Suitability of ozone pre-treatment for amoxicillin wastewater

2013 ◽  
Vol 68 (11) ◽  
pp. 2492-2496 ◽  
Author(s):  
O. Lefebvre ◽  
X. Shi ◽  
J. G. Tein ◽  
H. Y. Ng
Keyword(s):  
Biochemical Oxygen Demand ◽  
Biological Treatment ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Biological Degradation ◽  
Reactor Performance ◽  
Pharmaceutical Wastewater ◽  
Pre Treatment ◽  
By Products

This study deals with the ozonation of amoxicillin in real pharmaceutical wastewater and its efficacy as a pre-treatment, prior to biological degradation by a mixed culture of bacteria in a sequencing batch reactor (SBR). An ozone utilization of 0.27 g/g-COD (chemical oxygen demand) lowered the pH of the wastewater to 6.6, reduced the specific ultraviolet absorption by 43% and increased the biochemical oxygen demand (BOD) concentration by 37%. The BOD:COD ratio became equal to 0.89, making the ozonated wastewater seemingly suitable for biological treatment; however, when the ozonated effluent was fed to the SBR, the reactor performance degraded, an effect which was attributed to ozonation by-products. In conclusion, ozonation might not be a suitable pre-treatment for pharmaceutical wastewater containing amoxicillin, and biotreatment with properly acclimated biomass may be a better option for treatment of such pharmaceutical wastewater.

Peranan BOD biosensor untuk proses optimasi pengolahan limbah sintetik di SBR

2019 ◽  
Vol 1 (2) ◽  
pp. 1
Author(s):  
Lindawati Lindawati
Keyword(s):  
Biochemical Oxygen Demand ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Oxygen Demand

Sebuah Sequencing Batch Reactor (SBR) digunakan untuk mengevaluasi peranan Biochemical Oxygen Demand (BOD) biosensor dalam proses optimasi proses pengolahan nutrien karbon, nitrogen dan fosfat. Hasil penelitian menunjukkan bahwa BOD biosensor dapat dipergunakan untuk penentuan karbon organik, sehingga reduksi siklus SBR dapat dilakukan dan efisiensi proses meningkat. Pola konsumsi karbon organik ditemukan dengan adanya ‘tanda diam’ pada fase anoksik/ anaerobik, di mana dari tanda ini, fase aerobik dapat segera dimulai. Reduksi durasi siklus SBR dari 8 jam menjadi 4 jam meningkatkan efiesiensi pengolahan C, N dan P yang meningkat pula (hampir dua kali lebih tinggi).

scholarly journals Sequencing batch reactor process for the removal of nitrogen from anaerobically treated domestic wastewater

2018 ◽  
Vol 77 (6) ◽  
pp. 1581-1590 ◽  
Author(s):  
L. Pelaz ◽  
A. Gómez ◽  
A. Letona ◽  
G. Garralón ◽  
M. Fdz-Polanco
Keyword(s):  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Anaerobic Treatment ◽  
Cycle Times ◽  
Working Volume ◽  
Nitrogen Ratio ◽  
Pre Treatment ◽  
Kjeldahl Nitrogen

Abstract This work presents the performance of a sequencing batch reactor (SBR) system used as a means of removing nitrogen from domestic wastewater containing a low chemical oxygen demand (COD) to nitrogen ratio due to pre-treatment with an anaerobic reactor. The aim of the work was to determine the feasibility of this system for the removal of nitrogen from the domestic wastewater. An SBR with a working volume of 5 L was investigated at different cycle times of 12, 8 and 6 h, at 18 °C. The efficiency of the SBR varied together with the duration of the cycle, where the optimum performance was seen in the 6 h cycle with the anoxic–aerobic–anoxic sequence. Due to the low quantity of organic matter present in the domestic wastewater after the anaerobic treatment, an additional supply of external carbon was necessary before the second anoxic stage. The removal efficiencies obtained were: 98% for total Kjeldahl nitrogen, 84% for total nitrogen and 77% for soluble COD. The reactor was thus shown to be viable, and it was concluded that this process may be successfully applied as a post-treatment for the removal of nitrogen from anaerobically treated domestic wastewater.

Biological Treatment of Poultry Slaughterhouse Wastewater by Using Different Fibers

2015 ◽  
Vol 802 ◽  
pp. 401-405 ◽  
Author(s):  
Nur Nasuha Ahmad Puat ◽  
Hamidi Abdul Aziz
Keyword(s):  
Biological Treatment ◽  
Room Temperature ◽  
Suspended Solids ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Slaughterhouse Wastewater ◽  
Average Percentage ◽  
Pollutant Concentrations ◽  
Overall Performance

This study evaluated the performance of sequencing batch reactor (SBR) with and without the fibers of poultry slaughterhouse wastewater (PSWW). The fibers act as attachment materials to the suspended solids, which are considered as pollutant in PSWW. PSWW contains high-pollutant concentrations. Experiments were conducted using two 60 L laboratory SBR reactors at room temperature (25 °C) and pH 7±0.5. The removal percentage of SBR with and without the fibers was compared in terms of chemical oxygen demand and biological oxygen demand. The removal percentage of SBR with fibers showed higher overall performance, which was approximately 90%. Meanwhile, the removal of SBR without fibers achieved an average percentage of about 70%, which was slightly lower compared with SBR reactor with fibers.

