Analisis Aspek Molekuler Biomarka Alkana Bercabang Core Badak 1/208 Muara Badak, Kutai Kartanegara, Kalimantan Timur

2015 ◽  
Vol 1 (1) ◽  
pp. 26
Author(s):  
R. Arizal Firmansyah ◽  
R. Y. Perry Burhan

Study compound biomarka branched alkanes on core 1/208 Rhinos have done to contribute to the activities of oil exploration wells 1/208 Muara Badak Badak, East Kalimantan's Kutai Kartanegara-through core biomarka profile branched alkanes. Core samples extracted by alternately with solvent mixture of toluene-methanol (3: 1) and chloroform-methanol (3: 1). Then fractionated by Column Chromatography and Thin Layer Chromatography to obtain aliphatic hydrocarbon fraction. Fractions obtained were identified using Gas Chromatography-Mass Spectrometry.The content biomarka aliphatichydrocarbon fraction were identified, among others, iso and anteiso alkanes, mono and trimethyl alkanes. Compounds iso and anteiso alkanes, and alkyl alkane other, providing information that the source of organic material core samples I and II is derived from microorganisms prokaryotic or biogenic precursor derived from cyanobacteria (marine microorganisms) and homologous monomethyl alkanes found in core samples II closer homologous series monomethyl alkanes found in sediments and oil and Precambrian Proterozoic era, so it can be said that the core sample II core samples older than I.

2011 ◽  
Vol 255-260 ◽  
pp. 4176-4180
Author(s):  
Yong Li Xu ◽  
Hao Jiang

The Bailey method put forward three very significant parameters CA, FAc and FAf, provided an effective way for the asphalt mixture gradation test, and it could evaluate the gradation of asphalt pavement core sample effectively. Based on the analysis of common gradation, the parameters of formula was revised, the application conditions of AC mixture and the parameter range for AC mixture was proposed, that based on the gradation which is standard recommended and the core samples in different pavement conditions. The results proposed theoretical basis for gradation examination correctly with the Bailey method.


1985 ◽  
Vol 25 (04) ◽  
pp. 502-514 ◽  
Author(s):  
Liang C. Shen

Abstract This paper describes an automated laboratory system that can measure accurately the dielectric properties of core samples in the ultrahigh-frequency properties of core samples in the ultrahigh-frequency (UHF) range. The system consists of a precision coaxial-line sample holder, a network analyzer, a plotter, a printer, and a desk computer. The computer is for measurement control, data acquisition, and data analysis. A new method is developed to measure and to compensate for the error of the network analyzer system. This method uses a brass sample and does not require standard terminations. A procedure for core sample preparation is also recommended to ensure accuracy of the data. Introduction The electromagnetic propagation tool (EPT) is a relatively new wireline sonde developed by Schlumberger for detection and quantification of hydrocarbon. It is operated at 1.1 GHz, which is in the UHF band of the electromagnetic spectrum. The EPT sonde measures the dielectric constant of the formation. Because water has a much higher dielectric constant (about 80 units) than oil (about 2 units) and gas (about 1 unit), the EPT sonde can distinguish hydrocarbon-bearing zones from the water-bearing zones even when the formation water is fresh. The dielectric constant of water at UHF is not very sensitive to salinity. Consequently, EPT is particularly useful in situations where the formation water resistivity is variable or unknown, as a result, for example, of water, steam, or chemical flooding. The EPT log displays the travel time and the rate of attenuation of the electromagnetic wave in the formation. From these data, the calculated complex dielectric constant of the formation may be calculated. This complex dielectric constant is related to water saturation, Sw, by an empirical formula called the complex refractive index method (CRIM): ............................(1) where = porosity, = dielectric constant of the water in the rock, = dielectric constant of oil or gas, and = dielectric constant of the rock grain. To verify the validity of the CRIM formula given by Eq. 1, a computer-controlled laboratory system has been set up to measure the dielectric constants of saturated core samples, dry core samples, and oils. The same system is now being used for routine measurements of cores for EPT log interpretation. Measurement Techniques Two basic techniques can be used to measure the complex dielectric constant of a saline-water-saturated rock at frequencies higher than 100 MHz. The first is the coaxial-line and waveguide method, and the other is the resonant-cavity method. We describe these methods and point out their advantages and disadvantages. Fig. 1 shows the configuration of the coaxial-line and waveguide method. In Figs. 1a and 1b, we see that the core sample is machined into a circular cylinder with a circular concentric hole drilled to fit the coaxial line. The line consists of an outer conductor and an inner conductor. In Fig. 1c, we see that the core sample is machined into a rectangular column to fit into a rectangular waveguide. The latter is a rectangular metal pipe without a central conductor. pipe without a central conductor. Longitudinal slots are cut along the outer conductor of the coaxial line (Fig. 1b) or on top of the rectangular waveguide (Fig. 1c) to allow a probe to be inserted partially into the region where electromagnetic fields are present. The probe travels along the length of the structure and detects the amplitude and the phase of the electromagnetic fields present in the structure. During the measurement, an electromagnetic wave of the selected frequency is sent propagating down the line or the waveguide until it encounters the core sample. Reflection occurs so that part of the wave is absorbed, and part is reflected and travels in the reverse direction. The phase and the amplitude of the reflected wave are determined by the complex dielectric constant of the sample. The reflected wave interacts with the incident wave and creates an interference pattern called the standing wave pattern. The complex dielectric constant of the core sample can be determined from the standing wave pattern recorded by the traveling probe. This method was used by Poley et al. for sandstone samples up to 1.2 GHz. It was also used by Tam to test nine dry rocks, mainly sedimentary, in the frequency range 150 to 1000 MHz. The rectangular waveguide was used by Roberts and Von Hippel to measure a variety of materials at 5 GHz. The configuration shown in Fig. 1a was used by Rau and Wharton to measure formation samples in the frequency range 500 MHz to 1.1 GHz. This arrangement calls for placing the sample at the center, rather than at the end, of a coaxial line. The amplitudes and the phases of both the reflected and the transmitted waves are recorded and are called the scattering matrix parameters. parameters. SPEJ p. 502


