A Test for Detecting Rock Property Nonuniformities in Core Samples (includes associated papers 15342 and 15842 )

1985 ◽  
Vol 25 (06) ◽  
pp. 909-916 ◽  
Author(s):  
A.T. Watson ◽  
P.D. Kerig ◽  
R.W. Otter

Abstract Homogeneous core samples are needed for EOR experiments. We have devised a simple test for detecting the presence of nonuniformities in cores. The test consists of presence of nonuniformities in cores. The test consists of measuring the pressure drop across the core during a two-phase immiscible displacement experiment. We show that for a constant injection rate, the pressure drop will be linear with time provided that the core is homogeneous. In situations for which the initial section of the core is homogeneous, but the properties are not uniform in a latter section of the core, the location of the position where the rock properties fast change may be approximately determined. The effect of heterogeneities on the pressure-drop profile is demonstrated with analytical solutions and profile is demonstrated with analytical solutions and laboratory experiments. Introduction Core samples are used routinely for EOR or relative permeability experiments. For such experiments, selection permeability experiments. For such experiments, selection of a homogeneous core sample is necessary. Visual inspection of the core is not sufficient to ensure homogeneity. Often, vugs or shale barriers may be present, which may invalidate experimental results. In this paper, a simple test to detect the presence of core heterogeneities is devised. The scale of heterogeneities considered corresponds to the usual macroscopic description of porous medium properties. The properties of a porous medium (e.g., the properties. The properties of a porous medium (e.g., the porosity and permeability) at any particular location refer porosity and permeability) at any particular location refer to average quantities for some appropriate (small) representative volume element. In this way, each (locally averaged) property is defined at every point within the medium, the collection of which defines the representation of each property as a function of position. If each macroscopic property has the same value at all positions, the medium is said to be homogeneous. Otherwise, the medium is heterogeneous. A more complete discussion of macroscopic properties and heterogeneities can be found in Refs. 1 through 3. The macroscopic scale is a natural one to use for core selection because attempts to model coreflood experiments or to estimate properties of the porous medium on the basis of measured flow data generally will use mathematical models that use macroscopic properties. A homogeneous core sample is necessary for the experimental determination of relative permeabilities from displacement experiments. Explicit methods for estimating relative permeabilities from displacement data are based on the permeabilities from displacement data are based on the Buckley-Leverett model, in which the core is assumed to be homogeneous. The absolute permeability generally is determined from a single-phase flow experiment and thus represents an average value for the entire core. If the core is not homogeneous, so that the absolute permeability takes on different values in different locations permeability takes on different values in different locations in the core, errors will appear in the relative permeability estimates. Although the magnitude of the errors will depend on many factors, a macroscopically homogeneous sample is always preferred. Note that heterogeneities may also be defined on a microscopic scale. A porous medium that is macroscopically homogeneous may be microscopically heterogeneous. In fact, this typically would be the case because few real porous media structures are microscopically homogeneous. In this paper, we develop a test for detecting the presence of macroscopic heterogeneities in core samples. presence of macroscopic heterogeneities in core samples. The test is conducted by displacing the fluid that initially saturates the porous medium with a second fluid that is immiscible with the displaced fluid. The pressure drop across the core is recorded up to the time of breakthrough of the displacing fluid. The test is based on the observation that, with a constant injection rate and incompressible fluids, the pressure drop will be linear with time provided that the core is homogeneous. It is also shown provided that the core is homogeneous. It is also shown that, if the porosity and permeability for a heterogeneous core may be approximated as functions of the longitudinal spatial dimension, the pressure drop will be linear with time provided that the region in which both fluid phases are flowing simultaneously has uniform properties. The detection of heterogeneities by this method is discussed and illustrated with analytical solutions for the displacement process and with laboratory experimental data. Theory We consider here a displacement experiment with two incompressible fluids. Initially, the core is saturated with one fluid and the other fluid is injected at one end. For example, if the core initially contains only oil or air, water might be injected at one end. The core could contain the irreducible saturation of the displacing fluid initially, although this is not experimentally convenient and is not necessary for conducting the test. The pressure drop across the core is recorded through the time of breakthrough of the displacing fluid at the core outlet. SPEJ P. 909

2019 ◽  
Vol 89 ◽  
pp. 04005 ◽  
Author(s):  
A Giwelli ◽  
MZ Kashim ◽  
MB Clennell ◽  
L Esteban ◽  
R Noble ◽  
...  

