Heavy metals speciation in soakaways sediment and evaluation of metal retention properties of surrounding soil

2007 ◽  
Vol 56 (11) ◽  
pp. 81-89 ◽  
Author(s):  
M.A. Hossain ◽  
H. Furumai ◽  
F. Nakajima ◽  
R.K. Aryal
Keyword(s):  
Heavy Metals ◽  
Surface Soil ◽  
Speciation Analysis ◽  
Core Sample ◽  
Significant Heterogeneity ◽  
Soil Core ◽  
Metal Retention ◽  
Adsorption Sites ◽  
Stormwater Infiltration ◽  
Underlying Soil

Heavy metals speciation analysis was carried out on sediment samples accumulated within soakaways in an old stormwater infiltration facility in Tokyo, Japan and on a soil core sample collected near the facility. Heavy metals content in soakaways sediments were much elevated compared to nearby surface soil with the content for Zn, Pb and Cd reaching about 5 to 10 times the content in surface soil. Speciation results revealed that significant amount of the accumulated heavy metals were present in potential mobile fractions, posing threat of release to underlying soil with changing environmental conditions. Detail analyses of soil characteristics indicated significant heterogeneity with depth, especially between the surface soil and underlying soil at site. Decrease in potential adsorption sites with depth was observed in case of underlying soil. Reduced adsorption capacity for heavy metals was evidenced for underlying soil when compared with surface soil. Furthermore, less capability of the soil organic matter to bind heavy metals was evidenced through speciation analyses, which raises concern over the long-term pollution retention potential of the underlying soil receiving infiltrated runoff.

Competitive adsorption of heavy metals in soil underlying an infiltration facility installed in an urban area

2009 ◽  
Vol 59 (2) ◽  
pp. 303-310 ◽  
Author(s):  
M. A. Hossain ◽  
H. Furumai ◽  
F. Nakajima
Keyword(s):  
Heavy Metals ◽  
Competitive Adsorption ◽  
Surface Soil ◽  
Speciation Analysis ◽  
Batch Adsorption ◽  
Elevated Concentration ◽  
Bcr Sequential Extraction ◽  
Soil System ◽  
Sequential Extraction Method ◽  
Underlying Soil

Accumulation of heavy metals at elevated concentration and potential of considerable amount of the accumulated heavy metals to reach the soil system was observed from earlier studies in soakaways sediments within an infiltration facility in Tokyo, Japan. In order to understand the competitive adsorption behaviour of heavy metals Zn, Ni and Cu in soil, competitive batch adsorption experiments were carried out using single metal and binary metal combinations on soil samples representative of underlying soil and surface soil at the site. Speciation analysis of the adsorbed metals was carried out through BCR sequential extraction method. Among the metals, Cu was not affected by competition while Zn and Ni were affected by competition of coexisting metals. The parameters of fitted ‘Freundlich’ and ‘Langmuir’ isotherms indicated more intense competition in underlying soil compared to surface soil for adsorption of Zn and Ni. The speciation of adsorbed metals revealed less selectivity of Zn and Ni to soil organic matter, while dominance of organic bound fraction was observed for Cu, especially in organic rich surface soil. Compared to underlying soil, the surface soil is expected to provide greater adsorption to heavy metals as well as provide greater stability to adsorbed metals, especially for Cu.

Vertical distribution and speciation of heavy metals in stormwater infiltration facilities: possible heavy metals release to groundwater

2007 ◽  
Vol 2 (2) ◽  
Author(s):  
R. K. Aryal ◽  
H. Furumai ◽  
F. Nakajima ◽  
M. A. Hossain
Keyword(s):  
Heavy Metals ◽  
Road Dust ◽  
Residual Fraction ◽  
Future Possibility ◽  
The Road ◽  
Speciation Study ◽  
Metal Contents ◽  
Exchangeable Fraction ◽  
Stormwater Infiltration ◽  
Underlying Soil

The infiltration inlet facilities on the side of the road along with the sewage system have been constructed two decades ago in highly urbanized residential area in Tokyo. Possible release of heavy metals from the infiltration inlet was studied by analyzing sediment samples in different vertical depth. Seven heavy metals (Cr, Mn, Co, Ni, Cu, Zn and Pb) were measured. The heavy metal contents in sediment decreased with depth. The low content of heavy metals at the bottom sediment compared to the top indicated possible release of heavy metals from the inlet sediment. The heavy metals speciation study showed that the order of the extractability/mobility in the sediment in acid exchangeable fraction was Zn and Mn>Co>Ni>Cu >Cr and Pb. The mobility order in road dust also followed the similar pattern. In reducible fraction (metal oxide bound) Pb was the most mobile in the sediment while the other metals mobility order was not similar. In oxidizable fraction (organic and sulfide bound) the order was different for the sediment and road dusts. The residual fraction contained 18 to 83% heavy metals. The presence of heavy metals in acid exchangeable, reducible and oxidizable fractions indicated a future possibility of their release to the underlying soil and the groundwater.

scholarly journals Spatial distribution of heavy metals in the surface soil of source-control stormwater infiltration devices – Inter-site comparison

2017 ◽  
Vol 579 ◽  
pp. 881-892 ◽  
Author(s):  
Damien Tedoldi ◽  
Ghassan Chebbo ◽  
Daniel Pierlot ◽  
Philippe Branchu ◽  
Yves Kovacs ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Surface Soil ◽  
Source Control ◽  
Stormwater Infiltration

