scholarly journals Радиационные константы в спектре иона W VII

2020 ◽  
Vol 128 (8) ◽  
pp. 1074
Author(s):  
А.В. Логинов ◽  
В.И. Никитченко
Keyword(s):  
Transition Probabilities ◽  
Energy Levels ◽  
Radiative Transition ◽  
Coupling Scheme ◽  
Intermediate Coupling ◽  
Hartree Fock ◽  
Experimental Energy ◽  
Intermediate Coupling Scheme

Radiative transition probabilities 4f135p66p + 4f145p56p - 4f136s, 4f137s, and 4f137s levels lifetimes for erbium-like W VII were calculated smiempirically in intermediate coupling scheme using experimental energy levels. Radial transition integrals were derived in length form with Hartree-Fock functions.

scholarly journals Recombination Spectra of Planetary Nebulae

1983 ◽  
Vol 103 ◽  
pp. 514-516
Author(s):  
P.O. Bogdanovich ◽  
Z.B. Rudzikas ◽  
T. H. Feklistova ◽  
A.F. Kholtygin ◽  
A.A. Nikitin ◽  
...  
Keyword(s):  
Transition Probabilities ◽  
Planetary Nebulae ◽  
Dielectronic Recombination ◽  
Wave Functions ◽  
Energy Spectra ◽  
Coupling Scheme ◽  
Intermediate Coupling ◽  
Hartree Fock ◽  
Radiative Transitions ◽  
Intermediate Coupling Scheme

The lines of the transitions between the subordinate levels of the CIII, NIII etc. ions are observed in the spectra of planetary nebulae (PN) (1). Their theoretical intensities may be found by solving the stationarity equations and accounting for both the recombination and cascade radiative transitions. It is possible to calculate the recombination spectra in various approaches: the single- or multi-configuration approximations (SCA and MCA) making use of both the superposition of configurations (SC) or the multiconfigurational Hartree-Fock-Jucys equations (2), taking into consideration the contribution of the dielectronic recombination to the intensities of the recombination lines. The energy spectra, the transition probabilities etc., as a rule ought to be calculated in the intermediate coupling scheme (2). Both analytical or numerical (e.g. Hartree-Fock) wave functions may be adopted.

scholarly journals Allowed and Forbidden n = 2?2 Transitions of the Elements Kr and Mo

1984 ◽  
Vol 37 (6) ◽  
pp. 601
Author(s):  
R Glass
Keyword(s):  
Transition Probabilities ◽  
Relativistic Effects ◽  
Correlation Effect ◽  
Coupling Scheme ◽  
Intermediate Coupling ◽  
Transition Energies ◽  
Hartree Fock ◽  
Physical Assumption ◽  
Variational Process ◽  
Intermediate Coupling Scheme

Relativistic intermediate-coupling wavefunctions are used to evaluate transition energies, line strengths and transition probabilities for all allowed and forbidden n = 2-2 transitions for krypton and molybdenum beryllium-like ions. Our results are in very good agreement with those calculated using the relativistic multi-configuration Hartree-Fock approximation. These calculations were carried out under the same physical assumption that the dominant correlation effect is the n = 2 intra-shell correlation. We also discuss the importance of relativistic effects on the radial functions, the relativistic intermediate-coupling scheme in the variational process, the importance of radiative corrections for transition energies between states with different occupation of the 2s shell, and the relative importance of intra- versus inter-shell correlation effects.

scholarly journals Interpretation of the spectrum of Pb(II). Theoretical transition probabilities and lifetimes

2001 ◽  
Vol 79 (7) ◽  
pp. 999-1009 ◽  
Author(s):  
C Colón ◽  
A Alonso-Medina
Keyword(s):  
Transition Probabilities ◽  
Energy Levels ◽  
Radiative Transition ◽  
Least Square ◽  
Large Contribution ◽  
Hartree Fock ◽  
Forbidden Transition ◽  
Method Of Least Square ◽  
Experimental Values ◽  
Good Agreement

Radiative transition probabilities for 190 lines arising from the ns 2S1/2, np 2P1/2,3/2, nd 2D3/2,5/2, nf 2F5/2,7/2, and 6p2 (4P1/2,3/2,5/2, 2D3/2,5/2, 2P1/2,3/2, and 2S1/2) levels of Pb(II) have been calculated. Lifetimes of the above mentioned levels have been determined from the present transition probabilities. These values were obtained in intermediate coupling (IC) and using ab initio relativistic Hartree-Fock calculations. For the IC calculations, we use the standard method of least-square fitting of experimental energy levels by means of computer codes from Cowan. The results of calculations for radiative transition probabilities and excited states lifetimes are presented and compared with the experimental results present in the literature and with other theoretical values. There is generally good agreement between our values and the experimental data available. Analysis of the interaction shows that the level 4P5/2 of the 6s6p2 configuration presents a large contribution to the 2D5/2 level of the 6s26d configuration. This result explains the good agreement between our result and the experimental values obtained to the observed as the 6s6p2 4P5/2 – 6s 25f2F7/2 dipole-forbidden transition. PACS Nos.: 32.70^*, 32.70Fw, 32.70Cs

scholarly journals Вероятности радиационных переходов в спектрах никелеподобных ионов Cd XXI, In XXII, Sn XXIII

