Fuel Ammonia from Fossil Energy: Hydrocarbon Utilization for Sustainable Development

2021 ◽  
Author(s):  
Takashi Akai ◽  
Makoto Shimouchi ◽  
Keisuke Miyoshi ◽  
Hiroshi Okabe

Abstract Synthetic ammonia from fossil energy can technically be used for power generation. Viewed as hydrocarbon utilization, it enables oil and gas industries to move towards the sustainable development of resources while minimizing their carbon footprint. We present an integrated high-level overview of this concept by highlighting the following key aspects: i) the carbon footprint of the process, ii) the necessity for carbon capture and storage (CCS), iii) power generation from fuel ammonia, and iv) market development. First, the carbon footprint was estimated based on the chemical formulas of the process, which revealed the necessity for CCS for the process to provide cleaner energy. Second, having reviewed these four key aspects, we showed that most elemental technologies comprising this new value chain have already been technically proven. Finally, we discuss and conclude with possible ways towards the commercialization of this value chain.

Author(s):  
Andrea Ciani ◽  
John P. Wood ◽  
Anders Wickström ◽  
Geir J. Rørtveit ◽  
Rosetta Steeneveldt ◽  
...  

Abstract Today gas turbines and combined cycle power plants play an important role in power generation and in the light of increasing energy demand, their role is expected to grow alongside renewables. In addition, the volatility of renewables in generating and dispatching power entails a new focus on electricity security. This reinforces the importance of gas turbines in guaranteeing grid reliability by compensating for the intermittency of renewables. In order to achieve the Paris Agreement’s goals, power generation must be decarbonized. This is where hydrogen produced from renewables or with CCS (Carbon Capture and Storage) comes into play, allowing totally CO2-free combustion. Hydrogen features the unique capability to store energy for medium to long storage cycles and hence could be used to alleviate seasonal variations of renewable power generation. The importance of hydrogen for future power generation is expected to increase due to several factors: the push for CO2-free energy production is calling for various options, all resulting in the necessity of a broader fuel flexibility, in particular accommodating hydrogen as a future fuel feeding gas turbines and combined cycle power plants. Hydrogen from methane reforming is pursued, with particular interest within energy scenarios linked with carbon capture and storage, while the increased share of renewables requires the storage of energy for which hydrogen is the best candidate. Compared to natural gas the main challenge of hydrogen combustion is its increased reactivity resulting in a decrease of engine performance for conventional premix combustion systems. The sequential combustion technology used within Ansaldo Energia’s GT36 and GT26 gas turbines provides for extra freedom in optimizing the operation concept. This sequential combustion technology enables low emission combustion at high temperatures with particularly high fuel flexibility thanks to the complementarity between its first stage, stabilized by flame propagation and its second (sequential) stage, stabilized by auto-ignition. With this concept, gas turbines are envisaged to be able to provide reliable, dispatchable, CO2-free electric power. In this paper, an overview of hydrogen production (grey, blue, and green hydrogen), transport and storage are presented targeting a CO2-free energy system based on gas turbines. A detailed description of the test infrastructure, handling of highly reactive fuels is given with specific aspects of the large amounts of hydrogen used for the full engine pressure tests. Based on the results discussed at last year’s Turbo Expo (Bothien et al. GT2019-90798), further high pressure test results are reported, demonstrating how sequential combustion with novel operational concepts is able to achieve the lowest emissions, highest fuel and operational flexibility, for very high combustor exit temperatures (H-class) with unprecedented hydrogen contents.