We conducted relatively long duration core-flooding tests on three representative core samples under reservoir conditions to quantify the potential impact of flow rates on fines production/permeability change. Supercritical CO2 was injected cyclically with incremental increases in flow rate (2─14 ml/min) with live brine until a total of 7 cycles were completed. To avoid unwanted fluid-rock reaction when live brine was injected into the sample, and to mimic the in-situ geochemical conditions of the reservoir, a packed column was installed on the inflow accumulator line to pre-equilibrate the fluid before entering the core sample. The change in the gas porosity and permeability of the tested plug samples due to different mechanisms (dissolution and/or precipitation) that may occur during scCO2/live brine injection was investigated. Nuclear magnetic resonance (NMR) T2 determination, X-ray CT scans and chemical analyses of the produced brine were also conducted. Results of pre- and post-test analyses (poroperm, NMR, X-ray CT) showed no clear evidence of formation damage even after long testing cycles and only minor or no dissolution (after large injected pore volumes (PVs) ~ 200). The critical flow rates (if there is one) were higher than the maximum rates applied. Chemical analyses of the core effluent showed that the rock samples for which a pre-column was installed do not experience carbonate dissolution.


2020 ◽  
Vol 17 (2) ◽  
pp. 1207-1213 ◽  
Author(s):  
Muhammad Aslam Md Yusof ◽  
Mohamed Zamrud Zainal ◽  
Ahmad Kamal Idris ◽  
Mohamad Arif Ibrahim ◽  
Shahrul Rizzal M. Yusof ◽  
...  

Sequestration of Carbon Dioxide (CO2) in sandstone formation filled by brine aquifers is widely considered a promising option to reduce the CO2 concentration in the atmosphere. However, the injection of reactive CO2 into sandstone rock creates injectivity problems because of CO2-brine-rock interactions. The injection flow rate and CO2-fluid-rock exposure conditions are important factors that control the intensity of the reactions. The focus of this research was therefore on evaluating the petrophysical modifications in sandstone core samples at distinct flow rates using different CO2 injection schemes. In this research, the porosity and permeability of Berea sandstone samples were measured using PoroPerm equipment. The core samples were initially saturated with dead brine (30 g/l NaCl) followed by injection either by supercritical CO2 (scCO2) only, CO2-saturated brine only and CO2-saturated brine together with scCO2 at different flow rates. During injection, the differential pressure between the core inlet face and outlet face were recorded. Fines from the produced effluent were separated and collected for characterization using Field Emission Scanning Electron Microscope and Energy Dispersive X-ray Spectroscopy (FESEM-EDX). Post-injection porosity and permeability of the core samples were measured and compared with the pre-injection data to monitor changes. All sandstone core specimens showed favorable storage capability features in the form of capillary residual trapping with residual CO2 saturation ranging from 40% to 48%. In addition, all samples experienced important changes in their petrophysical characteristics, which were more pronounced in the event of absolute porosity and permeability, which decreased from 20%–51% to 4%–32%. The suggested harm mechanism is primarily owing to salt precipitation and fines migration. Supported by FESEM images, the proposed damage mechanism is mainly due to salt precipitation and fines migration.


2011 ◽  
Vol 255-260 ◽  
pp. 4176-4180
Author(s):  
Yong Li Xu ◽  
Hao Jiang

The Bailey method put forward three very significant parameters CA, FAc and FAf, provided an effective way for the asphalt mixture gradation test, and it could evaluate the gradation of asphalt pavement core sample effectively. Based on the analysis of common gradation, the parameters of formula was revised, the application conditions of AC mixture and the parameter range for AC mixture was proposed, that based on the gradation which is standard recommended and the core samples in different pavement conditions. The results proposed theoretical basis for gradation examination correctly with the Bailey method.


Author(s):  
Yakov V. Shirshov ◽  
Sergey V. Stepanov

Digital core analysis using three-dimensional tomographic images of the internal structure of porous media has received significant development in recent years. Three-dimensional images of the core obtained with the help of x-ray computer tomography can be used to calculate the filtration properties of rocks. However, the question of the influence of the resolution quality of the three-dimensional core image on the simulation results still remains unanswered. This paper studies the influence of the resolution of the three-dimensional image of the core on the calculated absolute permeability in the case of a model porous medium consisting of axisymmetric conical constrictions of different sizes. Based on the initial representation of the model porous medium, several models with different discretization steps were generated, which correspond to images taken with different resolution. The results show that the resolution (the degree of discretization) significantly affects the calculated absolute permeability of the porous medium. The calculated permeability decreases with increasing sampling step. This is because the small channels are not visible at lower resolutions. Elimination of these channels leads to loss of connectivity of the model.


