scholarly journals Using Fenton Oxidation Method to Advanced Treatment of Landfill Leachate

2015 ◽  
Vol 9 (1) ◽  
pp. 58-61 ◽  
Author(s):  
Gao Yanjiao ◽  
Huang Runzhu ◽  
Song Tiehong
Keyword(s):  
Hydrogen Peroxide ◽  
Reaction Time ◽  
Landfill Leachate ◽  
Ferrous Sulfate ◽  
Ph Value ◽  
Removal Rate ◽  
Advanced Treatment ◽  
Test Results ◽  
Optimal Conditions ◽  
Optimal Reaction

Hydrogen peroxide and ferrous sulfate were used to advanced treatment of landfill leachate effluent from biochemical tanks. Some influences on removing COD and chroma including the pH value of solution, the dosage of ferrous sulfate, the dosage of hydrogen peroxide and reaction time were investigated. The test results showed that for removal of COD and chroma the optimal pH was 3.0, the best ferrous sulfate and hydrogen peroxide dosage was 1500mg/L, 20mL/L respectively, and the optimal reaction time was 60min. Under optimal conditions, COD and chroma removal rate could reach 79.7% and 95.2% respectively.

The Removal of High NH3-N Concentration in Landfill Leachate by Chemical Precipitation

2011 ◽  
Vol 281 ◽  
pp. 305-308
Author(s):  
Wei Hua Song ◽  
Jun Yin ◽  
Yu Wang
Keyword(s):  
Crystal Structure ◽  
Reaction Time ◽  
Landfill Leachate ◽  
Ph Value ◽  
Removal Rate ◽  
Chemical Precipitation ◽  
Municipal Landfill ◽  
N Concentration

The municipal landfill leachate concentration was 1670mg / L, NH3-N in leachate was fomed MgNH4PO4· 6H2O crystal precipitation by adding MgSO4 · 7H2O and Na2HPO4 · 12H2O. pH value, reaction timeand chemical dosage ratio was discussed. The results shows that the suitable reaction pH value is between 8 and 9.When PH value is too high, the crystal structure would bedest- ructed,it will make the fixed ammonia escaped from MgNH4PO4. Mg2+: NH4+: PO43-= 1.4:1:1.4 is the best choise under the conditions of pH 8.5, reaction time =20 min.The concentration of NH3-N in leachate was decreased from 1671Mg / L to 175Mg / L,the removal rate reaches to 98.5%.

Advanced Treatment of Biochemical Treated Coking Wastewater by Ozonation Process

2013 ◽  
Vol 726-731 ◽  
pp. 2515-2520 ◽  
Author(s):  
De Min Yang ◽  
Jian Mei Yuan
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Ozone Concentration ◽  
Ph Value ◽  
Removal Rate ◽  
Color Removal ◽  
Advanced Treatment ◽  
Coking Wastewater ◽  
Initial Ph ◽  
Ozonation Process

Advanced treatment of biochemical treated coking wastewater was studied experimentally with ozonation process. The effects of initial pH value, ozone concentration, reaction temperature, and reaction time on the COD and color removal rate were investigated. The results showed that ozonation was an effective method for advanced treatment of biochemical treated coking wastewater. The increasing of initial pH value, ozone concentration, reaction temperature, and reaction time has enhanced the removal rate of COD and color. Meanwhile, the results also revealed that the maximal COD and color removal rate of 69.65% and 92.27% could be reached under the optimal conditions of the initial pH value is 10.5, ozone concentration is 150 mg/L, reaction temperature is 298 K, and reaction time is 30 min.

