Exploring Low-IFT Foam EOR in Fractured Carbonates: Success and Particular Challenges of Sub-10-md Limestone

SPE Journal ◽  
1900 ◽  
Vol 25 (02) ◽  
pp. 867-882
Author(s):  
Pengfei Dong ◽  
Maura Puerto ◽  
Guoqing Jian ◽  
Kun Ma ◽  
Khalid Mateen ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Surfactant Solution ◽  
Mineral Dissolution ◽  
Mobility Control ◽  
Matrix Permeability ◽  
Geochemical Properties ◽  
Remaining Oil ◽  
The Matrix ◽  
Incremental Oil Recovery ◽  
Foam Flooding

Summary The high formation heterogeneity in naturally fractured limestone reservoirs requires mobility control agents to improve sweep efficiency and boost oil recovery. However, typical mobility control agents, such as polymers and gels, are impractical in tight sub-10-md formations due to potential plugging issues. The objective of this study is to demonstrate the feasibility of a low-interfacial-tension (low-IFT) foam process in fractured low-permeability limestone reservoirs and to investigate relevant geochemical interactions. The low-IFT foam process was investigated through coreflood experiments in homogeneous and fractured oil-wet cores with sub-10-md matrix permeability. The performance of a low-IFT foaming formulation and a well-known standard foamer [alpha olefin sulfonate (AOS) C14-16] were compared in terms of the efficiency of oil recovery. The effluent ionic concentrations were measured to understand how the geochemical properties of limestone influenced the low-IFT foam process. Aqueous stability and phase behavior tests with crushed core materials and brines containing various divalent ion concentrations were conducted to interpret the observations in the coreflood experiments. Low-IFT foam process can achieve significant incremental oil recovery in fractured oil-wet limestone reservoirs with sub-10-md matrix permeability. Low-IFT foam flooding in a fractured oil-wet limestone core with 5-md matrix permeability achieved 64% incremental oil recovery compared to waterflooding. In this process, because of the significantly lower capillary entry pressure for surfactant solution compared to gas, the foam primarily diverted surfactant solution from the fracture into the matrix. This selective diversion effect resulted in surfactant or weak foam flooding in the tight matrix and hence improved the invading fluid flow in the matrix. Meanwhile, the low-IFT property of the foaming formulation mobilized the remaining oil in the matrix. This oil mobilization effect of the low-IFT formulation achieved lower remaining oil saturation in the swept zones compared with the formulation lacking low-IFT property with oil. The limestone geochemical instability caused additional challenges for the low-IFT foam process in limestone reservoirs compared to dolomite reservoirs. The reactions of calcite with injected fluids—such as mineral dissolution and the exchange of calcium and magnesium—were found to increase the Ca2+ concentration in the produced fluids. Because the low-IFT foam process is sensitive to brine salinity, the additional Ca2+ may cause potential surfactant precipitation and unfavorable over-optimum conditions. It, therefore, may cause injectivity and phase-trapping issues especially in the homogeneous limestone. Results in this work demonstrated that despite the challenges associated with limestone dissolution, the low-IFT foam process can remarkably extend chemical enhanced oil recovery (EOR) in fractured oil-wet tight reservoirs with matrix permeability as low as 5 md.

Low-IFT Foaming System for Enhanced Oil Recovery in Highly Heterogeneous/Fractured Oil-Wet Carbonate Reservoirs

SPE Journal ◽  
2018 ◽  
Vol 23 (06) ◽  
pp. 2243-2259 ◽  
Author(s):  
Pengfei Dong ◽  
Maura Puerto ◽  
Guoqing Jian ◽  
Kun Ma ◽  
Khalid Mateen ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Fractured Reservoirs ◽  
Surfactant Solution ◽  
Capillary Forces ◽  
Mobility Control ◽  
Carbonate Reservoirs ◽  
Residual Oil ◽  
High Permeability ◽  
The Matrix ◽  
Foam Flooding

