scholarly journals Специфика статистики упругих и деформационно-прочностных свойств высокопрочных волокон полипропилена

2022 ◽  
Vol 64 (1) ◽  
pp. 85
Author(s):  
Ю.М. Бойко ◽  
В.А. Марихин ◽  
О.А. Москалюк ◽  
Л.П. Мясникова
Keyword(s):  
Polymeric Materials ◽  
High Strength ◽  
Polyamide 6 ◽  
Chain Conformation ◽  
Helical Chain ◽  
Statistical Distributions ◽  
Single Fibers ◽  
Weibull Models ◽  
Chain Conformations ◽  
Ultra High Molecular Weight

Regularities of statistical distributions of a complex of mechanical properties, including the module of elasticity (E), strength () and strain at break (b), high-strength industrial oriented polypropylene (PP) fibers have been analyzed using the Weibull and Gauss models based on large a wide array of measurements (50 identical samples in each series). The values of the statistical Weibull modulus (m) - a parameter characterizing the scatter of the measured values of the data arrays of E,  and b – have been estimated for the PP samples of two types: single fibers (monofilaments) and multifilament fibers consisting from several hundred single fibers. For the PP multifilament fibers, a more correct description of the distributions of E,  and b has been received both in the framework of the normal distribution (Gaussian distribution) and in the framework of the Weibull distribution in comparison with the description of such distributions for the PP monofilaments. The influence of the polymer chain conformation on the regularities of the statistical distributions of E,  and b for the high-strength oriented polymeric materials with different chemical chain structures and the correctness of their descriptions in the framework of the Gauss and Weibull models have been analyzed. For this purpose, the values of m calculated in this work for PP with a helical chain conformation have been compared with the values of m determined by us earlier for ultra-high molecular weight polyethylene and polyamide-6 with the chain conformations in the form of an in-plane trans-zigzag.

scholarly journals Статистический анализ прочности ориентированных волокон полиамида-6

2019 ◽  
Vol 45 (8) ◽  
pp. 37
Author(s):  
Ю.М. Бойко ◽  
В.А. Марихин ◽  
О.А. Москалюк ◽  
Л.П. Мясникова ◽  
Е.С. Цобкалло
Keyword(s):  
Tensile Strength ◽  
Large Data ◽  
High Strength ◽  
Polyamide 6 ◽  
Strength Distribution ◽  
Distribution Characteristic ◽  
Data Array ◽  
Plastic Materials ◽  
Weibull Models ◽  
First Time

AbstractStatistical analysis of distribution of the tensile strength of commercial oriented polyamide-6 (PA-6) fibers has been performed in the framework of the Gaussian and Weibull models using a large data array of the results of measurements for a large number (50) of identical samples. Using the example of PA-6, the dualism of strength distribution in oriented high-strength polymers is demonstrated for the first time, which consists in the validity of both the normal Gaussian distribution (characteristic of viscoelastic and plastic materials) and the Weibull distribution (characteristic of brittle materials).

scholarly journals Особенности статистических распределений прочностей моно- и полифиламентных ультраориентированных высокопрочных волокон сверхвысокомолекулярного полиэтилена

2020 ◽  
Vol 62 (4) ◽  
pp. 590
Author(s):  
Ю.М. Бойко ◽  
В.А. Марихин ◽  
О.А. Москалюк ◽  
Л.П. Мясникова
Keyword(s):  
Molecular Weight ◽  
Tensile Strength ◽  
Distribution Function ◽  
Draw Ratio ◽  
High Strength ◽  
Strength Distribution ◽  
Statistical Distributions ◽  
Gaussian Models ◽  
Uhmwpe Fibers ◽  
Ultra High Molecular Weight

The patterns of the statistical distributions of tensile strength of high-strength ultraoriented mono-and multifilament fibers, consisting of several hundred single fibers of ultra-high-molecular-weight polyethylene (UHMWPE), have been analyzed using the Weibull and Gaussian models by considering a large number of measurements (50 identical samples in each series). It has been shown that the strength distribution of the multifilament UHMWPE fibers can be described both within the normal Gaussian distribution and the standard Weibull distribution function. At the same time, the strength distribution of the UHMWPE monofilaments oriented to a final draw ratio of 120 is not subject to the normal distribution. The reasons for the revealed differences in the types of the statistical strength distributions of the mono- and multifilaments of high-strength UHMWPE during fracture are discussed.

