A Solution-processed Inorganic Emitter with High Spectral Effectiveness for Efficient Daytime Radiative Cooling in Hot Humid Climates
Abstract Daytime radiative cooling provides an eco-friendly solution to space cooling with zero energy consumption. Despite significant advances, most state-of-the-art radiative coolers show broadband infrared emission with low spectral effectiveness, which limits their cooling temperatures and climate applicabilities, especially in hot humid regions. Here we report an all-inorganic narrowband cooler comprising a solution-derived SiOxNy layer sandwiched between a reflective substrate and a self-assembly monolayer of SiO2 microspheres. It shows a high and diffusive solar reflectance (96%) and strong infrared-selective emittance (94.6%) with superior spectral effectiveness (1.44). Remarkable subambient cooling of up to 5°C was achieved under high humidity without any solar shading or convection cover at noontime in a subtropical coastal city, Hong Kong. Owing to the all-inorganic hydrophobic structure, the emitter showed outstanding resistance to ultraviolet and water in the long-term durability tests. The scalable solution-based fabrication renders this stable high-performance emitter promising for large-scale deployment in various climates.