Summary Oil recovery in heterogeneous carbonate reservoirs is typically inefficient because of the presence of high-permeability fracture networks and unfavorable capillary forces within the oil-wet matrix. Foam, as a mobility-control agent, has been proposed to mitigate the effect of reservoir heterogeneity by diverting injected fluids from the high-permeability fractured zones into the low-permeability unswept rock matrix, hence improving the sweep efficiency. This paper describes the use of a low-interfacial-tension (low-IFT) foaming formulation to improve oil recovery in highly heterogeneous/fractured oil-wet carbonate reservoirs. This formulation provides both mobility control and oil/water IFT reduction to overcome the unfavorable capillary forces preventing invading fluids from entering an oil-filled matrix. Thus, as expected, the combination of mobility control and low-IFT significantly improves oil recovery compared with either foam or surfactant flooding. A three-component surfactant formulation was tailored using phase-behavior tests with seawater and crude oil from a targeted reservoir. The optimized formulation simultaneously can generate IFT of 10−2 mN/m and strong foam in porous media when oil is present. Foam flooding was investigated in a representative fractured core system, in which a well-defined fracture was created by splitting the core lengthwise and precisely controlling the fracture aperture by applying a specific confining pressure. The foam-flooding experiments reveal that, in an oil-wet fractured Edward Brown dolomite, our low-IFT foaming formulation recovers approximately 72% original oil in place (OOIP), whereas waterflooding recovers only less than 2% OOIP; moreover, the residual oil saturation in the matrix was lowered by more than 20% compared with a foaming formulation lacking a low-IFT property. Coreflood results also indicate that the low-IFT foam diverts primarily the aqueous surfactant solution into the matrix because of (1) mobility reduction caused by foam in the fracture, (2) significantly lower capillary entry pressure for surfactant solution compared with gas, and (3) increasing the water relative permeability in the matrix by decreasing the residual oil. The selective diversion effect of this low-IFT foaming system effectively recovers the trapped oil, which cannot be recovered with single surfactant or high-IFT foaming formulations applied to highly heterogeneous or fractured reservoirs.

A Novel Coreflood Test to Evaluate EOR Potential of Wettability-Altering Surfactants in Oil-Wet Heterogeneous Carbonate Reservoirs

2021 ◽  
Author(s):  
Yue Shi ◽  
Kishore Mohanty ◽  
Manmath Panda
Keyword(s):  
Oil Recovery ◽  
Carbonate Reservoirs ◽  
Wettability Alteration ◽  
Low Permeability ◽  
High Permeability ◽  
Matrix Permeability ◽  
Rock Heterogeneity ◽  
The Matrix ◽  
Flow Through ◽  
Main Factors

Abstract Oil-wetness and heterogeneity (i.e., existence of low and high permeability regions) are two main factors that result in low oil recovery by waterflood in carbonate reservoirs. The injected water is likely to flow through high permeability regions and bypass the oil in low permeability matrix. In this study, systematic coreflood tests were carried out in both "homogeneous" cores and "heterogeneous" cores. The heterogeneous coreflood test was proposed to model the heterogeneity of carbonate reservoirs, bypassing in low-permeability matrix during waterfloods, and dynamic imbibition of surfactant into the low-permeability matrix. The results of homogeneous coreflood tests showed that both secondary-waterflood and secondary-surfactant flood can achieve high oil recovery (>50%) from relatively homogenous cores. A shut-in phase after the surfactant injection resulted in an additional oil recovery, which suggests enough time should be allowed while using surfactants for wettability alteration. The core with a higher extent of heterogeneity produced lower oil recovery to waterflood in the coreflood tests. Final oil recovery from the matrix depends on matrix permeability as well as the rock heterogeneity. The results of heterogeneous coreflood tests showed that a slow surfactant injection (dynamic imbibition) can significantly improve the oil recovery if the oil-wet reservoir is not well-swept.

scholarly journals Influence of formation heterogeneity on foam flooding performance using 2D and 3D models: an experimental study