1985 ◽  
Vol 25 (04) ◽  
pp. 502-514 ◽  
Author(s):  
Liang C. Shen

Abstract This paper describes an automated laboratory system that can measure accurately the dielectric properties of core samples in the ultrahigh-frequency properties of core samples in the ultrahigh-frequency (UHF) range. The system consists of a precision coaxial-line sample holder, a network analyzer, a plotter, a printer, and a desk computer. The computer is for measurement control, data acquisition, and data analysis. A new method is developed to measure and to compensate for the error of the network analyzer system. This method uses a brass sample and does not require standard terminations. A procedure for core sample preparation is also recommended to ensure accuracy of the data. Introduction The electromagnetic propagation tool (EPT) is a relatively new wireline sonde developed by Schlumberger for detection and quantification of hydrocarbon. It is operated at 1.1 GHz, which is in the UHF band of the electromagnetic spectrum. The EPT sonde measures the dielectric constant of the formation. Because water has a much higher dielectric constant (about 80 units) than oil (about 2 units) and gas (about 1 unit), the EPT sonde can distinguish hydrocarbon-bearing zones from the water-bearing zones even when the formation water is fresh. The dielectric constant of water at UHF is not very sensitive to salinity. Consequently, EPT is particularly useful in situations where the formation water resistivity is variable or unknown, as a result, for example, of water, steam, or chemical flooding. The EPT log displays the travel time and the rate of attenuation of the electromagnetic wave in the formation. From these data, the calculated complex dielectric constant of the formation may be calculated. This complex dielectric constant is related to water saturation, Sw, by an empirical formula called the complex refractive index method (CRIM): ............................(1) where = porosity, = dielectric constant of the water in the rock, = dielectric constant of oil or gas, and = dielectric constant of the rock grain. To verify the validity of the CRIM formula given by Eq. 1, a computer-controlled laboratory system has been set up to measure the dielectric constants of saturated core samples, dry core samples, and oils. The same system is now being used for routine measurements of cores for EPT log interpretation. Measurement Techniques Two basic techniques can be used to measure the complex dielectric constant of a saline-water-saturated rock at frequencies higher than 100 MHz. The first is the coaxial-line and waveguide method, and the other is the resonant-cavity method. We describe these methods and point out their advantages and disadvantages. Fig. 1 shows the configuration of the coaxial-line and waveguide method. In Figs. 1a and 1b, we see that the core sample is machined into a circular cylinder with a circular concentric hole drilled to fit the coaxial line. The line consists of an outer conductor and an inner conductor. In Fig. 1c, we see that the core sample is machined into a rectangular column to fit into a rectangular waveguide. The latter is a rectangular metal pipe without a central conductor. pipe without a central conductor. Longitudinal slots are cut along the outer conductor of the coaxial line (Fig. 1b) or on top of the rectangular waveguide (Fig. 1c) to allow a probe to be inserted partially into the region where electromagnetic fields are present. The probe travels along the length of the structure and detects the amplitude and the phase of the electromagnetic fields present in the structure. During the measurement, an electromagnetic wave of the selected frequency is sent propagating down the line or the waveguide until it encounters the core sample. Reflection occurs so that part of the wave is absorbed, and part is reflected and travels in the reverse direction. The phase and the amplitude of the reflected wave are determined by the complex dielectric constant of the sample. The reflected wave interacts with the incident wave and creates an interference pattern called the standing wave pattern. The complex dielectric constant of the core sample can be determined from the standing wave pattern recorded by the traveling probe. This method was used by Poley et al. for sandstone samples up to 1.2 GHz. It was also used by Tam to test nine dry rocks, mainly sedimentary, in the frequency range 150 to 1000 MHz. The rectangular waveguide was used by Roberts and Von Hippel to measure a variety of materials at 5 GHz. The configuration shown in Fig. 1a was used by Rau and Wharton to measure formation samples in the frequency range 500 MHz to 1.1 GHz. This arrangement calls for placing the sample at the center, rather than at the end, of a coaxial line. The amplitudes and the phases of both the reflected and the transmitted waves are recorded and are called the scattering matrix parameters. parameters. SPEJ p. 502


Author(s):  
Nikita A. Popov ◽  
◽  
Ivan S. Putilov ◽  
Anastasiia A. Guliaeva ◽  
Ekaterina E. Vinokurova ◽  
...  

