Applications of Bentonite to Soil Decontamination

2018 ◽  
Vol 69 (7) ◽  
pp. 1695-1698
Author(s):  
Marin Rusanescu ◽  
Carmen Otilia Rusanescu ◽  
Gheorghe Voicu ◽  
Mihaela Begea

A calcium bentonite from Orasu Nou deposit (Satu Mare Romania) was used as raw material. We have conducted laboratory experiments to determine the influence of bentonite on the degree of heavy metal retention. It has been observed that the rate of retention increases as the heavy metal concentration decreases. Experimental studies have been carried out on metal retention ( Zn) in bentonite. In this paper, we realized laboratory experiments for determining the influence of metal (Zn) on the growth and development of two types of plants (Pelargonium domesticum and Kalanchoe) and the effect of bentonite on the absorption of pollutants. These flowers were planted in unpolluted soil, in heavy metal polluted soil and in heavy metal polluted soil to which bentonite was added to observe the positive effect of bentonite. It has been noticed that the flowers planted in unpolluted soil and polluted with heavy metals to which bentonite has been added, the flowers have flourished, the leaves are still green and the plants whose soils have been polluted with heavy metals began to dry after 6 days, three weeks have yellowish leaves and flowers have dried. Experiments have demonstrated the essential role of bentonite for the removal of heavy metals polluted soil.

2001 ◽  
Vol 44 (10) ◽  
pp. 53-58 ◽  
Author(s):  
L. C. Aralp ◽  
A. Erdincler ◽  
T. T. Onay

Heavy metal concentration in sludge is one of the major obstacles for the application of sludge on land. There are various methods for the removal of heavy metals in sludge. Using sulfur oxidizing bacteria for microbiological removal of heavy metals from sludges is an outstanding option because of high metal solubilization rates and the low cost. In this study, bioleaching by indigenous sulfur oxidizing bacteria was applied to sludges generated from the co-treatment of municipal wastewater and leachate for the removal of selected heavy metals. Sulfur oxidizing bacteria were acclimated to activated sludge. The effect of the high organic content of leachate on the bioleaching process was investigated in four sets of sludges having different concentrations of leachate. Sludges in Sets A, B, C and D were obtained from co-treatment of wastewater and 3%, 5%, 7% and 10% (v/v) leachate respectively. The highest Cr, Ni and Fe solubilization was obtained from Set A. Sulfur oxidizing bacteria were totally inhibited in Set D that received the highest volume of leachate.


2021 ◽  
Vol 24 (12) ◽  
pp. 2183-2189
Author(s):  
R. Ogunlana ◽  
A.I. Korode ◽  
Z.F. Ajibade

Some heavy metals have bio-importance as trace elements but the bio-toxic effects of many of them in human biochemistry are of great concern. The level of heavy metals concentrations of transformer oil polluted soil was assessed in Akungba Akoko community of Ondo State, Nigeria using Atomic Absorption Spectrophotometer. The concentration of heavy metals investigated ranges from: Cu (1400-18)mg/kg, Fe (96700- 15500)mg/kg, Cd (2- 0.5)mg/kg, Mn (62-29)kg/mg, Ni(5-1)mg/kg, Al(27-11)mg/kg, Zn(1400- 44)mg/kg, Pd (68-20)mg/kg and Ca (570- 135)mg/kg. From the study, it was observed that some transformer sites had more concentration of heavy metals than others, as a result of the heavy metals content of the transformer soil released to the surrounding soil, while in some samples of these heavy metals were absent or are below detection limit. Comparing the results with the World Health Organisation (W.H.O) maximum allowable limit in soil with results of the results of different samples collected, majority of the results were found to fall below W.H.O limit which implies that those sites are still contamination free with respect to the specific heavy metal and caution needs to be taken urgently to avoid potential contamination. Meanwhile, heavy metal concentration at some sites have gone beyond the W.H.O maximum allowable limit, calling for immediate remediation of the site.


Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4194
Author(s):  
Gabriela Toader ◽  
Daniela Pulpea ◽  
Traian Rotariu ◽  
Aurel Diacon ◽  
Edina Rusen ◽  
...  