2019 ◽  
Vol 17 (3) ◽  
pp. 734-748 ◽  
Author(s):  
Ling-Zhi Hu ◽  
Lin Sun ◽  
Jin-Zhou Zhao ◽  
Peng Wei ◽  
Wan-Fen Pu
Keyword(s):  
Oil Recovery ◽  
3D Models ◽  
Reduction Factor ◽  
Mobility Control ◽  
Displacement Efficiency ◽  
Vertical Heterogeneity ◽  
Oil Displacement Efficiency ◽  
Heterogeneous Formations ◽  
Major Factors ◽  
Foam Flooding

AbstractThe formation heterogeneity is considered as one of the major factors limiting the application of foam flooding. In this paper, influences of formation properties, such as permeability, permeability distribution, interlayer, sedimentary rhythm and 3D heterogeneity, on the mobility control capability and oil displacement efficiency of foam flooding, were systematically investigated using 2D homogeneous and 2D/3D heterogeneous models under 120 °C and salinity of 20 × 104 mg/L. The flow resistance of foam was promoted as the permeability increased, which thus resulted in a considerable oil recovery behavior. In the scenario of the vertical heterogeneous formations, it was observed that the permeability of the high-permeable layer was crucial to foam mobility control, and the positive rhythm appeared favorable to improve the foam flooding performance. The additional oil recovery increased to about 40%. The interlayer was favorable for the increases in mobility reduction factor and oil recovery of foam flooding when the low permeability ratio was involved. For the 3D heterogeneous formations, foam could efficiently adjust the areal and vertical heterogeneity through mobility control and gravity segregation, and thus enhancing the oil recovery to 11%–14%. The results derived from this work may provide some insight for the field test designs of foam flooding.

Visualization and Analysis of Surfactant Imbibition Into Oil-Wet Fractured Cores

SPE Journal ◽  
2016 ◽  
Vol 21 (01) ◽  
pp. 101-111 ◽  
Author(s):  
Mohammad Mirzaei ◽  
David A. DiCarlo ◽  
Gary A. Pope
Keyword(s):  
Oil Recovery ◽  
Fractured Reservoirs ◽  
Surfactant Solution ◽  
Ct Scanning ◽  
Recovery Curves ◽  
The Core ◽  
The Matrix ◽  
Insight Into ◽  
Scaling Group ◽  
Better Than

Summary Imbibition of surfactant solution into the oil-wet matrix in fractured reservoirs is a complicated process that involves gravity, capillary, viscous, and diffusive forces. The standard experiment for testing imbibition of surfactant solution involves an imbibition cell, in which the core is placed in the surfactant solution and the recovery is measured vs. time. Although these experiments prove the effectiveness of surfactants, little insight into the physics of the problem is achieved. In this study, we performed water and surfactant flooding into oil-wet fractured cores and monitored the imbibition of the surfactant solution by use of computed-tomography (CT) scanning. From the CT images, the surfactant-imbibition dynamics as a function of height along the core was obtained. Although the waterflood only displaced oil from the fracture, the surfactant solution imbibed into the matrix; the imbibition is frontal, with the greatest imbibition rate at the bottom of the core, and the imbibition decreases roughly linearly with height. Experiments with cores of different sizes showed that increase in either the height or the diameter of the core causes decrease in imbibition and fractional oil-recovery rate. We also perform numerical simulations to model the observed imbibition. On the basis of the experimental measurements and numerical-simulation results, we propose a new scaling group that includes both the diameter and the height of the core. We show that the new scaling groups scale the recovery curves better than the traditional scaling group.

scholarly journals MICROEMULSION FLOODING MECHANISM FOR OPTIMUM OIL RECOVERY ON CHEMICAL INJECTION

2018 ◽  
Vol 40 (2) ◽  
pp. 85-90
Author(s):  
Yani Faozani Alli ◽  
Edward ML Tobing ◽  
Usman Usman
Keyword(s):  
Oil Recovery ◽  
Mobility Control ◽  
Chemical Flooding ◽  
Residual Oil ◽  
Core Flooding ◽  
Oil Viscosity ◽  
Oil Saturation ◽  
Remaining Oil ◽  
Tertiary Oil Recovery