The paper analyzes a methodology aimed at differentiation of porosity, permeability and petrographic properties depending on facies attributes. Based on the Dunham classification, we offer in-depth studies of the influence of rock fabric, including full-size core samples, on changes in porosity and permeability. The work deals with the Permo-Carboniferous deposit of the Usinskoye field. Reservoir properties of the considered strata are highly heterogeneous. Along with highly porous and cavernous rocks, there are low porous and fractured varieties in the section, which refer to rocks of various lithological compositions. The porosity and permeability properties were analysed for more than 9,000 standard core samples and approximately 1,000 full-size core samples, taking into account the scale factor and including microfractures, large caverns and rock matrix, commensurable with the sample sizes.The analysis of the maximum variation range is of particular importance for structurally complex carbonate reservoirs. Furthermore, based on the conducted lithologic, petrographic and petrophysical studies, the authors identified four types of reservoirs and eight different types of lithogenesis, as well as estimated geological and physical parameters for each of them. Based on the cumulative correlation plots, four zones of heterogeneity were identified. They are subject to the influence of properties of the core samples of different lithogenesis types. This is the first time that the influence of various petrotypes/lithotypes on changes in the reservoir porosity and permeability has been studied for the Usinskoye field based on the petrographic and petrophysical research findings. All the conducted experiments show that the rocks of the Permo-Carboniferous deposit of the Usinskoye field are extremely heterogeneous in their permeability properties that vary much. Thus, it is necessary to differentiate the core-to-core petrophysical correlations depending on a void space fabric and lithology of rocks.


2015 ◽  
Vol 1 (1) ◽  
pp. 26
Author(s):  
R. Arizal Firmansyah ◽  
R. Y. Perry Burhan

Study compound biomarka branched alkanes on core 1/208 Rhinos have done to contribute to the activities of oil exploration wells 1/208 Muara Badak Badak, East Kalimantan's Kutai Kartanegara-through core biomarka profile branched alkanes. Core samples extracted by alternately with solvent mixture of toluene-methanol (3: 1) and chloroform-methanol (3: 1). Then fractionated by Column Chromatography and Thin Layer Chromatography to obtain aliphatic hydrocarbon fraction. Fractions obtained were identified using Gas Chromatography-Mass Spectrometry.The content biomarka aliphatichydrocarbon fraction were identified, among others, iso and anteiso alkanes, mono and trimethyl alkanes. Compounds iso and anteiso alkanes, and alkyl alkane other, providing information that the source of organic material core samples I and II is derived from microorganisms prokaryotic or biogenic precursor derived from cyanobacteria (marine microorganisms) and homologous monomethyl alkanes found in core samples II closer homologous series monomethyl alkanes found in sediments and oil and Precambrian Proterozoic era, so it can be said that the core sample II core samples older than I.


1971 ◽  
Vol 11 (04) ◽  
pp. 351-355 ◽  
Author(s):  
M.M. El-Saleh ◽  
S.M. Farouq Ali

