scholarly journals Experimental studies of iron transformations kinetics and autocatalysis during its physicochemical removal from underground water

Author(s):  
S. Yu Martynov ◽  
V. L. Poliakov

Abstract The mathematical model of physicochemical iron removal from groundwater was developed. It consists of three interrelated compartments. The results of the experimental research provide information in support of the first two compartments of the mathematical model. The dependencies for the concentrations of the adsorbed ferrous iron and deposited hydroxide concentrations are obtained as a result of the exact solution of the system of the mass transfer equations for two forms of iron in relation to the inlet surface of the bed. An analysis of the experimental data of the dynamics of the deposit accumulation in a small bed sample was made, using a special application that allowed to select the values of the kinetic coefficients and other model parameters based on these dependencies. We evaluated the autocatalytic effect on the dynamics of iron ferrous and ferric forms. The verification of the mathematical model was carried out involving the experimental data obtained under laboratory and industrial conditions.

2020 ◽  
pp. 44-49
Author(s):  
V. V. Kharlamov ◽  
◽  
D. I. Popov ◽  
P. S. Sokolov ◽  
L. E. Serkova ◽  
...  

The article presents the results of comparison of experimental studies and mathematical modeling of the stand for testing induction motors by the method of mutual load. A detailed description of the composition of the experimental equipment, which is based on a pair of frequency converters and connected to them a pair of engines of the АИС71В4 type with a nominal power of 0,75 kW, the shafts of which are rigidly connected by a coupling. The mathematical model of the electromechanical system used in the calculations is presented, and its main assumptions are listed. A table of parameter values and graphs obtained from calculated and experimental data are presented. The analysis of the obtained data shows the possibility of using the considered mathematical model with the existing assumptions in the design of electrical complexes intended for testing induction motors by the method of mutual load


2018 ◽  
Vol 40 (1) ◽  
pp. 44-50
Author(s):  
B.I. Basok ◽  
B.V. Davydenko ◽  
V.G. Novikov ◽  
R.Ya. Sorokovoy

The work is devoted to the estimation of the intensity and energy of solar radiation at the earth's surface. The aim of the research is to develop a mathematical model of solar radiation, necessary for the design of devices for renewable energy, as well as in the design and construction of buildings and structures. The mathematical model of solar radiation is realized in the Python code. The program code allows you to calculate the intensity of solar radiation and solar insolation on any day of the year. The model is verified by the results of experimental studies of solar radiation in the Odessa region and by the results of our own experimental data.


Author(s):  
O. V. Lapshin ◽  
A. M. Shul’pekov ◽  
R. M. Gabbasov ◽  
V. D. Kitler

Experimental studies were carried out with theoretical calculations of wave synthesis in the Ni–Al–Cu system were performed using the mathematical model developed. Approximate analytical formulas were obtained for synthesis performance evaluation. The inverse problem method was used to get kinetic constants that determine process dynamics based on the experimental data and analytical relationships. It is shown that the combustion front propagation velocity increases monotonically with an increase in the reaction sample relative density in the range of relative density values of 0.4 to 0.6. The depth of copper melt penetration from the center of the sample into the nickel-aluminum matrix depends on the relative density of the sample and copper wire diameter: higher densities and larger diameters lead to an increase in the liquid-phase impregnation area. The rate of nickel and aluminum powder frame wetting with copper melt is limited by the synthesis wave speed. Based on the experimental data and analytical ratios, we estimated the effective kinetic constants describing the high-temperature synthesis of the Ni + Al reaction mixture in the presence of copper additives. The thermal effect of the NiAl intermetallic formation reaction and the preexponential factor in the chemical transformation equation are calculated, the exponent value in the ratio for the mixture thermal conductivity is established; a constant determining the process of nickel-aluminum matrix impregnation with copper melt is found. The macroscopic approach used to analyze the NiAl intermetallic synthesis makes it possible to determine all the desired physicochemical characteristics and model parameters. The mathematical model is suitable for predictive estimates and experimental data analysis in the macroscopic approximation. Approximate analytical formulas are obtained for calculating the NiAl intermetallic synthesis characteristics. They allow for calculating the through channel characteristics and can be used in the design of NiAl products.


Author(s):  
V. Mogila ◽  
M. Kovtanets ◽  
M. Morneva

The Department of Railwayand Road Transport, lift and care system of Volodymyr Dahl East Ukrainian National University, an energy-saving cooling system for diesel locomotives using phase transitions of the coolant has been developed. The proposed cooling system allows to maintain constant optimal temperatures of cooling objects at ambient temperatures ± 40 ºC and in any mode of operation of the diesel engine. For thermal calculation of the radiator section operating in the mode of the steam condenser, the mathematical model of process of heat transfer from steam to walls of a flat tube at condensation is developed that considers geometrical features of section of a tube. The adequacy of this mathematical model is verified by comparing the simulation results with the obtained experimental data. During the tests, the outlet water temperature, inlet and outlet air temperature, and air pressure in front of and behind the radiator were measured. Having the values of wall temperature, steam temperature and condensate, knowing the value of steam consumption and the experimental heat transfer coefficient, it becomes possible to verify the adequacy of the mathematical model by comparing the simulation results with the obtained experimental data. Schemes of bench equipment, test methods, experimental planning and basic calculation dependences required for testing serial radiator sections of a locomotive in the standard mode of operation and in the mode of steam condensers are presented.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Indah Hartati ◽  
Wahyudi Budi Sediawan ◽  
Hary Sulistyo ◽  
Muhammad Mufti Azis ◽  
Moh Fahrurrozi