Microwave-Ferrous Sulfate Modified Activated Carbon Adsorption Study on Phosphorus Removal

2014 ◽  
Vol 919-921 ◽  
pp. 2149-2152
Author(s):  
Ya Feng Li ◽  
Chun Fei Wei
Keyword(s):  
Activated Carbon ◽  
Reaction Time ◽  
Phosphorus Removal ◽  
Ferrous Sulfate ◽  
Removal Rate ◽  
High Concentration ◽  
Activated Carbon Adsorption ◽  
Modified Activated Carbon ◽  
Carbon Adsorption ◽  
Treated Effluent

Using microwave-ferrous sulfate modified activated carbon adsorption manner to remove the high concentration of phosphorus in wastewater. The power of microwavethe concentration of ferrous sulfate and reaction time on phosphorus removal were studied. When the power of microwave was 425W,the concentration of ferrous sulfate was 0.1mol/L,reaction time was 50 min,the removal rate of TP reaches 95.67%,the treated effluent TP can be dropped to 0.48mg/L,the TP can reaches the first effluent standard of TP in the comprehensive wastewater discharge standard (GB8978-1996).Microwave-ferrous sulfate modified activated carbon is adapted to treat high concentration phosphorus in the wastewater.

Study on the Photocatalytic Degradation of Diesel Pollutants in Seawater by a Prepared Nano Ag-Droped Zinc Oxide

2014 ◽  
Vol 609-610 ◽  
pp. 311-316
Author(s):  
Xiao Cai Yu ◽  
Dong Dong Hu ◽  
Jin Fang Chen ◽  
Xiao Jie Jin ◽  
Xu Zheng
Keyword(s):  
Reaction Time ◽  
Photocatalytic Degradation ◽  
Calcination Temperature ◽  
Ph Value ◽  
Uv Light ◽  
Removal Rate ◽  
Orthogonal Experiment ◽  
Influential Factors ◽  
Influential Factor ◽  
Sonochemical Method

ZnO and Ag-droped ZnO photocatalysts with different Ag loadings (0.5, 1.0, 1.5, 2.0at%) and different calcination temperature (300, 400, 500, 600, 700°C) were synthesized by a sonochemical method. The morphology and crystal pattern of some prepared catalysts were characterized by XRD and SEM techniques which demonstrated that the prepared catalysts were of hexagonal wurtzite structure. Ag loadings, calcination temperature and other factors, dosage of photocatalyst, reaction time and pH value of seawater, were also taken into consideration in the procedure of photocatalytic degradation reaction under UV light. An orthogonal experiment was carried out to investigate the best combination of factors which can reach the best diesel pollution removal rate and the influence order of factors. Reaction time and dosage of catalyst were the most influential factors in this experiment, and the factor of calcination temperature was the weakest influential factor. The removal rate of diesel can up to 78% when the experiment was undertaken under the very conditions: the dosage of catalyst 2.0g/L, reaction time 2.0h, Ag loading of catalyst 1.0 at%, calcinations temperature 400°C and pH value 8.5.

Advanced Treatment on Papermaking Wastewater Using Photo-Fenton Modified Fly Ash

2014 ◽  
Vol 535 ◽  
pp. 230-236
Author(s):  
Xiao Feng Jia ◽  
Wen Ning Mai ◽  
Xiao Rui Wang ◽  
Jun Zhou
Keyword(s):  
Fly Ash ◽  
Biological Treatment ◽  
Ph Value ◽  
Advanced Treatment ◽  
Toxic Substances ◽  
Reaction Conditions ◽  
Single Factor Analysis ◽  
Optimal Reaction ◽  
Modified Fly Ash ◽  
Papermaking Wastewater

There are still some recalcitrant and toxic substances contained in the papermaking wastewater after the biological treatment, so it is necessary to conduct advanced treatment. This paper designed the types and modified methods of fly ash, and then utilized the orthogonal test and single factor analysis to determine the influence of various factors and the combination of optimal levels of Photo-Fenton method of modified fly ash. The results show that the acid modified fly ash has great synergistic catalytic effect. The optimal reaction conditions of papermaking wastewater treatment using the method without adjusting the pH value of raw water are shown as follows: the dosage of fly ash is 34g/L, the dosage of H2O2 is 8.2mmol/L, the dosage of FeSO4·7H2O is 8.8mmol/L and the reaction time is controlled in 45min.In this case, the removal efficiency for COD can reach 71.72%.