The issue of heavy metal and radionuclide contamination is still causing a great deal of concern worldwide for environmental protection and industrial sites remediation. Various techniques have been developed for surface decontamination aiming for high decontamination factors (DF) and minimal environmental impact, but strippable polymeric nanocomposite coatings are some of the best candidates in this area. In this study, novel strippable coatings for heavy metal and radionuclides decontamination were developed based on the film-forming ability of polyvinyl alcohol, with the remarkable metal retention capacity of bentonite nanoclay, together with the chelating ability of sodium alginate and with “new-generation” “green” complexing agents: iminodisuccinic acid (IDS) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC). These environmentally friendly water-based decontamination solutions are capable of generating strippable polymeric films with optimized mechanical and thermal properties while exhibiting high decontamination efficiency (DF ≈ 95–98% for heavy metals tested on glass surface and DF ≈ 91–97% for radionuclides 241Am, 90Sr-Y and 137Cs on metal, painted metal, plastic, and glass surfaces).


Author(s):  
Ngo The Cuong ◽  
Tran Hoan Quoc ◽  
Svetlana Vasilievna Zolotokopova

The article focuses on the study of change of containing heavy metals (zinc, copper, iron, cadmium, lead, arsenic) in the abiotic and biotic components of the Serepok river (Vietman) influenced by wastewater discharge from industrial areas. Heavy metal content was determined in the river water and bottom sediments in the four zones: above and within the boundaries of industrial regions Xoa Phu and Tam Thang and in two water reservoirs situated below the boundaries of those industrial areas. Tilapia Galilean ( Sarotherodon galilaeus ), Hemibagrus ( Hemibagrus ), and sazan ( Cyprinus carpio ) caught in these areas were the hydrobionts under study in which liver, gills, skeleton and muscles accumulation of heavy metals was detected. In the organs of fish caught in the river within industrial region, heavy metals concentration was 3-7 times higher. The greatest concentration of heavy metals was found in the liver and gills of fish caught in the boundaries of industrial regions, the least concentration was in the muscles. In most cases, significant correlation between heavy metal concentration in organs of fishes and in river water, bottom sediments has been revealed.


Author(s):  
MdDidarul Islam, Ashiqur Rahaman, Aboni Afrose

This study was based on determining concentration of essential and toxic heavy metal in coconut water available at a local Hazaribagh area in Dhaka, Bangladesh. All essential minerals, if present in the drinking water at high concentration or very low concentration, it has negative actions. In this study, fifteen samples and eight heavy metals were analyzed by Atomic Absorption Spectroscopy (AAS) method which was followed by wet ashing digestion method. The concentration obtained in mg/l were in the range of 0.3 to 1.5, 7.77 to 21.2, 0 to 0.71, 0 to 0.9, 0 to 0.2, 0.9 to 17.3, 0.1 to 0.9, 0 to 0.9 and 0 to 0.7 for Fe, Ni, Cu, Cd, Cr, Zn, Pb and Se respectively. From this data it was concluded that any toxic heavy metals like Cd, Cr, Pb and Ni exceed their toxicity level and some essential nutrients were in low concentration in those samples. 


2016 ◽  
Vol 5 (10) ◽  
pp. 4933
Author(s):  
Sabia Sultana ◽  
A. K. M. Nur Alam Siddiki ◽  
Md. Rokonujjaman ◽  
M. Niamul Naser ◽  
Abdus Salam ◽  
...  

The heavy metal concentration (e.g., Mn, Zn, Pb and Ni) were determined in soft tissues and shells of freshwater mussels (Lamellidens marginalis) at the various sites of Dhanmondi lake, Dhaka, Bangladesh between the period April, 2010 and March 2011. The heavy metal concentrations in shells and soft tissues of freshwater mussels were tended to vary significantly among sampling points and seasons in Dhanmondi Lake. Distribution of heavy metals in shell and soft tissue of Lamellidens marginalis followed the order Mn>Zn>Pb>Ni, respectively. According to the t-test, level of manganese, zinc and lead under investigation between shell and tissue showed statistically significant differences [Mn: t=-11.387; df=16; P=0.000; Zn: t=-2.590; df=16; P=0.020 and Pb: t=-2.8679; df=16; P=0.011].


