scholarly journals Improving Photoluminescence Quantum Yield of CdTe Quantum Dots Using a Binary Solvent (Water + Glycerin) in the One-Pot Approach Synthesis

2021 ◽  
Author(s):  
Lucas da Rosa ◽  
Isabella Aversa ◽  
Ellen Raphael ◽  
André Polo ◽  
Alfredo Duarte ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Quantum Yield ◽  
Cdte Quantum Dots ◽  
Molar Ratio ◽  
Binary Solvent ◽  
One Pot ◽  
Solvent Water ◽  
Water Solvent ◽  
Photoluminescence Quantum Yield

The present work describes the comparison of the optical and structural properties between CdTe quantum dots (QD) synthesized in water and in the binary solvent (water + glycerin) via one-pot approach synthesis. The optical properties of the nanocrystals obtained with different synthesis parameters were characterized by UV-visible and photoluminescence spectroscopies. The structural chracterization were performed by Fourier transform infrared spectroscopy (FTIR), zeta potential, size-distribution by dynamic light scattering (DLS), X-ray diffraction (XRD), and also by high-resolution transmission electron microscopy (HRTEM). The optical properties of CdTe QD when synthesized in the binary solvent were better, resulting in the increase of photoluminescence quantum yield (φƒ). The CdTe QD prepared in 120 min, at pH 10.0, in the Cd:Te molar ratio 20:1, using the molar ratio 1:1.5 of Cd:TGA (thioglycolic acid), exhibited a narrow photoluminescence band and enhanced φƒ for the samples synthesized in a binary solvent in comparison to water solvent (58.4 and 49.5%, respectively).

Effective blue-violet photoluminescence through lanthanum and fluorine ions co-doping for CsPbCl3 perovskite quantum dots

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2484-2491 ◽  
Author(s):  
Yue Zhai ◽  
Xue Bai ◽  
Gencai Pan ◽  
Jinyang Zhu ◽  
He Shao ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Quantum Yield ◽  
Feasible Method ◽  
Co Doping ◽  
Photoluminescence Quantum Yield ◽  
Perovskite Quantum Dots ◽  
Fluorine Ions

Co-doping of cation (La3+) and anion (F−) ions is a feasible method to improve the optical properties of CsPbCl3 QDs, and high photoluminescence quantum yield of 36.5% is achieved in CsPb(Cl0.7F0.3)3:La3+ QDs.

scholarly journals AgCl-doped CdSe quantum dots with near-IR photoluminescence

2017 ◽  
Vol 8 ◽  
pp. 1156-1166 ◽  
Author(s):  
Pavel Aleksandrovich Kotin ◽  
Sergey Sergeevich Bubenov ◽  
Natalia Evgenievna Mordvinova ◽  
Sergey Gennadievich Dorofeev
Keyword(s):  
Quantum Dots ◽  
Optical Properties ◽  
Quantum Yield ◽  
Reaction Yield ◽  
Cdse Quantum Dots ◽  
Optimal Conditions ◽  
Spherical Nanoparticles ◽  
Near Ir ◽  
Photoluminescence Quantum Yield

We report the synthesis of colloidal CdSe quantum dots doped with a novel Ag precursor: AgCl. The addition of AgCl causes dramatic changes in the morphology of synthesized nanocrystals from spherical nanoparticles to tetrapods and finally to large ellipsoidal nanoparticles. Ellipsoidal nanoparticles possess an intensive near-IR photoluminescence ranging up to 0.9 eV (ca. 1400 nm). In this article, we explain the reasons for the formation of the ellipsoidal nanoparticles as well as the peculiarities of the process. The structure, Ag content, and optical properties of quantum dots are also investigated. The optimal conditions for maximizing both the reaction yield and IR photoluminescence quantum yield are found.

Determination of particle size distribution of water-soluble CdTe quantum dots by optical spectroscopy

RSC Advances ◽  
2014 ◽  
Vol 4 (68) ◽  
pp. 36024-36030 ◽  
Author(s):  
J. C. L. Sousa ◽  
M. G. Vivas ◽  
J. L. Ferrari ◽  
C. R. Mendonca ◽  
M. A. Schiavon
Keyword(s):  
Quantum Dots ◽  
Particle Size ◽  
Optical Properties ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Water Soluble ◽  
Cdte Quantum Dots ◽  
One Pot ◽  
The One

In the present study, we report the synthesis of glutathione (GSH) capped CdTe quantum dots (QDs) using the one-pot approach as well as their optical properties.

Simple One-Pot Synthesis and High-Resolution Patterning of Perovskite Quantum Dots Using a Photocurable Ligand

2021 ◽  
Author(s):  
Byeong M. Oh ◽  
Yong-Cheol Joung ◽  
Jian Zheng ◽  
Na Young Cho ◽  
Myungkwan Song ◽  
...  
Keyword(s):  
Quantum Dots ◽  
High Resolution ◽  
Quantum Yield ◽  
Color Purity ◽  
One Pot ◽  
One Pot Synthesis ◽  
Photoluminescence Quantum Yield ◽  
Perovskite Quantum Dots ◽  
High Color Purity

Perovskite quantum dots (PeQDs) have a high-photoluminescence quantum yield with high color purity, which meets the latest requirements of the display industry. However, the difficulty in patterning of PeQDs limits...