Study on the Model of Limonite-TiO2 Combined Microspheres Photolysising Phenol in Source Water

2012 ◽  
Vol 518-523 ◽  
pp. 121-124
Author(s):  
Hong Xia Xia ◽  
Qi Hong Zhu
Keyword(s):  
Reaction Time ◽  
Light Intensity ◽  
Ph Value ◽  
Removal Rate ◽  
Source Water ◽  
Quadratic Regression ◽  
Solution Ph ◽  
Experimental Conditions ◽  
Orthogonal Regression ◽  
Single Factor Experiment

This paper investigates the effect of Limonite/TiO2 combined microspheres dosage,solution pH, reaction time,light intensity on the removal rate of phenol in source water.Based on the single factor experiment, the experimental conditions are optimized by quadratic regression orthogonal rotation combination design.The quadratic orthogonal regression model of removal rate of phenol(y) to four factors of Limonite/TiO2 combined microspheres dosage(x1),pH(x2),reaction time (x3)and light intensity (x4) is established as Y=88.64+4.43X1+ 6.69X3+3.75X4-4.79X12-13.20X22-4.21X32-2.69X42+8.06X1X2-6.76X1X3-4.45X1X4.It can conclude from the model that when Limonite/TiO2 combined microspheres dosage is 1.5583g,solution pH value is 4.5095,reaction time is 102.12min,light intensity is 1710.8（x10 lux）,the yield(y) reaches the maximal(95.83%) and consistent with the confirmatory experiment result..

Study on the Photocatalytic Degradation of Diesel Pollutants over a Sol-Gel Prepared TiO2

2012 ◽  
Vol 476-478 ◽  
pp. 1926-1929
Author(s):  
Xiao Cai Yu ◽  
Dong Dong Hu ◽  
Qian Du ◽  
Xv Zheng ◽  
Ji Yao Guo
Keyword(s):  
Reaction Time ◽  
Photocatalytic Degradation ◽  
Room Temperature ◽  
Ph Value ◽  
Removal Rate ◽  
Sol Gel ◽  
Initial Concentration ◽  
Five Factors ◽  
Degradation Reaction ◽  
Diesel Degradation

Nanoscale titanium dioxide (TiO2) has been fabricated through a sound sol-gel method at room temperature with Tetra-n-butyl Titanate as the precursor, and the particles are characterized by XRD and TEM techniques. The results manifest that the as-prepared TiO2 is amorphous with the anatase structure and its size is around 33.2nm. Five factors, including dosage of TiO2, initial concentration of diesel, pH value, photocatalytic degradation reaction time and the presence of H2O2, are considered in the diesel degradation experiments. An orthogonal test is carried out to optimize the photocatalytic degradation of diesel pollutants based on the single-factor experiments. It reveals that when the dosage of TiO2 is 1.0g/L, the initial concentration of diesel is 0.5g/L, pH value is 6, the reaction time is 4h and the H2O2 dosage is 0.09%, the removal rate of diesel pollutants can up to 88%. Besides, the influence of each factor on removing diesel can be arranged in decreasing order: initial concentration of diesel> photocatalytic reaction time> pH value> TiO2 dosage> H2O2 dosage.

scholarly journals Influence of low-temperature reaction time on morphology and phase composition of short calcium phosphate whiskers

2019 ◽  
Vol 13 (1) ◽  
pp. 57-64 ◽  
Author(s):  
Monika Biernat ◽  
Zbigniew Jaegermann ◽  
Paulina Tymowicz-Grzyb ◽  
Gustaw Konopka
Keyword(s):  
Hydrogen Peroxide ◽  
Phase Composition ◽  
Reaction Time ◽  
Calcium Phosphate ◽  
Biphasic Calcium Phosphate ◽  
Calcium Pyrophosphate ◽  
Temperature Reaction ◽  
Test Results ◽  
Lower Temperature ◽  
Hydrothermal Methods

