Two Approaches Provide Quality Control for NMR Measurement of Unconventional Rock

2021 ◽  
Vol 73 (02) ◽  
pp. 59-60
Author(s):  
Chris Carpenter

This article, written by JPT Technology Editor Chris Carpenter, contains highlights of paper SPE 201358, “Quality Control of NMR Measurements in Unconventional Rocks Using Hilbert Transforms and Semilogarithmic Derivatives,” by Pierre Aérens, SPE, David Medellin, and Carlos Torres-Verdin, SPE, The University of Texas at Austin, prepared for the 2020 SPE Annual Technical Conference and Exhibition, originally scheduled to be held in Denver, 5-7 October. The paper has not been peer reviewed. Nuclear magnetic resonance (NMR) measurements are extremely valuable in the assessment of fluid-flow properties of rocks. However, inverted transverse-relaxation time (T2) distributions are often biased. The authors of the complete paper introduce and compare two quality-control approaches based on two different signal-processing practices: the semilogarithmic derivative and the Hilbert transform. This work provides the basis of effective quality-control methods for NMR measurements for the petrophysical interpretation of rocks with complex pore-size distributions. The fast and reliable quality control of estimated T2 distributions is not affected by inversion artifacts, relying only on unfiltered, raw data. Introduction Borehole NMR measurements are commonly riddled with excessive noise that precludes high-resolution assessments of rock and fluid properties, especially in unconventional rock. Inverted T2 distributions can be biased by positivity constraints and the regularization method used in the inversion, making it difficult to determine whether the estimated pore-size distributions are reliable or byproducts of the inversion or regularization. Quality control of inversion results is essential for the robust quantitative interpretation of proton magnetization decays. The complete paper presents a mathematical analysis for the two data-quality assessment methods and the work flow to estimate pseudo-T2 distributions on the basis of time-decay proton magnetizations. The estimation and assessment methods are then applied to both synthetic and experimental data sets to verify their validity and reliability. The laboratory examples are detailed in the complete paper. Validation With Synthetic Cases The authors apply the derivative and Hilbert methods to two synthetic examples for a total of three cases. Both synthetic examples comprise three exponential magnetization decays, with amplitudes equal to A1=0.5, A2 =0.2, and A3=0.3. The first example is referred to as ideal because it is not contaminated with noise and because the authors chose the T2 peak times separated by three orders of magnitude at 1 µs, 1 ms, and 1000 ms, respectively. The second example showcases a more-realistic choice of T2 peak values, namely 0.1, 10, and 200 ms, respectively.

2020 ◽  
Author(s):  
Scott C. Hauswirth ◽  
◽  
Majdi Abou Najm ◽  
Christelle Basset

2014 ◽  
Vol 936 ◽  
pp. 942-949 ◽  
Author(s):  
Hao Tian Zhang ◽  
Qiu Yu Zhang ◽  
Bao Liang Zhang ◽  
Chun Mei Li

Porous properties have notable effect on separating effect of organic polymer-based monolithic column. Different applications of monolithic columns require tailored pore size distributions. On account of that, P(GMA-co-EGDMA) monolithic columns were prepared with novel ternary porogenic agents. Glass tubes was chosen as polymerization mold. Moreover, factors influencing the inner pore morphology, pore size and specific surface area were investigated systematically. The results showed that the increasing of the solubility of porogenic agents and the amount of crosslinker, the decreasing of the amount of porogenic agents and temperature rising all could give rise to the decreasing of pore size. Remarkably, the effect of initiator was studied for the first time. The results showed that amount of initiator had no remarkable influence on porous properties. By controlling effect factors, P(GMA-co-EGDMA) Monolithic Columns with pore size from dozens to thousands of nanometer, which can be applied in separation of molecules with different size.


Fuel ◽  
2017 ◽  
Vol 206 ◽  
pp. 352-363 ◽  
Author(s):  
Yong Li ◽  
Cheng Zhang ◽  
Dazhen Tang ◽  
Quan Gan ◽  
Xinlei Niu ◽  
...  

2001 ◽  
Vol 714 ◽  
Author(s):  
Kazuhiko Omote ◽  
Shigeru Kawamura

ABSTRACTWe have successively developed a new x-ray scattering technique for a non-destructive determination of pore-size distributions in porous low-κ thin films formed on thick substrates. The pore size distribution in a film is derived from x-ray diffuse scattering data, which are measured using offset θ/2θ scans to avoid strong specular reflections from the film surface and its substrate. Γ-distribution mode for the pores in the film is used in the calculation. The average diameter and the dispersion parameter of the Γ-distribution function are varied and refined by computer so that the calculated scattering pattern best matches to the experimental pattern. The technique has been used to analyze porous methyl silsesquioxane (MSQ) films. The pore size distributions determined by the x-ray scattering technique agree with that of the commonly used gas adsorption technique. The x-ray technique has been also used successfully determine small pores less than one nanometer in diameter, which is well below the lowest limit of the gas adsorption technique.


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