Abstract Results of an experimental study of oil recovery by a steam slug driven by a cold waterflood in a linear porous medium are described. The model included simulation of heat losses to the adjacent formations. Steam displacements were conducted, using a number of hydrocarbons and various steam-slug sizes, with the core initially containing a residual oil or irreducible water saturation. It was found that the steam-slug displacement is more efficient in the case of light oils than for the heavier ones. The injection of cold water following steam resulted in almost total condensation of the steam present in the porous medium, with the process degenerating into a hot waterflood. The oil process degenerating into a hot waterflood. The oil recovery efficiency of the process depends on whether an oil bank is formed during the steam-injection phase and whether the oil responds favorably to a hot phase and whether the oil responds favorably to a hot waterflood Introduction Steam injection has been shown to be an effective oil recovery method both by field and laboratory tests. However, the method has the inherent disadvantages of a high cost of operation and excessive heat losses. The modification discussed here consists in the injection of cold water after a slug of steam, which helps to offset the above disadvantages partly at the expense of oil recovery. The injected water serves to propel the oil bank formed ahead of the steam-invaded zone and transports the heat contained in the steam-swept zone farther downstream, thus leading to more complete utilization of the heat injected. EXPERIMENTAL APPARATUS AND PROCEDURE Fig. 1 depicts a schematic diagram of the apparatus employed. It consisted of a 4-ft-long core composed of a steel tube having a rectangular cross-section (see Table 1 for dimensions and other information) packed with glass beads (mesh size 200 to 270, corresponding to 0.0021 to 0.0029 in.) and fitted with 15 iron-constantan thermocouples and eight pressure gauges. The two ends of the core were fitted with sintered bronze plates to ensure strictly linear fluid flow. In order to simulate the underlying formations, the core was placed upon a sand-filled wooden box having a depth placed upon a sand-filled wooden box having a depth of 2.5 ft and a length and width equal to those of the core. An identical box was placed in contact with the top surface of the core to simulate the overlying formations. The sand packs simulated infinitely thick formations, since the temperatures at the upper and lower extremities remained undisturbed during a run. The sides of the two boxes were fitted with thermometers and insulated, together with the exposed surface of the core; the top and bottom surfaces of the core were in contact with sand. An electrical system was designed for temperature measurement at the 15 points; the core inlet and outlet were fitted with thermocouples. A technique was devised for pressure measurement virtually without disturbing the flow. A positive-displacement pump, in conjunction with a coil immersed in a high-temperature oil bath, was used for conducting hot waterfloods as well as for preparing the core for a run (Fig. 1). Steam, having a quality of 95 percent was supplied by an electric boiler capable of delivering up to 69 lb/hr at pressures up m 250 psig. The core effluent was passed though a suitable condenser provided with passed though a suitable condenser provided with a backpressure regulator used to control the steam injection rate. The average steam (as condensate) injection rate for a run was estimated by dividing the total effluent volume minus the volume of the water needed to fill up the core at the end of steam injection, by the steam injection time. The properties of the fluids used are listed in Table 1. The hydrocarbon mixtures were chosen to study the steam distillation effects. Drakeol 15 and 33 at 80 deg. F are high-boiling mineral oils having viscosities of 515 and 100.0 cp, respectively. Viscosity-temperature behavior for the hydrocarbons used is shown in Fig. 2. The core was saturated with distilled water and then saturated with the oil to be tested by displacement (terminal WOR 1:100). If desired, the core was waterflooded prior to steam injection (terminal WOR 100:1). SPEJ P. 351


2020 ◽  
Vol 10 (24) ◽  
pp. 9065
Author(s):  
Aliya Mukhametdinova ◽  
Polina Mikhailova ◽  
Elena Kozlova ◽  
Tagir Karamov ◽  
Anatoly Baluev ◽  
...  

The experimental and numerical modeling of thermal enhanced oil recovery (EOR) requires a detailed laboratory analysis of core properties influenced by thermal exposure. To acquire the robust knowledge on the change in rock saturation and reservoir properties, the fastest way is to examine the rock samples before and after combustion. In the current paper, we studied the shale rock properties, such as core saturation, porosity, and permeability, organic matter content of the rock caused by the combustion front propagation within the experimental modeling of the high-pressure air injection. The study was conducted on Bazhenov shale formation rock samples. We reported the results on porosity and permeability evolution, which was obtained by the gas pressure-decay technique. The measurements revealed a significant increase of porosity (on average, for 9 abs. % of porosity) and permeability (on average, for 1 mD) of core samples after the combustion tube experiment. The scanning electron microscopy showed the changes induced by thermal exposure: the transformation of organic matter with and the formation of new voids and micro and nanofractures in the mineral matrix. Low-field Nuclear Magnetic Resonance (NMR) was chosen as a primary non-disruptive tool for measuring the saturation of core samples in ambient conditions. NMR T1–T2 maps were interpreted to determine the rock fluid categories (bitumen and adsorbed oil, structural and adsorbed water, and mobile oil) before and after the combustion experiment. Changes in the distribution of organic matter within the core sample were examined using 2D Rock-Eval pyrolysis technique. Results demonstrated the relatively uniform distribution of OM inside the core plugs after the combustion.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Zhihang Li ◽  
Xiong Hu

The sensitivity of oil reservoir rocks to stress is the basis for oilfield development, which determines the production method employed in the field. Therefore, it is critical to understand the stress sensitivity behavior of oil reservoir rocks in an oilfield. In this paper, a novel method for determining the stress sensitivity of oil reservoir rocks by triaxial stress testing without fluid flooding was proposed. It measures the triaxial stress and strain of the core rock samples, and based on which, the core porosity and permeability under stress can be evaluated by theoretical model. In the model, the pores of the core were assumed to be a bundle of capillaries and the necessary relationship was derived to calculate the changes of porosity and permeability of the core samples caused by the strain. Through comparison with and analysis of experimental results obtained for various rock core samples under different stress and strain conditions, it is observed that the theoretical model match well with that of the experiments. This method provides a new approach for the stress sensitivity analysis of oil reservoirs without fluid flooding.


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