Applications of Bentonite to Soil Decontamination

2018 ◽  
Vol 69 (7) ◽  
pp. 1695-1698
Author(s):  
Marin Rusanescu ◽  
Carmen Otilia Rusanescu ◽  
Gheorghe Voicu ◽  
Mihaela Begea
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Laboratory Experiments ◽  
Experimental Studies ◽  
Heavy Metal Concentration ◽  
Polluted Soil ◽  
Raw Material ◽  
Soil Decontamination ◽  
Metal Retention ◽  
Removal Of Heavy Metals

A calcium bentonite from Orasu Nou deposit (Satu Mare Romania) was used as raw material. We have conducted laboratory experiments to determine the influence of bentonite on the degree of heavy metal retention. It has been observed that the rate of retention increases as the heavy metal concentration decreases. Experimental studies have been carried out on metal retention ( Zn) in bentonite. In this paper, we realized laboratory experiments for determining the influence of metal (Zn) on the growth and development of two types of plants (Pelargonium domesticum and Kalanchoe) and the effect of bentonite on the absorption of pollutants. These flowers were planted in unpolluted soil, in heavy metal polluted soil and in heavy metal polluted soil to which bentonite was added to observe the positive effect of bentonite. It has been noticed that the flowers planted in unpolluted soil and polluted with heavy metals to which bentonite has been added, the flowers have flourished, the leaves are still green and the plants whose soils have been polluted with heavy metals began to dry after 6 days, three weeks have yellowish leaves and flowers have dried. Experiments have demonstrated the essential role of bentonite for the removal of heavy metals polluted soil.

Relationships between Heavy Metals and Their Connection to Amorphous and Total Iron in a Frequently Subsampled Clay Pit Core Sample

2021 ◽  
Author(s):  
Josip Jurković ◽  
Senad Murtić ◽  
Fejzo Bašić ◽  
Teofil Gavrić ◽  
Emina Sijahović ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Core Sample ◽  
Total Iron

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals Urban soil assessment caused by heavy metals contamination in Yogyakarta City, Indonesia

2021 ◽  
Vol 851 (1) ◽  
pp. 012026
Author(s):  
A T Sekarningsih ◽  
W Budianta ◽  
I W Warmada ◽  
H Hinode
Keyword(s):  
Heavy Metals ◽  
Surface Soil ◽  
Pollution Index ◽  
Soil Samples ◽  
City Center ◽  
Urban City ◽  
Heavy Metals Contamination ◽  
The City ◽  
Cu And Zn ◽  
Yogyakarta City

Abstract The effect of urbanization and industrialization in the urban city is soil contamination by heavy metals. This study was conducted to assess Pb, Cu, Zn, and Cd, in the soil of Yogyakarta city and its surrounding, Indonesia. The assessment was done by analyzing 45 surface soil samples in the study area, divided into three-zone. They are divided based on the distance of each zone to the center of the city. The zone III is located in the outermost of the study area, and zone I is inside the city. The results of the study showed that generally, the highest concentration of metals was located in zone I, which is located near or directly situated in a city center. The result indicated that Pb and Cd had the highest pollution index compared to Cu and Zn. The pollition load indeks (PLI) and geoaccumulation indeks (Igeo) calculations in the whole study area showed that the values demonstrated a moderate class in average. Special attention was needed to be given to the zone I, which has a higher PLI and Igeo index to reduce the source of emission for Pb and Cd.

scholarly journals Empirical Characterization of Heavy Metals in Crude Oil Spill Sites in Emohua, Rivers State, Nigeria

2021 ◽  
Vol 2 (5) ◽  
pp. 24-28
Author(s):  
Nnamdi Michael Ahiamadu ◽  
Ify L. Nwaogazie ◽  
Yusuf O. L. Momoh
Keyword(s):  
Heavy Metals ◽  
Surface Water ◽  
Oil Spill ◽  
Environmental Protection Agency ◽  
Surface Soil ◽  
Soil Samples ◽  
Petroleum Resource ◽  
Significant Difference ◽  
Rivers State ◽  
Pb Concentration

The study assessed the concentration of heavy metals in three oil spill sites in Emohua local government area in Rivers State, Nigeria. Soil samples were collected at depth 0-30cm for surface soil samples and up to 10m for sub-surface soil samples depending on the depth of borehole. Groundwater samples were collected from drilled boreholes while the surface water samples were collected from fishponds or water bodies (rivers) close to the oil spill sites. The samples taken from the oil spill sites were analysed to determine the level of concentration of 10 Department of Petroleum Resource (DPR) specified heavy metals (Cd, Zn, Cu, Pb, Cr, Ba, Ni, Hg, As, and Co). BUCK Scientific Atomic Absorption Spectrophotometer (AAS) was used in detecting the concentration of the heavy metals. For the surface soil, Pb concentration in site A and B were significantly higher than what was obtained at site C, with a mean concentration of 219.70, 130.01 and 3.41mg/kg respectively for the three sites. The mean lead (Pb) concentration obtained in the surface soil was within DPR and United State Environmental Protection Agency (USEPA) acceptable limits. Barium also has significant concentration in both the surface soil and sub-surface soil. Kruskal Wallis test indicated significant difference in the Pb, Cd, Zn, Cu, Cr and Ba concentration in surface/topsoil among the three sites and also indicated significant difference in the concentrations of Pb, Cd, Cr, Ni, Ba and As in sub-surface soil among the sites. Little heavy metal concentration was found in both the groundwater and surface water. The study showed that even if some heavy metals were detected at the oil spill sites, they do not pose any serious health risk, as all the heavy metals in the four environmental media at the three sampling sites were below the national limit stipulated by the Department of Petroleum Resource (DPR), Nigeria.

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