Multifaceted Synthesis, Properties and Applications of Polyurethanes and its Composites

2019 ◽  
Vol 23 (4) ◽  
pp. 361-389 ◽  
Author(s):  
Shivang K. Desai ◽  
Smritilekha Bera ◽  
Dhananjoy Mondal

The primary aim of this article is to update many important synthetic pathways, properties and applications of the polyurethanes and its composites. Polyurethanes (PUs) are a special group of versatile materials with a great potential for different use in the development of modern, healthy and clean society, including its multifaceted use in the fields of construction and building related work, transportation, furniture and bedding, appliances, packaging, textiles, fibres, apparel, machinery and foundry, electronics, footwear, medical and so forth. Over the last 8-9 decades, several synthetic strategies of the diverse polyurethanes (PUs) are maturely designed and actively executed using various sustainable and non-sustainable methods for miscellaneous applications in different areas. The major advantages of the modern PUs are to impose desired properties in the materials pertinent to the field of work during their preparation by changing a different kind of monomers and additives. Briefly, this review summarizes the overall accounts, importance, synthetic approaches, properties, and miscellaneous applications in the desired scenario in details.

2018 ◽  
Vol 35 (1) ◽  
pp. 45-72 ◽  
Author(s):  
Lorenzo M. Polgar ◽  
Francesca Fallani ◽  
Juul Cuijpers ◽  
Patrizio Raffa ◽  
Antonius A. Broekhuis ◽  
...  

Abstract Water-swellable elastomers (WSE) constitute a class of rubbery materials that have been widely studied both in academia and industry during the last 25 years. Market pull is the major driver for the exploration of these materials. The need of WSE in several sealing applications has driven the attention of many academic researchers toward the possibility to provide a rubber with water-swelling characteristics. As commercial rubbers are hydrophobic materials, making them swell in water presents an interesting and difficult challenge. This paper reviews the scientific and patent literature on the fundamental aspects of WSE: the various synthetic approaches, the properties of the corresponding polymers (not only the swelling performance but also the mechanical behavior), and some of their applications. Particular attention is paid to the chemical structure/performance relationships of WSE. Finally, the authors speculate on a great future for WSE that can be rationally designed for improved and/or new applications.


2021 ◽  
Vol 11 (5) ◽  
pp. 1978
Author(s):  
Zaneta Swiatkowska-Warkocka

Bimetal CuFe (copper-iron) nanoparticles, which are based on the earth-abundant and inexpensive metals, have generated a great deal of interest in recent years. The possible modification of the chemical and physical properties of these nanoparticles by changing their size, structure, and composition has contributed to the development of material science. At the same time, the strong tendency of these elements to oxidize under atmospheric conditions makes the synthesis of pure bimetallic CuFe nanoparticles still a great challenge. This review reports on different synthetic approaches to bimetallic CuFe nanoparticles and bimetallic CuFe nanoparticles supported on various materials (active carbide, carbide nanotubes, silica, graphite, cellulose, mesoporous carbide), their structure, physical, and chemical properties, as well as their utility as catalysts, including electrocatalysis and photocatalysis.


2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.


This review paper covers the major synthetic approaches attempted towards the synthesis of some Non-Steroidal Anti-Inflammatory Drugs (Naproxen, Ibuprofen and Nabumetone)


2020 ◽  
Author(s):  
André Schumann ◽  
Jonas Bresien ◽  
Malte Fischer ◽  
Christian Hering-Junghans

Cyclotriarsanes are rare and limited synthetic approaches have hampered reactivity studies on these systems. Described in here is a scalable synthetic protocol towards (AsAr)<sub>3</sub> (Ar = Dip, 2,6-<sup>i</sup>Pr<sub>2</sub>-C<sub>6</sub>H<sub>3</sub>; Tip, 2,4,6-<sup>i</sup>Pr<sub>3</sub>-C<sub>6</sub>H<sub>2</sub>), which allowed to study their reactivity towards [Cp<sub>2</sub>Ti(C<sub>2</sub>(SiMe<sub>3</sub>)<sub>2</sub>], affording titanocene diarsene complexes and towards N-heterocyclic carbenes (NHCs) to give straightforward access to a variety of NHC-arsinidene adducts. The electronic structure of the titanium diarsene complxes has been studied and they are best described as Ti(IV) species with a doubly reduced As<sub>2</sub>Ar<sub>2</sub> ligand. These findings will make (AsAr)<sub>3</sub> valuable precursors in the synthetic inorganic and organic chemistry.


2020 ◽  
Vol 84 (11) ◽  
pp. 1366-1369
Author(s):  
S. V. Stolyar ◽  
V. P. Ladygina ◽  
A. V. Boldyreva ◽  
O. A. Kolenchukova ◽  
A. M. Vorotynov ◽  
...  