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
M. Azizul Moqsud

AbstractIn this research, bioremediation of tsunami-affected polluted soil has been conducted by using collective microorganisms and recycled waste glass. The Tohoku earthquake, which was a mega earthquake in Japan triggered a huge tsunami on March 11th, 2011 that caused immeasurable damage to the geo-environmental conditions by polluting the soil with heavy metals and excessive salt content. Traditional methods to clean this polluted soil was not possible due to the excess cost and efforts. Laboratory experiments were conducted to examine the capability of bioremediation of saline soil by using recycled waste glass. Different collective microorganisms which were incubated inside the laboratory were used. The electrical conductivity (EC) was measured at different specified depths. It was noticed that the electrical conductivity decreased with the assist of the microbial metabolisms significantly. Collective microorganisms (CM2) were the highly capable to reduce salinity (up to 75%) while using recycled waste glass as their habitat.


2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.


1994 ◽  
Vol 30 (10) ◽  
pp. 173-177 ◽  
Author(s):  
Lee Chan-Won ◽  
Kwon Young-Tack

Over the past two decades, the coastal waters of Jinhae Bay have been extensively used by coastal communities and industries for the disposal of domestic and various industrial wastes, therefore increasing the level of pollutants in coastal waters with a subsequent increase in sediments, especially of heavy metals. Specific objectives of this research are to investigate the distribution of heavy metal concentration in biota, to compare the concentrations with those in sediment and water and to relate the bioconcentration to the different heavy metals in biota obtained from several sites. Sixty one percent of heavy metals was found in particulate form during the high runoff season and 32% during the dry season. The behavior of the particulate metals after flowing in to the enclosed coastal sea is an important factor in heavy metal contamination. Copper, lead and chromium contamination of sediment was revealed at several sites. The bioconcentration factors (BCFs) of zinc, cadmium, copper, nickel, chromium and lead by the mussel (Mytilus edulis) were determined as 2,900, 2,814, 807, 423, 228 and 127 in the decreasing order, respectively. The areas located nearest to highly populated city and industries exhibited mussels with the largest accumulation of copper, lead and chromium.


Forests ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1608
Author(s):  
Aslihan Esringü ◽  
Metin Turan ◽  
Asli Cangönül

Heavy metal pollution is among the important environmental problems in the world. Many techniques have already been used to remove the heavy metals such as lead (Pb) and cadmium (Cd). Among them, the phytoremediation method is an environmentally friendly and green technology. This study was carried out to determine the efficiency of fulvic acid (FA) application in removing Pb and Cd from polluted soil using Tagetes eracta L. and Zinnia elegans Jacq. ornamental plants. The results indicated that, FA application, number of flower per plants, and plant fresh weight of Tagetes eracta plants and Zinnia elegans plants increased 187.5%, 104.5% and 155.5%, 57.7%, respectively with application of 7000 mg L−1 FA at 100 mg kg−1 Pb pollution condition, whereas 42.85%, 16.5%, and 44.4–36.1% with application of 7000 mg L−1 FA at 30 mg kg±1 Cd pollution condition, respectively. With the FA application in the Zinnia elegans plant, the root part has accumulated 51.53% more Pb than the shoot part. For Cd, the shoot part accumulated 35.33% more Cd than the root. The effect of FA application on superoxide dismutase (SOD), peroxidase (POD) and, catalase (CAT) of the Tagetes eracta were decreased as 32.7%, 33.1%, and 35.1% for Pb, 21.2%, 25.1%, and 26,1%, for Cd, and 15.1%, 22.7%, and 37.7% for Pb, and 7.55%, 18.0%, and 18.8% for Cd were in Zinnia elegans respectively. In conclusion, Tagetes eracta and Zinnia elegans can not be recommended for remediation of Pb and Cd polluted area, but FA can be recommended for Pb and Cd stabilization in polluted soil.


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