Organic Matter Oxidation Potential Determination in a Periodically Flooded Histosol under Sugarcane

2004 ◽  
Vol 68 (3) ◽  
pp. 994 ◽  
Author(s):  
D. R. Morris ◽  
B. Glaz ◽  
S. H. Daroub
2007 ◽  
Vol 55 (10) ◽  
pp. 145-153 ◽  
Author(s):  
T. Ölmez ◽  
I. Kabdaşlı ◽  
O. Tünay

In this study, the effects of the phosphonic acid based sequestering agent EDTMPA used in the textile dye baths on colour and organic matter removal by ozone oxidation was experimentally investigated. Procion Navy HEXL dyestuff that has been commonly used for the reactive dyeing of cellulose fibers was selected as the model component. The organic matter oxidation by ozone was determined to obey the pseudo-first order kinetics as they are treated singly or in combination. COD removal rates obtained from pseudo-first order reaction kinetics showed that oxidation of Navy HEXL alone (0.0947 L/min) was faster than that of EDTMPA (0.0171 L/min) and EDTMPA with dye (0.0155 L/min) at pH 3.0. It was also found that reaction rates of single EDTMPA removal and EDTMPA and dye mixture removal increased as the reaction pH was increased from 3.0 to 10.5.


Cerâmica ◽  
2015 ◽  
Vol 61 (360) ◽  
pp. 420-427
Author(s):  
C. P. de Moura ◽  
M. V. S. Fernandes ◽  
L. R. D. da Silva ◽  
L. C. G. Vasconcellos ◽  
R. F. do Nascimento ◽  
...  

Abstract Nontronite samples pillared with aluminium (Pt/Al-PilM) and aluminium-lanthanum (Pt/AlLa-PilM) were prepared from natural nontronite, characterized and tested as catalyst in n-octane hydroisomerization reaction. The results were compared with those obtained from the same reaction using commercial Y-zeolite impregnated with platinum (Pt-Y). Experiments with commercial zeolite show that platinum is essential to maintain the reactional selectivity of the products. The conversion capacities of (Pt/Al- PilM) and (Pt/AlLa-PilM) were 70% and 40%, respectively, surpassing the Pt-Y performance of 30%, but with the same selectivity. X-ray diffraction data show that organic matter oxidation followed by cationic homogenization is of paramount importance for pillared clay preparation.


1985 ◽  
Vol 65 (3) ◽  
pp. 593-597 ◽  
Author(s):  
N. M. MILES ◽  
M. SCHNITZER ◽  
C. R. DE KIMPE

Oxidation of organic matter with H2O2 produced substantial amounts of NH3 which was then fixed by vermiculite, causing partial or complete collapse and converting the mineral to a mica-like product. The collapse of the mineral was indicated by shifts in the 001 spacing from 1.476 to 1.030 nm and the appearance of a well-defined band at 1430 cm−1 in the IR spectrum, indicative of the presence of NH4+ in the interlayer positions of the clay. Our data suggest that: (a) the transformation of vermiculite to mica during H2O2 oxidation may result in underestimation of the vermiculite content of soils by XRD, and (b) the wide occurrence of mixed-layer minerals in soils may in part have resulted from the fixation of NH3 liberated from the microbial mineralization of organically bound N. Key words: Ammonia, X-ray diffraction, IR spectrophotometry, mixed-layer minerals, H2O2 pretreatment


Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-19 ◽  
Author(s):  
Galina P. Kayukova ◽  
Anastasiya N. Mikhailova ◽  
Igor P. Kosachev ◽  
Dmitry A. Emelyanov ◽  
Mikhail A. Varfolomeev ◽  
...  

The features of the oil-bearing capacity of the productive strata of Permian deposits in the interval of 117.5-188.6 m along the section of individual wells of the Ashal’cha field of heavy superviscous oil (Tatarstan) were revealed depending on the content, composition, and thermal effects of organic matter (OM) oxidation in the rocks. It is shown that the rocks are very heterogeneous in their mineral composition and in the content of both free hydrocarbons by extraction with organic solvents and insoluble OM closely associated with the rock. The total content of OM in rocks varies from 1.72 to 9.12%. The features of group and hydrocarbon composition of extracts from rocks are revealed depending on their mineral composition and the content of organic matter in them. According to the molecular mass distribution of alkanes of normal and isoprenoid structure, extracts from rocks are differentiated according to three chemical types of oil: type A1, in which n-alkanes of composition C14 and above are present, and types A2 and B2, in which n-alkanes are destroyed to varying degrees by processes microbial destruction, which indicates a different intensity of biochemical processes in productive strata of Permian sediments. These processes lead to a decrease in the amount of OM in the rocks and an increase in the content of resins and asphaltenes in the oil extracted from them, as well as an increase in the viscosity of the oil. Using the method of differential scanning calorimetry of high pressure, it was found that the studied rock samples differ from each other in quantitative characteristics of exothermic effects in both low-temperature (LTO) 200-350°С and high-temperature (HTO) 350-600°С zones of OM oxidation. The total thermal effect of destruction processes of OM depends on the content of OM in the rocks and its composition. The research results show that when heavy oil is extracted using thermal technologies, the Permian productive strata with both low and high OM contents will be involved in the development, and the general thermal effect of the oxidation of which will contribute to increased oil recovery.


Soil Science ◽  
1982 ◽  
Vol 134 (4) ◽  
pp. 226-232 ◽  
Author(s):  
JOHN E. MANGLER ◽  
ROBERT L. TATE

2008 ◽  
Vol 8 (6) ◽  
pp. 673-680
Author(s):  
Byoung-Ho Lee ◽  
Won-Chul Song ◽  
Hyun-Joo Yang ◽  
Jeong-Hyun Kim ◽  
Young-Suk Kim

Owing to the strong oxidation potential, ozone has been used widely in advanced water treatment. However, degradation and oxidation efficiencies of NOM (Natural Organic Matter) by the traditional ozone contact system are normally believed to be low. Oxidation efficiency of NOM by the PHOC (Pressurized High Ozone Contact) method was compared with that by the MOC (Mechanical Ozone Contact, the traditional system) method for the drinking water treatment. Sand filtered water of the drinking water treatment plant was used for experimental samples. Removal rates of UV254 absorbance, KMnO4 consumption and DOC by the MOC system were 18.4%, 2.39%, and 2.72% respectively with 1 mg-O3/L. On the other hand, removal rates of KMnO4 consumption, TOC, DOC, UV254 absorbance and SUVA by the PHOC system were 8–20%, 7.52–34.4%, 6.65–18.2%, 37.4–60.8% and 33.8–60% with 1–3 mg/L of ozone concentrations. Concentration of BDOC after ozone application was 0.003–0.044 mg/L by the MOC method, while 0.084–0.044 mg/L by the PHOC method with 1–3 mg/L of ozone concentrations. Concerning molecular weight distribution, fractions of NOM below 1 kDa were increased by the PHOC method of ozone application. Analysis shows that the reason for overall enhancement of the treatment efficiencies by the PHOC system is because contacting surface area of numerous micro ozone bubbles was increased dramatically in the PHOC system, and oxidation potential was enhanced by increased ozone concentrations in the ozone contact tank. Thus, it is understood that the PHOC method is a more efficient system for ozone application than the traditional MOC system in drinking water treatment process.


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