Author(s):  
Elena P. Osipova ◽  
◽  
Angela G. Astarkina ◽  
Sergey V. Astarkin ◽  
Daniil A. Strelnikov ◽  
...  

To assess the influence of zeolite group minerals on the migration of reservoir fluids in terrigenous deposits, complex (X-ray and gas-geochemical) studies of core material in the Yamal oil and gas region field were conducted. 54 core samples from the Pyakyakhinsky and Yuzhno-Messoyakhsky deposits were studied including 43 zeolitized and 11 non-zeolitized samples. The core samples were studied by gas chromatography to determine the content of hydrocarbons adsorbed in the pore space of the core, as well as by X-ray diffractometry to determine the mineral composition of the samples under study. The regularities of hydrocarbons distribution in the studied samples depending on the degree of their zeolization are established. The differences in the distribution of hydrocarbons in zeolitized and non-zeolitized siltstones have their own explanation. Having an ordered crystal structure and a certain size of the entrance windows zeolites are able to sorb.


1964 ◽  
Vol 19 (2) ◽  
pp. 315-318 ◽  
Author(s):  
H. J. Clitheroe

Thin-layer chromatography has been adapted to separate material of high biological potency from much of the inactive material contained in component A of the menstrual stimulant. The chromatoplates were developed with solvent mixture of chloroform, methanol, and water (60:10:1). Visualization of the spots was carried out by various methods; ultraviolet fluorescence of the charred material appeared to be the most sensitive. Samples of ricinoleic and phloionolic acids were used as reference standards. The biological active material of the component A preparations always ran just in front of phloionolic acid. Menstrual fluid was collected in vaginal cups; total volume and crude liquid extract measurements were also carried out on the fluid. uterine smooth muscle stimulant; menstrual flow rates Submitted on October 1, 1963


1985 ◽  
Vol 25 (06) ◽  
pp. 909-916 ◽  
Author(s):  
A.T. Watson ◽  
P.D. Kerig ◽  
R.W. Otter

