scholarly journals Are solution processed CsPbI3 perovskite nanocrystalline films similar to traditional crystalline semiconductors?

Author(s):  
Kanishka Kobbekaduwa ◽  
Exian Liu ◽  
Qian Zhao ◽  
Pan Adhikari ◽  
Chendi Xie ◽  
...  

Abstract We use ultrafast photocurrent spectroscopy with a sub-25 picosecond resolution to address a long-standing question in emergent perovskite materials: are solution-processed CsPbI3 perovskites nanocrystal films similar to their counterparts semiconductors including GaAs and Si? Prior to carrier trapping, all semiconductors show similar transition of transport mechanism from the band-like transport due to the longitudinal optical (LO) phonon scattering in the higher temperature region to a combination of band-like and hopping transport mechanisms in the lower temperature region. The critical difference is that CsPbI3 demonstrate the strongest carrier-LO phonon interaction among all semiconductors, most likely due to the unique cation-halogen bond arrangements within the highly symmetric lattice structure. This ultrafast dynamics work establish a foundation of fundamental carrier transport understating for perovskite optoelectronics.

2010 ◽  
Vol 160 (15-16) ◽  
pp. 1623-1626 ◽  
Author(s):  
Myungkwan Song ◽  
Jin Su Park ◽  
Chul-Hyun Kim ◽  
Jang Soo Kim ◽  
Yeong-Soon Gal ◽  
...  

ACS Nano ◽  
2014 ◽  
Vol 8 (9) ◽  
pp. 9324-9331 ◽  
Author(s):  
Michael Engel ◽  
Katherine E. Moore ◽  
Asiful Alam ◽  
Simone Dehm ◽  
Ralph Krupke ◽  
...  

2017 ◽  
Vol 10 (2) ◽  
pp. 024103 ◽  
Author(s):  
Toshinori Matsushima ◽  
Sunbin Hwang ◽  
Shinobu Terakawa ◽  
Takashi Fujihara ◽  
Atula S. D. Sandanayaka ◽  
...  

2017 ◽  
Vol 7 (1) ◽  
Author(s):  
Jason D. Forster ◽  
Jared J. Lynch ◽  
Nelson E. Coates ◽  
Jun Liu ◽  
Hyejin Jang ◽  
...  

2017 ◽  
Vol 19 (27) ◽  
pp. 17560-17567 ◽  
Author(s):  
Tongzhou Wang ◽  
Congcong Liu ◽  
Fengxing Jiang ◽  
Zhaofen Xu ◽  
Xiaodong Wang ◽  
...  

The content of rGO could alter the carrier transport barrier, and the optimizing power factor was achieved at rGO–MS2 junctions.


2016 ◽  
Vol 40 (4) ◽  
pp. 511-520 ◽  
Author(s):  
Chun-Lang Yeh

The effects of choke ring dimension on the thermal and fluid flow in a practical SRU (sulfur recovery unit) thermal reactor are investigated numerically. It is found that zone 1 is a higher temperature region. In contrast, zone 2 is a lower temperature region. The average temperature for the rich oxygen supply is higher than that of normal oxygen supply. Without a choke ring, the temperature difference between zone 1 and zone 2 is smaller and the temperature in zone 1 becomes lower while the temperature in zone 2 becomes higher. In addition, the average temperature in zone 1 and the sulfur concentration at exit are the lowest without a choke ring. The reactor with a choke ring height of 0.74 m has the lowest peak temperature and the largest sulfur concentration at exit. Finally, with a choke ring height of 1.11 m, the blockage effect of the choke ring leads to the largest peak skin friction coefficient.


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