Experimental Design and Evaluation of Surfactant Polymer for a Heavy Oil Field in South of Sultanate of Oman

2021 ◽  
Author(s):  
Ali Reham Al-Jabri ◽  
Rouhollah Farajzadeh ◽  
Abdullah Alkindi ◽  
Rifaat Al-Mjeni ◽  
David Rousseau ◽  
...  

Abstract Heavy oil reservoirs remain challenging for surfactant-based EOR. In particular, selecting fine-tuned and cost effective chemical formulations requires extensive laboratory work and a solid methodology. This paper reports a laboratory feasibility study, aiming at designing a surfactant-polymer pilot for a heavy oil field with an oil viscosity of ~500cP in the South of Sultanate of Oman, where polymer flooding has already been successfully trialed. A major driver was to design a simple chemical EOR method, to minimize the risk of operational issues (e.g. scaling) and ensure smooth logistics on the field. To that end, a dedicated alkaline-free and solvent-free surfactant polymer (SP) formulation has been designed, with its sole three components, polymer, surfactant and co-surfactant, being readily available industrial chemicals. This part of the work has been reported in a previous paper. A comprehensive set of oil recovery coreflood tests has then been carried out with two objectives: validate the intrinsic performances of the SP formulation in terms of residual oil mobilization and establish an optimal injection strategy to maximize oil recovery with minimal surfactant dosage. The 10 coreflood tests performed involved: Bentheimer sandstone, for baseline assessments on large plugs with minimized experimental uncertainties; homogeneous artificial sand and clays granular packs built to have representative mineralogical composition, for tuning of the injection parameters; native reservoir rock plugs, unstacked in order to avoid any bias, to validate the injection strategy in fully representative conditions. All surfactant injections were performed after long polymer injections, to mimic the operational conditions in the field. Under injection of "infinite" slugs of the SP formulation, all tests have led to tertiary recoveries of more than 88% of the remaining oil after waterflood with final oil saturations of less than 5%. When short slugs of SP formulation were injected, tertiary recoveries were larger than 70% ROIP with final oil saturations less than 10%. The final optimized test on a reservoir rock plug, which was selected after an extensive review of the petrophysical and mineralogical properties of the available reservoir cores, led to a tertiary recovery of 90% ROIP with a final oil saturation of 2%, after injection of 0.35 PV of SP formulation at 6 g/L total surfactant concentration, with surfactant losses of 0.14 mg-surfactant/g(rock). Further optimization will allow accelerating oil bank arrival and reducing the large PV of chase polymer needed to mobilize the liberated oil. An additional part of the work consisted in generating the parameters needed for reservoir scale simulation. This required dedicated laboratory assays and history matching simulations of which the results are presented and discussed. These outcomes validate, at lab scale, the feasibility of a surfactant polymer process for the heavy oil field investigated. As there has been no published field test of SP injection in heavy oil, this work may also open the way to a new range of field applications.

2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.


SPE Journal ◽  
2016 ◽  
Vol 21 (01) ◽  
pp. 74-86 ◽  
Author(s):  
M.. Tagavifar ◽  
R.. Fortenberry ◽  
E.. de Rouffignac ◽  
K.. Sepehrnoori ◽  
G. A. Pope

Summary A hybrid process is developed and optimized for heavy-oil recovery that combines moderate reservoir heating and chemical enhanced oil recovery in the form of alkali/cosolvent/polymer flood. The process is simulated by use of a model derived from existing laboratory and pilot data of a 5,000-cp heavy-oil field. It is found that hot waterflooding is efficient in heating the reservoir only when high early injectivity is achievable. This may not be the case if incipient fluid injectivity is low and/or long, continuous, horizontal shale baffles are present. To remedy the former, an electrical-preheating period is devised, whereas switching to a horizontal flood could overcome the latter. Once the reservoir temperature is raised sufficiently, a moderately unstable alkali/cosolvent/polymer flood is capable of mobilizing and displacing oil. A best combined strategy for efficient reservoir heating, high oil recovery, and cost effectiveness is found to involve reducing the oil viscosity to values of approximately 300–500 cp and combining a degree of mobility control and low interfacial tension as recovery mechanisms.


Author(s):  
Clement Fabbri ◽  
Romain de-Loubens ◽  
Arne Skauge ◽  
Gerald Hamon ◽  
Marcel Bourgeois