Photoluminescent Properties of TGA-Capped CdTe Quantum Dots

2011 ◽  
Vol 306-307 ◽  
pp. 1262-1265 ◽  
Author(s):  
Zhi Min Yuan ◽  
Jie Yang ◽  
Yu Lan Zhang ◽  
Rui Li Zhang ◽  
Ning Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Quantum Yield ◽  
Cdte Quantum Dots ◽  
Molar Ratio ◽  
Average Lifetime ◽  
Capping Agent ◽  
Peak Wavelength ◽  
Preparation Conditions ◽  
Cdte Qds ◽  
Increasing Temperature

An environmentally friendly synthesis was developed to fabricate aqueous CdTe quantum dots (QDs) using thilglycolic acid (TGA) as a capping agent. Optimal preparation conditions including pH (11.2) and TGA/Cd molar ratio (1.5:1) resulted in CdTe QDs with high photoluminescence (PL) quantum yield up to 56%. The TGA-capped CdTe QDs exhibited tunable PL from green to red. Lifetime measurement indicated that the average lifetime of the TGA-capped QDs increased with increasing their sizes (27.5 and 37.2 ns for the QDs with PL peak wavelength of 607 and 636 nm, respectively). The PL of the QDs revealed the dependence of temperature, in which the QDs exhibited a red-shifted PL peak with increasing temperature. Such PL behavior depended strongly on the QD sizes.

scholarly journals Engineering Sr-doping for enabling long-term stable FAPb1−xSrxI3 quantum dots with 100% photoluminescence quantum yield

2021 ◽  
Vol 9 (5) ◽  
pp. 1555-1566
Author(s):  
Andrés F. Gualdrón-Reyes ◽  
David F. Macias-Pinilla ◽  
Sofia Masi ◽  
Carlos Echeverría-Arrondo ◽  
Said Agouram ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Quantum Yield ◽  
Toxic Metals ◽  
Environmentally Friendly ◽  
Photoluminescence Quantum Yield ◽  
Improved Performance ◽  
Pb Substitution

The Pb substitution in quantum dots (PQDs) with lesser toxic metals has been widely searched to be environmentally friendly, and be of comparable or improved performance compared to the lead-perovskite.

Poly(Vinylidene Fluoride)-Passivated CsPbBr3 Perovskite Quantum Dots with Near-Unity Photoluminescence Quantum Yield and Superior Stability

2021 ◽  
Author(s):  
Lin Yang ◽  
Bowen Fu ◽  
Xu Li ◽  
Hao Chen ◽  
Lili Li
Keyword(s):  
Quantum Dots ◽  
Quantum Yield ◽  
Vinylidene Fluoride ◽  
Excellent Performance ◽  
Inorganic Perovskite ◽  
Photoluminescence Quantum Yield ◽  
Poly Vinylidene Fluoride ◽  
Perovskite Quantum Dots ◽  
Optoelectronic Applications ◽  
Pl Quenching

All inorganic perovskite quantum dots (QDs) have received great attention owing to their excellent performance in optoelectronic applications. However, they often suffer from the defect-related photoluminescence (PL) quenching and phase...

Room temperature synthesis of Sn2+ doped highly luminescent CsPbBr3 quantum dots for high CRI white light-emitting diodes

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Yan ◽  
Qionghua Mo ◽  
Shuangyi Zhao ◽  
Wensi Cai ◽  
Zhigang Zang
Keyword(s):  
Quantum Dots ◽  
Quantum Yield ◽  
White Light ◽  
Room Temperature ◽  
Temperature Synthesis ◽  
Light Emitting ◽  
Photoluminescence Quantum Yield ◽  
Hot Injection ◽  
White Light Emitting Diodes ◽  
Cspbbr3 Quantum Dots

With a high photoluminescence quantum yield (PLQY) being able to exceed 90% for those prepared by hot injection method, CsPbBr3 quantum dots (QDs) have attracted intensive attentions for white light-emitting...

One-pot synthesis of double silane-functionalized carbon dots with tunable emission and excellent coating properties for WLEDs application

2021 ◽  
Author(s):  
Wenbing Cao ◽  
Yuhan Wu ◽  
Xin Li ◽  
Xuanfeng Jiang ◽  
Yuhong Zhang ◽  
...  
Keyword(s):  
Optical Properties ◽  
Carbon Dots ◽  
Great Influence ◽  
Alkoxy Group ◽  
Color Temperature ◽  
Molar Ratio ◽  
Coating Properties ◽  
One Pot ◽  
Light Emitting ◽  
Light Emitting Devices

Abstract Silane-functionalized carbon dots (SiCDs) can be exploited as effective color converting materials for the solid-state light-emitting devices. However, most of SiCDs reported thus far have shown photoluminescence emissions in the blue and green spectral range, which limit them to construct an efficient white light-emitting diodes (WLEDs) due to the lack of long-wavelength emission. Herein, a series of double silane-functionalized carbon dots (DSiCDs) were prepared via a one-step solvothermal method. The results show that the organic functional group of the silane has great influence on the optical properties of DSiCDs and the number of alkoxy group in the silane has great influence on coating properties of DSiCDs. In addition, the DSiCDs prepared by (3-aminopropyl)triethoxysilane and N-[3-(Trimethoxysilyl)propyl]ethylenediamine with molar ratio of 7:3 show excellent optical properties with the maximum emission at 608 nm under 400 nm excitation. Furthermore, they can be completely dried within 1 h at room temperature to form fluorescent coating with high stability and strong adhesion to the substrate. Together with their excellent optical and coating properties, they can be directly coated on LED chips to prepare WLEDs, with a CIE coordinate of (0.33,0.31), color rendering index of 81.6, and color temperature of 5774 K.

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