The formation of microemulsion in the injection of surfactant at chemical flooding is crucial for the effectiveness of injection. Microemulsion can be obtained either by mixing the surfactant and oil at the surface or injecting surfactant into the reservoir to form in situ microemulsion. Its translucent homogeneous mixtures of oil and water in the presence of surfactant is believed to displace the remaining oil in the reservoir. Previously, we showed the effect of microemulsion-based surfactant formulation to reduce the interfacial tension (IFT) of oil and water to the ultralow level that suffi cient enough to overcome the capillary pressure in the pore throat and mobilize the residual oil. However, the effectiveness of microemulsion flooding to enhance the oil recovery in the targeted representative core has not been investigated.In this article, the performance of microemulsion-based surfactant formulation to improve the oil recovery in the reservoir condition was investigated in the laboratory scale through the core flooding experiment. Microemulsion-based formulation consist of 2% surfactant A and 0.85% of alkaline sodium carbonate (Na2CO3) were prepared by mixing with synthetic soften brine (SSB) in the presence of various concentration of polymer for improving the mobility control. The viscosity of surfactant-polymer in the presence of alkaline (ASP) and polymer drive that used for chemical injection slug were measured. The tertiary oil recovery experiment was carried out using core flooding apparatus to study the ability of microemulsion-based formulation to recover the oil production. The results showed that polymer at 2200 ppm in the ASP mixtures can generate 12.16 cP solution which is twice higher than the oil viscosity to prevent the fi ngering occurrence. Whereas single polymer drive at 1300 ppm was able to produce 15.15 cP polymer solution due to the absence of alkaline. Core flooding experiment result with design injection of 0.15 PV ASP followed by 1.5 PV polymer showed that the additional oil recovery after waterflood can be obtained as high as 93.41% of remaining oil saturation after waterflood (Sor), or 57.71% of initial oil saturation (Soi). Those results conclude that the microemulsion-based surfactant flooding is the most effective mechanism to achieve the optimum oil recovery in the targeted reservoir.

scholarly journals Optimization Design of Injection Strategy for Surfactant-Polymer Flooding Process in Heterogeneous Reservoir under Low Oil Prices

Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3789 ◽  
Author(s):  
He ◽  
Chen ◽  
Yu ◽  
Wen ◽  
Liu
Keyword(s):  
Oil Recovery ◽  
Oil Prices ◽  
Water Flooding ◽  
Fractional Flow ◽  
Simultaneous Injection ◽  
Oil Distribution ◽  
Remaining Oil ◽  
Remaining Oil Distribution ◽  
Incremental Oil Recovery ◽  
Injection Strategies

Surfactant–polymer (SP) flooding has significant potential to enhance oil recovery after water flooding in mature reservoirs. However, the economic benefit of the SP flooding process is unsatisfactory under low oil prices. Thus, it is necessary to reduce the chemical costs and improve SP flooding efficiency to make SP flooding more profitable. Our goal was to maximize the incremental oil recovery of the SP flooding process after water flooding by using the equal chemical consumption cost to ensure the economic viability of the SP flooding process. Thus, a systematic study was carried out to investigate the SP flooding process under different injection strategies by conducting parallel sand pack flooding experiments to optimize the SP flooding design. Then, the comparison of the remaining oil distribution after water flooding and SP flooding under different injection strategies was studied. The results demonstrate that the EOR efficiency of the SP flooding process under the alternating injection of polymer and surfactant–polymer (PASP) is higher than that of conventional simultaneous injection of surfactant and polymer. Moreover, as the alternating cycle increases, the incremental oil recovery increases. Based on the analysis of fractional flow, incremental oil recovery, and remaining oil distribution when compared with the conventional simultaneous injection of surfactant and polymer, the alternating injection of polymer and surfactant–polymer (PASP) showed better sweep efficiency improvement and recovered more remaining oil trapped in the low permeability zone. Thus, these findings could provide insights into designing the SP flooding process under low oil prices.

