Simultaneous Experimental Analysis of Oil Content And Molecular Composition of Shale Fractions
Abstract The important research content and basis of exploration and development is to evaluate the reservoir property, oil bearing property, fluidity and compressibility of shale reservoir.The key of exploration and development is to evaluate the oil-bearing and fluidity of shale reservoir.In this paper, the "shale oil content and fine components synchronous experimental analysis device" is used. Five temperature ranges of 30 ℃-90 ℃, 90 ℃-150 ℃, 100 ℃- 200 ℃, 150 ℃-250 ℃ and 250 ℃-300 ℃ were adopted. The heating rate of each temperature segment was 25 ℃ / min, and the final temperature was kept constant for 5 min. The oil content of shale (pyrolysis S1) was cut into five fractions.Simultaneous determination of oil content and molecular composition of shale fractions,and the external standard method was used to evaluate the oil content and fluidity.The results show that the five fractions of shale are mainly composed of nC1-nC9 gas, nC10-nC15 gasoline, nC12-nC20 kerosene, nC15-nC22 diesel oil and nC18-nC26 heavy oil of the first member of Qingshangkou formation in Songliao basin.There are differences in the fractionation and oil content characteristics of samples with different maturity in different wells.The parent material, properties and quality of crude oil are reflected in shale. The higher the maturity of shale oil is, the more light components are, the larger the light / heavy ratio parameter value of (gasoline + kerosene + diesel) and heavy oil is, the better the fluidity is, and the easier to exploit effectively.