2019 ◽  
Vol 38 (4) ◽  
pp. 733-750
Author(s):  
Sébastien Chailleux

Analyzing the case of France, this article aims to explain how the development of enhanced oil recovery techniques over the last decade contributed to politicizing the subsurface, that is putting underground resources at the center of social unrest and political debates. France faced a decline of its oil and gas activity in the 1990s, followed by a renewal with subsurface activity in the late 2000s using enhanced oil recovery techniques. An industrial demonstrator for carbon capture and storage was developed between 2010 and 2013 , while projects targeting unconventional oil and gas were pushed forward between 2008 and 2011 before eventually being canceled. We analyze how the credibility, legitimacy, and governance of those techniques were developed and how conflicts made the role of the subsurface for energy transition the target of political choices. The level of political and industrial support and social protest played a key role in building project legitimacy, while the types of narratives and their credibility determined the distinct trajectories of hydraulic fracturing and carbon capture and storage in France. The conflicts over enhanced oil recovery techniques are also explained through the critical assessment of the governance framework that tends to exclude civil society stakeholders. We suggest that these conflicts illustrated a new type of politicization of the subsurface by merging geostrategic concerns with social claims about governance, ecological demands about pollution, and linking local preoccupations to global climate change.


Environments ◽  
2018 ◽  
Vol 5 (10) ◽  
pp. 108 ◽  
Author(s):  
Tryfonas Pieri ◽  
Alexandros Nikitas ◽  
Arturo Castillo-Castillo ◽  
Athanasios Angelis-Dimakis

Carbon capture and utilization (CCU) is recognized by the European Union, along with carbon, capture and storage (CCS), as one of the main tools towards global warming mitigation. It has, thus, been extensively studied by various researchers around the world. The majority of the papers published so far focus on the individual stages of a CCU value chain (carbon capture, separation, purification, transportation, and transformation/utilization). However, a holistic approach, taking into account the matching and the interaction between these stages, is also necessary in order to optimize and develop technically and economically feasible CCU value chains. The objective of this contribution is to present the most important studies that are related to the individual stages of CCU and to perform a critical review of the major existing methods, algorithms and tools that focus on the simulation or optimization of CCU value chains. The key research gaps will be identified and examined in order to lay the foundation for the development of a methodology towards the holistic assessment of CCU value chains.


Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3599 ◽  
Author(s):  
Martinez-Fernandez ◽  
deLlano-Paz ◽  
Calvo-Silvosa ◽  
Soares

Carbon mitigation is a major aim of the power-generation regulation. Renewable energy sources for electricity are essential to design a future low-carbon mix. In this work, financial Modern Portfolio Theory (MPT) is implemented to optimize the power-generation technologies portfolio. We include technological and environmental restrictions in the model. The optimization is carried out in two stages. Firstly, we minimize the cost and risk of the generation portfolio, and afterwards, we minimize its emission factor and risk. By combining these two results, we are able to draw an area which can be considered analogous to the Capital Market Line (CML) used by the Capital Asset Pricing model (CAPM). This area delimits the set of long-term power-generation portfolios that can be selected to achieve a progressive decarbonisation of the mix. This work confirms the relevant role of small hydro, offshore wind, and large hydro as preferential technologies in efficient portfolios. It is necessary to include all available renewable technologies in order to reduce the cost and the risk of the portfolio, benefiting from the diversification effect. Additionally, carbon capture and storage technologies must be available and deployed if fossil fuel technologies remain in the portfolio in a low-carbon approach.


Author(s):  
Ioannis Hadjipaschalis ◽  
Costas Christou ◽  
Andreas Poullikkas

In this work, a technical, economic and environmental analysis concerning the use of three major power generation plant types including pulverized coal, integrated gasification combined cycle (IGCC) and natural gas combined cycle, with or without carbon dioxide (CO2) capture and storage (CCS) integration, is carried out. For the analysis, the IPP optimization software is used in which the electricity unit cost and the CO2 avoidance cost from the various candidate power generation technologies is calculated. The analysis indicates that the electricity unit cost of IGCC technology with CCS integration is the least cost option with the lowest CO2 avoidance cost of all candidate technologies with CCS integration. Further investigation concerning the effect of the loan interest rate on the economic performance of the candidate plants revealed that up to a value of loan interest of approximately 5.7%, the IGCC plant with CCS retains the lowest electricity unit cost. Above this level, the natural gas combined cycle plant with post-combustion CCS becomes more economically attractive.


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