AbstractHydrotropes have been largely explored as reactive extraction agent for lignin separation. In this paper, a mathematical model of hydrotropic-reactive extraction of sugarcane bagasse lignin was proposed and validated by experimental data from literature. The mathematical model was developed by assuming the particle is in slab shape, and by considering simultaneous processes of hydrotrope intra particle diffusion, second order reaction of lignin-hydrotrope, and intra-particle soluble delignification product diffusion. The proposed model results in a set of partial differential equations which were then solved by explicit finite difference approximation method. The mathematical model parameters were determined by fitting the model to the hydrotropic reactive extraction experimental data reported by Ansari and Gaikar (2014). Simulations show that the mathematical model of the hydrotropic-reactive extraction were well fitted to the experimental data with the obtained hydrotrope effective diffusivity (DeA) of 5.0 × 10−11 m2/s, effective diffusivity of soluble lignin product (DeC) of 9.0 × 10−12 m2/s and reaction rate constant (kr) of 1.78 × 10−10 m3/(g.s). It was also observed that the reaction was first order to the hydrotrope (n = 1), and one half order to the lignin (m = 0.5). Meanwhile the pseudo-stoichiometric mass ratio of hydrotrope to lignin was 6.4 g hydrotrope/g lignin.


2018 ◽  
Vol 14 (1) ◽  
pp. 76-83 ◽  
Author(s):  
Glib Vatulia ◽  
Maryna Rezunenko ◽  
Dmytro Petrenko ◽  
Sergii Rezunenko

AbstractExperimental studies of rectangular steel-concrete columns under centric compression with random eccentricity were conducted. The stress-strain state and the carrying capacity exhaustion have been assessed. The regression dependence is proposed to determine the maximum carrying capacity of such columns. The mathematical model takes into account the combined influence of the physical and geometric characteristics of the columns, such as their length, crosssectional area, casing thickness, prism strength of concrete, yield strength of steel, modulus of elasticity of both steel and concrete. The correspondence of the obtained model to the experimental data, as well as the significance of the regression parameters are confirmed by the Fisher and Student criteria.


Author(s):  
Oleksii Timkov ◽  
Dmytro Yashchenko ◽  
Volodymyr Bosenko

The article deals with the development of a physical model of a car equipped with measuring, recording and remote control equipment for experimental study of car properties. A detailed description of the design of the physical model and of the electronic modules used is given, links to application libraries and the code of the first part of the program for remote control of the model are given. Atmega microcontroller on the Arduino Uno platform was used to manage the model and register the parameters. When moving the car on the memory card saved such parameters as speed, voltage on the motor, current on the motor, the angle of the steered wheel, acceleration along three coordinate axes are recorded. Use of more powerful microcontrollers will allow to expand the list of the registered parameters of movement of the car. It is possible to measure the forces acting on the elements of the car and other parameters. In the future, it is planned to develop a mathematical model of motion of the car and check its adequacy in conducting experimental studies on maneuverability on the physical model. In addition, it is possible to conduct studies of stability and consumption of electrical energy. The physical model allows to quickly change geometric dimensions and mass parameters. In the study of highway trains, this approach will allow to investigate the various layout schemes of highway trains in the short term. It is possible to make two-axle road trains and saddle towed trains, three-way hitched trains of different layout. The results obtained will allow us to improve not only the mathematical model, but also the experimental physical model, and move on to further study the properties of hybrid road trains with an active trailer link. This approach allows to reduce material and time costs when researching the properties of cars and road trains. Keywords: car, physical model, experiment, road trains, sensor, remote control, maneuverability, stability.


1999 ◽  
Author(s):  
Mahmut D. Mat ◽  
Yüksel Kaplan ◽  
Olusegun J. Ilegbusi

Abstract Subcooled boiling of water in a vertical pipe is numerically investigated. The mathematical model involves solution of transport equations for vapor and liquid phase separately. Turbulence model considers the turbulence production and dissipation by the motion of the bubbles. The radial and axial void fractions, temperature and velocity profiles in the pipe are calculated. The estimated results are compared to experimental data available in the literature. It is found that while present study satisfactorily agrees with experimental data in the literature, it improves the prediction at lower void fractions.


Author(s):  
A I Ryazanov

This paper describes the aerohydrodvnamics of processes in chambers of Gorlov's hydro-pneumatic power system. The mathematical model is developed to determine the main parameters of the processes: water and air velocities, air pressure in the chamber, the periods of time required to fill and empty the chambers and the output of energy during the cycle. The results obtained are in agreement with experimental data and model tests.


2015 ◽  
Vol 14 (2) ◽  
pp. 90 ◽  
Author(s):  
K. L. M. Dos Passos ◽  
B. M. Viegas ◽  
E. N. Macêdo ◽  
J. A. S. Souza ◽  
E. M. Magalhães

The use of the waste of the Bayer process, red mud, is due to its chemical and mineralogical composition that shows a material rich in oxides of iron, titanium and aluminum. Some studies conducted show that this waste can be applied as a source of alternative raw material for concentration and subsequent recovery of titanium compounds from an iron leaching process, which is present in higher amounts, about 30% by weight. To obtain a greater understanding about the leaching kinetics, the information of the kinetic data of this process is very important. In this context, the main objective of this work is the development of a mathematical model that is able to fit the experimental data (conversion / extraction iron, titanium and aluminum) of the leaching process by which is possible to obtain the main kinetic parameters such as the activation energy and the velocity of chemical reactions as well as the controlling step of the process. The development of the mathematical model was based on the model of core decreasing. The obtained model system of ordinary differential equations was able to fit the experimental data obtained from the leaching process, enabling the determination of the controlling step, the rate constants and the activation energies of the leaching process.


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