In the domain of heavy to extra heavy oil production, viscous polymer may be injected after water injection (tertiary mode), or as an alternative (secondary mode) to improve the sweep efficiency and increase oil recovery. To prepare field implementation, nine polymer injection experiments in heavy oil have been performed at core scale, to assess key modelling parameters in both situations. Among this consistent set of experiments, two have been performed on reconstituted cylindrical sandpacks in field-like conditions, and seven on consolidated Bentheimer sandstone in laboratory conditions. All experiments target the same oil viscosity, between 2000 cP and 7000 cP, and the viscosity of Partially Hydrolyzed Polyacrylamide solutions (HPAM 3630) ranges from 60 cP to 80 cP. Water and polymer front propagation are studied using X-ray and tracer measurements. The new experimental results presented here for water flood and polymer flood experiments are compared with experiments described in previous papers. The effects of geometry, viscosity ratio, injection sequence on recoveries, and history match parameters are investigated. Relative permeabilities of the water flood experiment are in line with previous experiments in linear geometry. Initial water floods led to recoveries of 15–30% after one Pore Volume Injected (PVI), a variation influenced by boundary conditions, viscosity, and velocities. The secondary polymer flood in consolidated sandstone confirms less stable displacement than tertiary floods in same conditions. Comparison of secondary and tertiary polymer floods history matching parameters suggests two mechanisms. First, hysteresis effect during oil bank mobilization stabilizes the tertiary polymer front; secondly, the propagation of polymer at higher oil saturation leads to lower adsorption during secondary experiment, generating a lower Residual Resistance Factor (RRF), close to unity. Finally, this paper discusses the use of the relative permeabilities and polymer properties estimated using Darcy equation for field simulation, depending on water distribution at polymer injection start-up.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-17
Author(s):  
Xianhong Tan ◽  
Wei Zheng ◽  
Taichao Wang ◽  
Guojin Zhu ◽  
Xiaofei Sun ◽  
...  

The supercritical multithermal fluids (SCMTF) were developed for deep offshore heavy oil reservoirs. However, its EOR mechanisms are still unclear, and its numerical simulation method is deficient. In this study, a series of sandpack flooding experiments were first performed to investigate the viability of SCMTF flooding. Then, a novel numerical model for SCMTF flooding was developed based on the experimental results to characterize the flooding processes and to study the effects of injection parameters on oil recovery on a lab scale. Finally, the performance of SCMTF flooding in a practical deep offshore oil field was evaluated through simulation. The experiment results show that the SCMTF flooding gave the highest oil recovery of 80.89%, which was 29.60% higher than that of the steam flooding and 11.09% higher than that of SCW flooding. The history matching process illustrated that the average errors of 3.24% in oil recovery and of 4.33% in pressure difference confirm that the developed numerical model can precisely simulate the dynamic of SCMTF flooding. Increases in temperature, pressure, and the mole ratio of scN2 and scCO2 mixture to SCW benefit the heavy oil production. However, too much increase in temperature resulted in formation damage. In addition, an excess of scN2 and scCO2 contributed to an early SCMTF breakthrough. The field-scale simulation indicated that compared to steam flooding, the SCMTF flooding increased cumulative oil production by 27122 m3 due to higher reservoir temperature, expanded heating area, and lower oil viscosity, suggesting that the SCMTF flooding is feasible in enhancing offshore heavy oil recovery.


2018 ◽  
Vol 140 (10) ◽  
Author(s):  
Zhanxi Pang ◽  
Peng Qi ◽  
Fengyi Zhang ◽  
Taotao Ge ◽  
Huiqing Liu

Heavy oil is an important hydrocarbon resource that plays a great role in petroleum supply for the world. Co-injection of steam and flue gas can be used to develop deep heavy oil reservoirs. In this paper, a series of gas dissolution experiments were implemented to analyze the properties variation of heavy oil. Then, sand-pack flooding experiments were carried out to optimize injection temperature and injection volume of this mixture. Finally, three-dimensional (3D) flooding experiments were completed to analyze the sweep efficiency and the oil recovery factor of flue gas + steam flooding. The role in enhanced oil recovery (EOR) mechanisms was summarized according to the experimental results. The results show that the dissolution of flue gas in heavy oil can largely reduce oil viscosity and its displacement efficiency is obviously higher than conventional steam injection. Flue gas gradually gathers at the top to displace remaining oil and to decrease heat loss of the reservoir top. The ultimate recovery is 49.49% that is 7.95% higher than steam flooding.


2021 ◽  
Vol 143 (7) ◽  
Author(s):  
Ali Alarbah ◽  
Ezeddin Shirif ◽  
Na Jia ◽  
Hamdi Bumraiwha

Abstract Chemical-assisted enhanced oil recovery (EOR) has recently received a great deal of attention as a means of improving the efficiency of oil recovery processes. Producing heavy oil is technically difficult due to its high viscosity and high asphaltene content; therefore, novel recovery techniques are frequently tested and developed. This study contributes to general progress in this area by synthesizing an acidic Ni-Mo-based liquid catalyst (LC) and employing it to improve heavy oil recovery from sand-pack columns for the first time. To understand the mechanisms responsible for improved recovery, the effect of the LC on oil viscosity, density, interfacial tension (IFT), and saturates, aromatics, resin, and asphaltenes (SARA) were assessed. The results show that heavy oil treated with an acidic Ni-Mo-based LC has reduced viscosity and density and that the IFT of oil–water decreased by 7.69 mN/m, from 24.80 mN/m to 17.11 mN/m. These results are specific to the LC employed. The results also indicate that the presence of the LC partially upgrades the structure and group composition of the heavy oil, and sand-pack flooding results show that the LC increased the heavy oil recovery factor by 60.50% of the original oil in place (OOIP). Together, these findings demonstrate that acidic Ni-Mo-based LCs are an effective form of chemical-enhanced EOR and should be considered for wider testing and/or commercial use.