Abstract Homogeneous core samples are needed for EOR experiments. We have devised a simple test for detecting the presence of nonuniformities in cores. The test consists of presence of nonuniformities in cores. The test consists of measuring the pressure drop across the core during a two-phase immiscible displacement experiment. We show that for a constant injection rate, the pressure drop will be linear with time provided that the core is homogeneous. In situations for which the initial section of the core is homogeneous, but the properties are not uniform in a latter section of the core, the location of the position where the rock properties fast change may be approximately determined. The effect of heterogeneities on the pressure-drop profile is demonstrated with analytical solutions and profile is demonstrated with analytical solutions and laboratory experiments. Introduction Core samples are used routinely for EOR or relative permeability experiments. For such experiments, selection permeability experiments. For such experiments, selection of a homogeneous core sample is necessary. Visual inspection of the core is not sufficient to ensure homogeneity. Often, vugs or shale barriers may be present, which may invalidate experimental results. In this paper, a simple test to detect the presence of core heterogeneities is devised. The scale of heterogeneities considered corresponds to the usual macroscopic description of porous medium properties. The properties of a porous medium (e.g., the properties. The properties of a porous medium (e.g., the porosity and permeability) at any particular location refer porosity and permeability) at any particular location refer to average quantities for some appropriate (small) representative volume element. In this way, each (locally averaged) property is defined at every point within the medium, the collection of which defines the representation of each property as a function of position. If each macroscopic property has the same value at all positions, the medium is said to be homogeneous. Otherwise, the medium is heterogeneous. A more complete discussion of macroscopic properties and heterogeneities can be found in Refs. 1 through 3. The macroscopic scale is a natural one to use for core selection because attempts to model coreflood experiments or to estimate properties of the porous medium on the basis of measured flow data generally will use mathematical models that use macroscopic properties. A homogeneous core sample is necessary for the experimental determination of relative permeabilities from displacement experiments. Explicit methods for estimating relative permeabilities from displacement data are based on the permeabilities from displacement data are based on the Buckley-Leverett model, in which the core is assumed to be homogeneous. The absolute permeability generally is determined from a single-phase flow experiment and thus represents an average value for the entire core. If the core is not homogeneous, so that the absolute permeability takes on different values in different locations permeability takes on different values in different locations in the core, errors will appear in the relative permeability estimates. Although the magnitude of the errors will depend on many factors, a macroscopically homogeneous sample is always preferred. Note that heterogeneities may also be defined on a microscopic scale. A porous medium that is macroscopically homogeneous may be microscopically heterogeneous. In fact, this typically would be the case because few real porous media structures are microscopically homogeneous. In this paper, we develop a test for detecting the presence of macroscopic heterogeneities in core samples. presence of macroscopic heterogeneities in core samples. The test is conducted by displacing the fluid that initially saturates the porous medium with a second fluid that is immiscible with the displaced fluid. The pressure drop across the core is recorded up to the time of breakthrough of the displacing fluid. The test is based on the observation that, with a constant injection rate and incompressible fluids, the pressure drop will be linear with time provided that the core is homogeneous. It is also shown provided that the core is homogeneous. It is also shown that, if the porosity and permeability for a heterogeneous core may be approximated as functions of the longitudinal spatial dimension, the pressure drop will be linear with time provided that the region in which both fluid phases are flowing simultaneously has uniform properties. The detection of heterogeneities by this method is discussed and illustrated with analytical solutions for the displacement process and with laboratory experimental data. Theory We consider here a displacement experiment with two incompressible fluids. Initially, the core is saturated with one fluid and the other fluid is injected at one end. For example, if the core initially contains only oil or air, water might be injected at one end. The core could contain the irreducible saturation of the displacing fluid initially, although this is not experimentally convenient and is not necessary for conducting the test. The pressure drop across the core is recorded through the time of breakthrough of the displacing fluid at the core outlet. SPEJ P. 909


2011 ◽  
Vol 74 (8) ◽  
pp. 1334-1337 ◽  
Author(s):  
DANIEL F. JOHNS ◽  
CHRISTY L. BRATCHER ◽  
CHRIS R. KERTH ◽  
THOMAS McCASKEY

Translocation of Escherichia coli among beef loins processed with a mechanical tenderizer was evaluated. Two beef striploins were inoculated on the lean side with 6.4 to 7.2 ml of a nalidixic acid–resistant E. coli at 8.2 to 10.1 log CFU/ml. Total E. coli inoculated onto striploins ranged from 1.12 × 109 to 9.10 × 1010 CFU. Striploins were passed once (lean side up, anterior end first) through a mechanical blade tenderizer. After the inoculated striploins had been tenderized, uninoculated beef striploins (n = 5) were passed once (lean side up, anterior end first) through the same mechanical tenderizer. This procedure was repeated twice for a total of 12 striploins. Six core samples were taken from each striploin starting with the anterior end. Each core was cut into six sections; sections 1 through 4 represented the top 4 cm of the core sample, and sections 5 and 6 represented the remaining part of the core split in half. After tenderization, E. coli levels were highest (P < 0.05) in loin 1. Loin 2 had higher levels (P < 0.05) than did loins 4, 5, and 6. No differences in E. coli levels (P > 0.05) were found among loins 3, 4, 5, and 6, for which levels were below the limit of detection. Levels of E. coli from section 1 were higher than those for all other sections. Section 2 had higher levels (P < 0.05) than did sections 3, 4, 5, and 6. E. coli recovery from section 6 was higher (P < 0.05) than that from sections 3, 4, and 5. No differences in E. coli recovery (P > 0.05) were found among sections 3, 4, and 5. Data indicate that even after inoculation of E. coli a high initial levels, contamination from one loin to another is quickly reduced to <10 CFU/g.


Author(s):  
Yelena I. Shtyrkova ◽  
Yelena I. Polyakova

The results of fossil diatoms investigation from the deltaic sediments are presented. Samples were obtained from the core DM-1 and two Holocene outcrops from the Damchik region of the Astrakhan Nature Reserve. In the core samples eight periods of sedimentation based on diatom analysis were identified: the sediments formed in shallow freshwater basins and deltaic channels. The samples from the outcrops were investigated in much greater detail.


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