scholarly journals The nanostructuring of ultra-high-molecular-weight polyethylene in thermal and mechanical fields as revealed by DSC

2021 ◽  
Vol 2103 (1) ◽  
pp. 012095
Author(s):  
L P Myasnikova ◽  
A K Borisov ◽  
Yu M Boiko ◽  
A P Borsenko ◽  
V F Drobot’ko ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Melting Temperature ◽  
Mechanical Characteristics ◽  
Thickness Distribution ◽  
High Strength ◽  
High Modulus ◽  
Know How ◽  
First Time ◽  
Ultra High Molecular Weight

Abstract The ultra-high-molecular-weight polyethylene reactor powders are widely used for the actively developing solvent-free method for producing high-strength high-modulus PE filaments, which includes the compaction and sintering of a powder followed by orientational hardening. To find an appropriate regime of the technological process, it is important to know how the nanostructure changes when transforming from a powder to a precursor for hardening. Nanocrystalline lamellae are characteristics of the powder structure. For the first time, the DSC technique was used to follow changes in the thickness distribution of lamellae in ultra-high-molecular-weight polyethylene reactor powder on its way to a precursor for orientation hardening. It was found that the percentage of thick (>15 nm) and thin (10 nm) lamellae in compacted samples and those sintered at temperatures lower than the melting temperature of PE (140°C) remains nearly the same. However, significant changes in the content of lamellae of different thicknesses were observed in the samples sintered at 145°C with subsequent cooling under different conditions. The influence of the lamellae thickness distribution in precursors on the mechanical characteristics of oriented filaments was discussed.

A room-temperature self-healing elastomer with ultra-high strength and toughness fabricated via optimized hierarchical hydrogen-bonding interactions

2022 ◽  
Author(s):  
Liangliang Xia ◽  
Ming Zhou ◽  
Hongjun Tu ◽  
wen Zeng ◽  
xiaoling Yang ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Mechanical Strength ◽  
Room Temperature ◽  
Polymeric Materials ◽  
High Strength ◽  
Self Healing ◽  
High Mechanical Strength ◽  
Hydrogen Bonding Interactions ◽  
Healing Efficiency ◽  
Good Healing

The preparation of room-temperature self-healing polymeric materials with good healing efficiency and high mechanical strength is challenging. Two processes are essential to realise the room-temperature self-healing of materials: (a) a...

Influence of Machining Parameters of the Drilling Polymers UHMW-PE and PTFE

2015 ◽  
Vol 1120-1121 ◽  
pp. 1297-1301 ◽  
Author(s):  
Breno Ferreira Lizardo ◽  
Luciano Machado Gomes Vieira ◽  
Juan Carlos Campos Rubio ◽  
Marcelo Araújo Câmara
Keyword(s):  
Thrust Force ◽  
Polymeric Materials ◽  
Machining Parameters ◽  
New Materials ◽  
Hole Quality ◽  
Tool Geometries ◽  
Dimensional Deviation ◽  
Fiber Metal ◽  
Ultra High Molecular Weight ◽  
Quality Surface

Over the years, with the increasing development of engineering materials, the emergence of new composites, fiber metal laminated, biomaterials, metal alloys etc., and with demand for products less expensive, less polluting and more efficient, the manufacturing engineering also needs to develop to be able to process these new materials. Materials and tool geometries, intelligent mechanisms, modular machines, also follow this setting. To that end, this work comes to raise the main parameters that influence in the hole quality surface of finished product. Were used two polymeric materials, ultra high molecular weight polyethylene (UHMW-PE) and polytetrafluoroethylene (PTFE), two feed rates, three rotations and three tool geometries, allowing to identify which of these parameters have greater influence on the thrust force and the characteristics of the finished product and dimensional deviation.

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