2021 ◽  
Author(s):  
Jasmine Shivani Medina ◽  
Iomi Dhanielle Medina ◽  
Gao Zhang

Abstract The phenomenon of higher than expected production rates and recovery factors in heavy oil reservoirs captured the term "foamy oil," by researchers. This is mainly due to the bubble filled chocolate mousse appearance found at wellheads where this phenomenon occurs. Foamy oil flow is barely understood up to this day. Understanding why this unusual occurrence exists can aid in the transfer of principles to low recovery heavy oil reservoirs globally. This study focused mainly on how varying the viscosity and temperature via pressure depletion lab tests affected the performance of foamy oil production. Six different lab-scaled experiments were conducted, four with varying temperatures and two with varying viscosities. All experiments were conducted using lab-scaled sand pack pressure depletion tests with the same initial gas oil ratio (GOR). The first series of experiments with varying temperatures showed that the oil recovery was inversely proportional to elevated temperatures, however there was a directly proportional relationship between gas recovery and elevation in temperature. A unique observation was also made, during late-stage production, foamy oil recovery reappeared with temperatures in the 45-55°C range. With respect to the viscosities, a non-linear relationship existed, however there was an optimal region in which the live-oil viscosity and foamy oil production seem to be harmonious.


SPE Journal ◽  
2019 ◽  
Vol 24 (02) ◽  
pp. 413-430
Author(s):  
Zhanxi Pang ◽  
Lei Wang ◽  
Zhengbin Wu ◽  
Xue Wang

Summary Steam-assisted gravity drainage (SAGD) and steam and gas push (SAGP) are used commercially to recover bitumen from oil sands, but for thin heavy-oil reservoirs, the recovery is lower because of larger heat losses through caprock and poorer oil mobility under reservoir conditions. A new enhanced-oil-recovery (EOR) method, expanding-solvent SAGP (ES-SAGP), is introduced to develop thin heavy-oil reservoirs. In ES-SAGP, noncondensate gas and vaporizable solvent are injected with steam into the steam chamber during SAGD. We used a 3D physical simulation scale to research the effectiveness of ES-SAGP and to analyze the propagation mechanisms of the steam chamber during ES-SAGP. Under the same experimental conditions, we conducted a contrast analysis between SAGP and ES-SAGP to study the expanding characteristics of the steam chamber, the sweep efficiency of the steam chamber, and the ultimate oil recovery. The experimental results show that the steam chamber gradually becomes an ellipse shape during SAGP. However, during ES-SAGP, noncondensate gas and a vaporizable solvent gather at the reservoir top to decrease heat losses, and oil viscosity near the condensate layer of the steam chamber is largely decreased by hot steam and by solvent, making the boundary of the steam chamber vertical and gradually a similar, rectangular shape. As in SAGD, during ES-SAGP, the expansion mechanism of the steam chamber can be divided into three stages: the ascent stage, the horizontal-expansion stage, and the descent stage. In the ascent stage, the time needed is shorter during ES-SAGP than during SAGP. However, the other two stages take more time during nitrogen, solvent, and steam injection to enlarge the cross-sectional area of the bottom of the steam chamber. For the conditions in our experiments, when the instantaneous oil/steam ratio is lower than 0.1, the corresponding oil recovery is 51.11%, which is 7.04% higher than in SAGP. Therefore, during ES-SAGP, not only is the volume of the steam chamber sharply enlarged, but the sweep efficiency and the ultimate oil recovery are also remarkably improved.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Yong Du ◽  
Guicai Zhang ◽  
Jijiang Ge ◽  
Guanghui Li ◽  
Anzhou Feng

Oil viscosity was studied as an important factor for alkaline flooding based on the mechanism of “water drops” flow. Alkaline flooding for two oil samples with different viscosities but similar acid numbers was compared. Besides, series flooding tests for the same oil sample were conducted at different temperatures and permeabilities. The results of flooding tests indicated that a high tertiary oil recovery could be achieved only in the low-permeability (approximately 500 mD) sandpacks for the low-viscosity heavy oil (Zhuangxi, 390 mPa·s); however, the high-viscosity heavy oil (Chenzhuang, 3450 mPa·s) performed well in both the low- and medium-permeability (approximately 1000 mD) sandpacks. In addition, the results of flooding tests for the same oil at different temperatures also indicated that the oil viscosity put a similar effect on alkaline flooding. Therefore, oil with a high-viscosity is favorable for alkaline flooding. The microscopic flooding test indicated that the water drops produced during alkaline flooding for oils with different viscosities differed significantly in their sizes, which might influence the flow behaviors and therefore the sweep efficiencies of alkaline fluids. This study provides an evidence for the feasibility of the development of high-viscosity heavy oil using alkaline flooding.


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