Effect of Petrochemical Activated Sludge on Soil Properties
Excess activated sludge produced at SITEL, the integrated wastewater treatment plant of Pólo Petroquímico do Sul (South Petrochemical Complex), situated in the municipality of Triunfo, State of Rio Grande do Sul, Brazil, is disposed of by subsurface injection on pangola grass fields at average application rates of 24 tons/years (dry basis). With the purpose of investigating the effect produced by the application of sludge at higher rates on the soil-plant-water system, as well as the response of more commercially valuable grass species, a growth-leaching pot experiment is being conducted at the Department of Soils of UFRGS (Federal University of Rio Grande do Sul), with the supervision of SITEL. After one year, comprehensive soil analyses showed the following results:Sludge decomposition in soil, worked out from evolution of CO2, amounted to 2.7% of C lost as CO2 in relation to the C added, in 50 days, 27°C (daylight temperature) and sludge application rate of 24 t/ha.Sludge application brought about an enrichment of soil C, N and P restricted to the top layer.No significant modifications were observed in soil pH and contents of K, Ca, Mg, Fe, Mn and B in the top layer of soil, even at the higher sludge application rates.Slight increases were observed in contents of Na, Cu, S and electrical conductivity of the top layer, effects compatible with the characteristics of the sludge applied.Appreciable increases were observed in soil contents of Zn, Cr, Cd and Ni, in correlation with the increasing sludge application rates. The resulting values, however, fell well below the tolerable limits.Proper management of a sludge application system that reproduces the conditions chosen for this investigation can yield a useful site life of many years without appreciable environmental risks.