Numerical Calculation of Flow Characteristics of Enhanced Foam System in Porous Medium

2016 ◽  
Vol 9 (1) ◽  
pp. 29-36
Author(s):  
Chengli Zhang ◽  
Guodong Qu ◽  
Guoqiang Cui ◽  
Mingxing Bai
Keyword(s):  
Porous Media ◽  
Numerical Calculation ◽  
Unsteady Flow ◽  
Oil Recovery ◽  
Oil And Gas ◽  
Surfactant Solution ◽  
Average Density ◽  
Chemical Flooding ◽  
Flow Front ◽  
Foam Flooding

Enhanced foam flooding is a chemical flooding technology, which is applied to improve the recovery efficiency of oil and gas. The oil displacement agent of enhanced foam flooding is a foam that the polymer and surfactant solution as liquid. In this paper, three-dimensional mathematical model of unsteady flow is established about enhanced foam system in the porous media, and the numerical calculation method is given to study the enhanced foam flooding. The results show that: the unsteady flow of enhanced foam system in porous media exists flow front, the flow foam average density of flow front reach the peak; enhanced foam flooding can form the oil bank in the displacement front and the oil saturation of the oil bank reaches about 0.55, the oil bank can produce effective drive to remain oil and then improve oil recovery.

The Influence of Heterogeneity, Wetting, and Viscosity Ratio on Oil Recovery From Vertically Fractured Reservoirs

SPE Journal ◽  
2010 ◽  
Vol 16 (02) ◽  
pp. 411-428 ◽  
Author(s):  
Hamidreza Salimi ◽  
Johannes Bruining
Keyword(s):  
Contact Angle ◽  
Oil Recovery ◽  
Delay Time ◽  
Viscosity Ratio ◽  
Fractured Reservoirs ◽  
Contact Angles ◽  
Effective Length ◽  
Fracture Aperture ◽  
Matrix Permeability ◽  
The Matrix

Summary We use upscaling through homogenization to predict oil recovery from fractured reservoirs consisting of matrix columns, also called vertically fractured reservoirs (VFRs), for a variety of conditions. The upscaled VFR model overcomes limitations of the dual-porosity model, including the use of a shape factor. The purpose of this paper is to investigate three main physical aspects of multiphase flow in fractured reservoirs: reservoir wettability, viscosity ratio, and heterogeneity in rock/fluid properties. The main characteristic that determines reservoir behavior is the Péclet number that expresses the ratio of the average imbibition time divided by the residence time of the fluids in the fractures. The second characteristic dimensionless number is the gravity number. Upscaled VFR simulations, aimed at studying the mentioned features, add new insights. First, we discuss the results at low Péclet numbers. For only small gravity numbers, the effect of contact angle, delay time for the nonequilibrium capillary effect, the heterogeneity of the matrix-column size, and the matrix permeability can be ignored without appreciable loss of accuracy. The ultimate oil recovery for mixed-wet VFRs is approximately equal to the Amott index, and the oil production does not depend on the absolute value of the phase viscosity but on viscosity ratio. However, large gravity numbers enhance underriding, aggravated by large contact angles, longer delay times, and higher viscosity ratios. Layering can lead to an improvement or deterioration, depending on the fracture aperture and permeability distribution. At low Péclet numbers, the fractured reservoir behaves very similarly to a conventional reservoir and depends largely on the viscosity ratio and the gravity number. At high Péclet numbers, after water breakthrough, the oil recovery appears to be proportional to the cosine of the contact angle and inversely proportional to the sum of the oil and water viscosity. In addition, the mixed-wetting effect is more pronounced; there are significant influences of delay time (nonequilibrium effects), matrix permeability, matrix-column size, and the column-size distribution on oil recovery. At low gravity numbers and an effective length/thickness ratio larger than 10, the oil recovery is independent of the vertical-fracture-aperture distribution. For the same amount of injected water, the recovery at low Péclet numbers is larger than the recovery at high Péclet numbers.