Author(s):  
Maulana Akbar Shah @ U Tun Aung

Abstract In addition to compliance with the five pillars of Islam, Da’wah Islamiyyah is an indispensable act for Muslims who view their life missions as to propagate Islam. The act of da’wah is a mission only undertaken by those who are selected to do so, as Allah SWT said: “You are the best of peoples, taken out for mankind, you enjoin what is right, forbid what is wrong…,” (Al-Qur’an, Al- `Imran, 3:110). The phrase “you are taken out for mankind” is a very clear phrase which refers to a special group. Many du’at propagate Islam through regular procedures. In this contemporary day and age, it would be more successful if creative da’wah methodologies are used to special groups where special talent is required. Examples of these special target groups are individuals such as [1] pregnant mothers, [2] mothers of new born babies, [3] parents of toddlers, [4] parents of children [5] youth, teenagers and adolescents, [6] married couples, [7] elderly or aged individuals and [8] non-Muslims.  They are good targets to promote Islam. Thus, du’at must have special talents and knowledge to do so. In this regard, du’at must be equipped with exceptional knowledge of the target groups to propagate Islam effectively. The present paper attempts to highlight the distinctive natures of the above mentioned categories of individuals and explores how du’at should approach them when he or she encounters them for the purpose of promoting Islam.        Keywords: Call to Islam, Da’wah Islamiyyah, creative da’wah, creative da’ie, enjoin good, forbid evil.   Abstrak Selain mematuhi 5 rukun Islam, dakwah Islamiyyah tidak dapat diasingkan daripada seseorang Muslim yang bermatlamat untuk menyebarkan ajaran Islam. Berdakwah adalah suatu tugas yang hanya dijalankan oleh mereka yang terpilih. Seperti yang diwahyukan oleh Allah SWT “Kamu adalah sebaik-baik umat yang dilahirkan bagi umat manusia, kerana kamu menyuruh berbuat segala perkara yang baik dan melarang daripada segala perkara yang buruk dan keji...” (Al-Quran, Al-Imran, 3:110). Frasa “umat yang dilahirkan bagi umat manusia”  jelas dinyatakan di mana ia merujuk kepada satu golongan yang istimewa. Kebanyakan pendakwah menyebarkan Islam melalui metodologi yang sudah menjadi kebiasaan. Bagaimanapun, pada zaman ini, pendakwahan akan lebih berjaya jika kaedah yang kreatif digunakan kepada beberapa golongan yang tertentu. Antara contoh golongan yang dimaksudkan adalah [1] wanita yang mengandung, [2] ibu kepada bayi yang baru lahir, [3] ibu bapa kepada anak-anak kecil, [4] ibu bapa kepada kanak-kanak, [5] golongan belia dan remaja, [6] pasangan suami isteri, [7] warga emas, dan [8] golongan bukan Islam. Mereka merupakan sasaran yang sempurna untuk mempelajari Islam. Oleh hal demikian, para pendakwah mesti mempunyai bakat yang istimewa dan ilmu yang mencukupi untuk berdakwah. Para pendakwah juga harus memahami kumpulan sasaran dengan menyeluruh supaya penyebaran ajaran Islam akan lebih berkesan. Tujuan penulisan ini adalah untuk menggariskan sifat unik golongan yang dinyatakan di atas dan menerokai bagaimana para pendakwah harus mendekati mereka dengan niat untuk menyebarkan Islam.   Kata Kunci: Panggilan kepada Islam, dakwah Islamiyyah, dakwah kreatif, da’ie kreatif, menyuruh kepada kebaikan, menghalang daripada kejahatan.  


2013 ◽  
Vol 20 (22) ◽  
pp. 2798-2811 ◽  
Author(s):  
M. Gordaliza ◽  
P. Baraldi
Keyword(s):  

2020 ◽  
Vol 28 (2) ◽  
pp. 213-237 ◽  
Author(s):  
Andrea Mastinu ◽  
Giovanni Ribaudo ◽  
Alberto Ongaro ◽  
Sara Anna Bonini ◽  
Maurizio Memo ◽  
...  

: Cannabidiol (CBD) is a non-psychotropic phytocannabinoid which represents one of the constituents of the “phytocomplex” of Cannabis sativa. This natural compound is attracting growing interest since when CBD-based remedies and commercial products were marketed. This review aims to exhaustively address the extractive and analytical approaches that have been developed for the isolation and quantification of CBD. Recent updates on cutting-edge technologies were critically examined in terms of yield, sensitivity, flexibility and performances in general, and are reviewed alongside original representative results. As an add-on to currently available contributions in the literature, the evolution of the novel, efficient synthetic approaches for the preparation of CBD, a procedure which is appealing for the pharmaceutical industry, is also discussed. Moreover, with the increasing interest on the therapeutic potential of CBD and the limited understanding of the undergoing biochemical pathways, the reader will be updated about recent in silico studies on the molecular interactions of CBD towards several different targets attempting to fill this gap. Computational data retrieved from the literature have been integrated with novel in silico experiments, critically discussed to provide a comprehensive and updated overview on the undebatable potential of CBD and its therapeutic profile.


Sign in / Sign up

Export Citation Format

Share Document