The present work shows the results of the synthesis of multiphasic calcium phosphate whiskers from a mixture of biphasic calcium phosphate (?-tricalcium phosphate (?-TCP) and calcium pyrophosphate (CPP)) in the hydrogen peroxide solution-mediated process carried out in different time ranges. The process was performed at considerably lower temperature than typical hydrothermal methods used for obtaining of whiskers. Test results show that using the above-mentioned procedure triphasic calcium phosphate consisting of hydroxyapatite (HA),(?-TCP) and CPP can be obtained, where the whiskers are formed mainly from hydroxyapatite. It was found that morphology, phase composition and specific surface area of the reaction product can be controlled by changing the reaction time. The obtained triphasic HA/?-TCP/CPP short whiskers may be considered as a promising biocompatible and resorbable reinforcement in composites for bone tissue engineering with a faster resorption rate than that of HA.

Study on the Photocatalytic Degradation of Ammonia Nitrogen in Aquaculture Wastewater by Fe3+-Doped Nano-TiO2 under UV Irradiation

2012 ◽  
Vol 476-478 ◽  
pp. 2001-2004
Author(s):  
Xiao Cai Yu ◽  
Peng Fei Zhu ◽  
Kui Sheng Song ◽  
Dong Dong Hu ◽  
Qian Du
Keyword(s):  
Reaction Time ◽  
Photocatalytic Degradation ◽  
Uv Irradiation ◽  
Volume Fraction ◽  
Ph Value ◽  
Removal Rate ◽  
Ammonia Nitrogen ◽  
Nano Tio2 ◽  
Initial Concentration ◽  
Aquaculture Wastewater

The Fe3+-doped nano-TiO2 catalyst with various amounts of dopant Fe3+ irons was prepared by a sol-gel method. The products were characterized by XRD and SEM. The photocatalytic degradation of ammonia nitrogen in aquaculture wastewater was investigated by using Fe3+-doped nano-TiO2 under UV irradiation. In the experiment, the effect of Fe3+/TiO2 dosage, the ratio of dopant Fe3+, ammonia-N initial concentration, pH value, H2O2 volume concentration, and reaction time, respectively, on the removal of ammonia-N was investigated. The experimental results can be stated as follows: when the ratio of dopant Fe3+ was 0.25% wt, the dosage of Fe3+/TiO2 was 0.7 g/L, the initial concentration of ammonia-N was 10 mg/L, H2O2 volume fraction was 4 %, respectively, if the reaction time may last 4 h, the removal rate of ammonia-N was expected to reach 97.17 %.

Removal of Manganese(II) Ions from Wastewater by H2O2 as Oxidant

2014 ◽  
Vol 884-885 ◽  
pp. 125-128
Author(s):  
Wen Qiang Yang ◽  
Juan An ◽  
Jian Guo Yin ◽  
Xiao Li Yuan ◽  
Wen Tang Xia
Keyword(s):  
Hydrogen Peroxide ◽  
Reaction Time ◽  
Calcium Oxide ◽  
Reaction Temperature ◽  
Removal Rate ◽  
Treated Wastewater ◽  
Manganese Removal

Removal of manganese (II) ions from wastewater by H2O2as oxidant was studied. Effects of reaction temperature, hydrogen peroxide concentration, reaction time and calcium oxide concen-tration on the manganese removal were investigated. The results indicated that the removal rate of manganese exceeded 99.9% and the Mn (II) ions concentration of treated wastewater was lower than 0.1 mg·L-1under the conditions of reaction temperature 55 °C, concentration of H2O20.1 mL·L-1, reaction time 70 min, concentration of CaO 0.25 g·L-1.

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