon) by removing relatively low-wavelength surface features. Moreover, the MAF process appears to modify the surface mechanically.


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