On-site treatment of a motorway service area wastewater using a package sequencing batch reactor (SBR)

2005 ◽  
Vol 51 (10) ◽  
pp. 311-316 ◽  
Author(s):  
J. Del Solar ◽  
S. Hudson ◽  
T. Stephenson
Keyword(s):  
Biochemical Oxygen Demand ◽  
Suspended Solids ◽  
Sequencing Batch Reactor ◽  
Loading Rate ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Poor Performance ◽  
Service Area ◽  
Average Flow ◽  
Cycle Times

A sequencing batch reactor (SBR) treating the effluent of a motorway service station in the south of England situated on a major tourist route was investigated. Wastewater from the kitchens, toilets and washrooms facilities was collected from the areas on each side of the motorway for treatment on-site. The SBR was designed for a population equivalent (p.e.) of 500, assuming an average flow of 100 m3/d, influent biochemical oxygen demand (BOD) of 300 mg/l, and influent suspended solids (SS) of 300 mg/l. Influent monitoring over 8 weeks revealed that the average flow was only 65 m3/d and the average influent BOD and SS were 480 mg/l and 473 mg/l respectively. This corresponded to a high sludge loading rate (F:M) of 0.42 d−1 which accounted for poor performance. Therefore the cycle times were extended from 6 h to 7 h and effluent BOD improved from 79 to 27 mg/l.

scholarly journals Catalytic wet oxidation of high concentration pharmaceutical wastewater with Fe3+ as catalyst

2018 ◽  
Vol 2017 (3) ◽  
pp. 661-666
Author(s):  
Xu Zeng ◽  
Jun Liu ◽  
Jianfu Zhao
Keyword(s):  
Oxygen Pressure ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Kinetic Studies ◽  
Cod Removal ◽  
Wet Oxidation ◽  
Catalytic Wet Oxidation ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Temperature Time

Abstract Catalytic wet oxidation of high concentration pharmaceutical wastewater with Fe3+ as catalyst was carried out in a batch reactor. Results showed that the degradation of pharmaceutical wastewater was enhanced significantly by Fe3+. The effects of reaction parameters, such as the catalyst dose, reaction temperature, time, and initial oxygen pressure, were discussed. The chemical oxygen demand (COD) removal increased with the increases of catalyst dose, temperature, time and oxygen supply. With the initial COD 34,000–35,000 mg/L, approximately 70% COD removal can be achieved under the conditions of catalyst 1.0 g and oxygen pressure 1.0 MPa at 250 °C after 60 min. The results of kinetic studies showed that two reaction steps existed in this oxidation process, which followed an apparent first-order rate law. This process provides an effective approach for the pretreatment of high concentration pharmaceutical wastewater.

scholarly journals Dynamic control of nutrient-removal from industrial wastewater in a sequencing batch reactor, using common and low-cost online sensors

2015 ◽  
Vol 73 (4) ◽  
pp. 740-745 ◽  
Author(s):  
Jan Dries
Keyword(s):  
Activated Sludge ◽  
Nutrient Removal ◽  
Industrial Wastewater ◽  
Sequencing Batch Reactor ◽  
Batch Reactor ◽  
Low Cost ◽  
Dynamic Control ◽  
Oxygen Demand ◽  
Oxidation Reduction ◽  
Oxidation Reduction Potential

On-line control of the biological treatment process is an innovative tool to cope with variable concentrations of chemical oxygen demand and nutrients in industrial wastewater. In the present study we implemented a simple dynamic control strategy for nutrient-removal in a sequencing batch reactor (SBR) treating variable tank truck cleaning wastewater. The control system was based on derived signals from two low-cost and robust sensors that are very common in activated sludge plants, i.e. oxidation reduction potential (ORP) and dissolved oxygen. The amount of wastewater fed during anoxic filling phases, and the number of filling phases in the SBR cycle, were determined by the appearance of the ‘nitrate knee’ in the profile of the ORP. The phase length of the subsequent aerobic phases was controlled by the oxygen uptake rate measured online in the reactor. As a result, the sludge loading rate (F/M ratio), the volume exchange rate and the SBR cycle length adapted dynamically to the activity of the activated sludge and the actual characteristics of the wastewater, without affecting the final effluent quality.

Degradation of wine distillery wastewaters by the combination of aerobic biological treatment with chemical oxidation by Fenton's reagent

2005 ◽  
Vol 51 (1) ◽  
pp. 167-174 ◽  
Author(s):  
J. Beltran de Heredia ◽  
J. Torregrosa ◽  
J.R. Dominguez ◽  
E. Partido
Keyword(s):  
Chemical Oxygen Demand ◽  
Aromatic Compounds ◽  
Biological Treatment ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Chemical Oxidation ◽  
Utilization Rate ◽  
Fenton’S Reagent ◽  
Kinetic Rate Constant ◽  
Fenton's Reagent

The degradation of wine distillery wastewaters by aerobic biological treatment has been investigated in a batch reactor. The evolution of the chemical oxygen demand, biomass and total contents of polyphenolic and aromatic compounds was followed through each experiment. According to the Contois model, a kinetic expression for the substrate utilization rate is derived, and its biokinetic constant is evaluated. The final effluents of the aerobic biological experiments were oxidized by Fenton's reagent. The evolution of chemical oxygen demand, hydrogen peroxide concentration and total contents of polyphenolic and aromatic compounds was followed through each experiment. A kinetic model to interpret the experimental data is proposed. The kinetic rate constant of the global reaction is determined.

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