Abstract
In a core disruptive accident scenario, boron carbide, which is used as control rod material, may melt below the melting temperature of stainless steel due to the eutectic reaction with it. Produced eutectic mixture is assumed to relocate widely in the degraded core, and this behavior plays an important role to reduce the neutronic reactivity of the degraded core materials significantly. However, these behaviors have never been simulated in the severe accident computer codes, and reducing the uncertainty is important for reasonable assessment. To contribute improvement of the core disruptive accident analysis code to handle these eutectic melting and relocation behavior, authors had been carried out the evaluation of the thermophysical properties of stainless steel containing boron carbide, which needed as a basic data for cord improvement. Since the solubility range of boron against iron is expected to be wide, the crystalline phase of eutectic mixture may change according to boron concentration in the eutectic mixture. And this may affect the thermophysical properties themselves.
In this work, the density and specific heat of stainless steel containing 17 mass% boron carbide in a solid state are obtained and compared with these of stainless steel containing 0 and 5 mass% boron carbide. By adding 17 mass boron carbide to stainless steel type 316L, the density decreased approximately 24% and the specific heat increased approximately 25% at 293 K. The density of stainless steel containing boron carbide tended to decrease almost linearly depending on the amount of boron carbide added, none the less for difference of crystalline phase. On the other hand, increasing trend of the specific heat of stainless steel containing 17 mass% boron carbide accompanying elevating temperature showed different behavior from that of stainless steel containing 0 and 5 mass% boron carbide. This difference in the trend of the specific heat was considered to be caused the difference in the crystalline phase.
BORON CARBIDE-GRAPHITE NUCLEAR CONTROL-ROD MATERIAL: PREPARATION, THERMAL STABILITY, AND IRRADIATION EVALUATION