Design of an Economical Polymer Flood Pilot Addressing Field Development Uncertainties in the Sabriyah Upper Burgan Reservoir of North Kuwait

2021 ◽  
Author(s):  
Mohammed T. Al-Murayri ◽  
Dawood Kamal ◽  
Najres Al-Mahmeed ◽  
Anfal Al Kharji ◽  
Hadeel Baroon ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Oil And Gas ◽  
Oil And Gas Industry ◽  
Polymer Flooding ◽  
Mobility Control ◽  
Field Development ◽  
Reservoir Volume ◽  
Polymer Flood ◽  
Incremental Oil Recovery ◽  
Commercial Size

Abstract The Sabriyah Upper Burgan is a major oil reservoir in North Kuwait with high oil saturation and is currently considered for mobility control via polymer flooding. Although there is high confidence in the selected technology, there are technological and geologic challenges that must be understood to transition towards phased commercial field development. Engineering and geologic screening suggested that chemical flood technologies were superior to either miscible gas or waterflood technologies. Of the chemical flood technologies, mobility control flooding was considered the best choice due to available water ion composition and total dissolved solids (TDS). Evaluation of operational and economic considerations were instrumental in recommending mobility control polymer flooding for pilot testing. Laboratory selected acceptable polymer for use with coreflood incremental oil recovery being up to 9% OOIP. Numerical simulation recommended two commercial size pilots, a 3-pattern and a 5-pattern of irregular five spots, with forecast incremental oil recovery factors of 5.6% OOIP over waterflood. Geologic uncertainty is the greatest challenge in the oil and gas industry, which is exacerbated with any EOR project. Screening of the Upper Burgan reservoirs indicates that UB4 channel sands are the best candidates for EOR technologies. Reservoir quality is excellent and there is sufficient reservoir volume in the northwest quadrant of the field to justify not only a pilot but also future expansion. There is a limited edge water drive of unknown strength that will need to be assessed. The channel facies sandstones have porosities of +25%, permeabilities in the Darcy range, and initial oil saturations of +90%. Pore volume (PV) of the two recommended pilot varies from 29 to 45 million barrels. A total of 0.7 PV of polymer is expected to be injected in 5.6 and 7.9 years for the 3-pattern pilot and the 5-pattern pilot, respectively, with a water drive flush to follow for an additional 5 to 7 years. Incremental cost per incremental barrel of oil of a mobility control polymer flood which includes OPEX and CAPEX costs is $20 (USD). This paper evaluates the (commercial size) pilot design and addresses field development uncertainties.

Carbon Dots Stabilized Foam for Enhanced Oil Recovery

2021 ◽  
Author(s):  
Sivabalan Sakthivel ◽  
Mazen Kanj
Keyword(s):  
Oil Recovery ◽  
Oil And Gas ◽  
High Salinity ◽  
Foam Stability ◽  
Surfactant Solution ◽  
Oil And Gas Industry ◽  
Mobility Control ◽  
Carbon Nanodots ◽  
High Permeability ◽  
Drainage Rate

Abstract Foams are the divergent fluids that are employed in the upstream oil and gas industry to reduce fluid channeling and fingering in the high permeability region. Foams are usually generated in the high permeability reservoirs (e.g. glass beads) by the alternative injection of surfactant and gas. Conventional foaming systems exhibit stability issues at the high temperature and high salinity reservoir conditions. In this investigation, we study the stability and efficiency (in terms of both enhanced inflow performance and added oil recovery) of foams formed using surfactant solution with and without carbon Nanodots (CND). The study involved using different brine salinities, CND concentrations, temperature and pressure conditions, and types of surfactants. A multifaceted interrelationship of the various influencing mechanisms is demonstrated. Foams are examined using foam analyzer, HP/HT coreflood and microfluidic setup. In trace amounts (5-10 ppm), CND contributed to 60-70% improvement in foam stability in high salinity brine. The improvement is attributed by the reduction of the drainage rate of the lamellae and a delay of the bubble rupturing point. Both microfluidic and core-flood experiments showed noticeable improvement in mobility control with the addition of the CND. This is contributed to an improved foamability, morphology, strength, and stability of the foam.

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