2019 ◽  
Vol 126 (2) ◽  
pp. 118
Author(s):  
А.В. Логинов
Keyword(s):  
Electric Dipole ◽  
Coupling Scheme ◽  
Intermediate Coupling ◽  
Hartree Fock ◽  
Intermediate Coupling Scheme

AbstractProbabilities of electric-dipole 3 d ^94 p → 3 d ^10, 3 d ^94 s transitions in the spectra of nickel-like ions Cd XXI, In XXII, and Sn XXIII are calculated semiempirically in the intermediate coupling scheme. The radial integrals necessary for obtaining absolute values of the probabilities are calculated in the length form with Hartree–Fock functions.

scholarly journals New Transition and Energy Levels of Three-Times Ionized Krypton (Kr IV)

Atoms ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 48
Author(s):  
M. Raineri ◽  
M. Gallardo ◽  
J. Reyna Almandos ◽  
A. G. Trigueiros ◽  
C. J. B. Pagan
Keyword(s):  
Transition Probabilities ◽  
Energy Levels ◽  
Pulsed Discharge ◽  
Core Polarization ◽  
Polarization Effects ◽  
Hartree Fock ◽  
Theta Pinch ◽  
New Energy ◽  
First Time

A capillary pulsed-discharge and a theta-pinch were used to record Kr spectra in the region of 330–4800 Å. A set of 168 transitions of these spectra were classified for the first time. We extended the analysis to twenty-five new energy levels belonging to 3s23p24d, 3s23p25d even configurations. We calculated weighted transition probabilities (gA) for all of the experimentally observed lines and lifetimes for new energy levels using a relativistic Hartree–Fock method, including core-polarization effects.

scholarly journals Extended theoretical transition data in C i–iv

2021 ◽  
Vol 502 (3) ◽  
pp. 3780-3799
Author(s):  
W Li ◽  
A M Amarsi ◽  
A Papoulia ◽  
J Ekman ◽  
P Jönsson
Keyword(s):  
Transition Probabilities ◽  
Energy Levels ◽  
Oscillator Strengths ◽  
Atomic Data ◽  
Internal Validation ◽  
Hartree Fock ◽  
Relativistic Configuration ◽  
The Difference ◽  
The One ◽  
Relative Differences

ABSTRACT Accurate atomic data are essential for opacity calculations and for abundance analyses of the Sun and other stars. The aim of this work is to provide accurate and extensive results of energy levels and transition data for C i–iv. The Multiconfiguration Dirac–Hartree–Fock and relativistic configuration interaction methods were used in this work. To improve the quality of the wavefunctions and reduce the relative differences between length and velocity forms for transition data involving high Rydberg states, alternative computational strategies were employed by imposing restrictions on the electron substitutions when constructing the orbital basis for each atom and ion. Transition data, for example, weighted oscillator strengths and transition probabilities, are given for radiative electric dipole (E1) transitions involving levels up to 1s22s22p6s for C i, up to 1s22s27f for C ii, up to 1s22s7f for C iii, and up to 1s28g for C iv. Using the difference between the transition rates in length and velocity gauges as an internal validation, the average uncertainties of all presented E1 transitions are estimated to be 8.05 per cent, 7.20 per cent, 1.77 per cent, and 0.28 per cent, respectively, for C i–iv. Extensive comparisons with available experimental and theoretical results are performed and good agreement is observed for most of the transitions. In addition, the C i data were employed in a re-analysis of the solar carbon abundance. The new transition data give a line-by-line dispersion similar to the one obtained when using transition data that are typically used in stellar spectroscopic applications today.

An Investigation on the Fine Structure Levels in the Ground State Configuration for the Antimony Anion

2014 ◽  
Vol 69 (8-9) ◽  
pp. 397-402
Author(s):  
Leyla Özdemir ◽  
Sadiye Tuna
Keyword(s):  
Fine Structure ◽  
Ground State ◽  
Transition Probabilities ◽  
Relativistic Effects ◽  
Electric Quadrupole ◽  
Radiative Transition ◽  
Ground State Configuration ◽  
Hartree Fock ◽  
First Time ◽  
State Configuration

We have investigated the correlation, relativistic, and isotope shift effects on the fine structure levels in the ground state configuration for the antimony anion ( Sb-). Energies and radiative transition probabilities (for magnetic dipole, M1, and electric quadrupole, E2) have been obtained using the multiconfiguration Hartree-Fock method within the framework of the Breit-Pauli Hamiltonian. Therefore, the most important configuration interaction and relativistic effects have been included. Comparisons with other available works are presented. For some M1 and E2 lines the considered transition probabilities are reported for the first time

scholarly journals Population of Excited States of Al10+ in a Plasma by a Time-Dependent Model

1984 ◽  
Vol 86 ◽  
pp. 221-224
Author(s):  
H. Guennou ◽  
A. Sureau
Keyword(s):  
Population Distribution ◽  
Transition Probabilities ◽  
Ground Level ◽  
Radiative Transition ◽  
Time Dependent ◽  
Hartree Fock ◽  
Ion Collisions ◽  
Finite Set ◽  
Dependent Model ◽  
Time Dependent Model

The present model is the time-dependent version of a previous model (Sureau et al. 1983) in which the population distribution was assumed in steady state. A finite set of levels is partitioned in four subsets: the Z-ion ground-level and, contingently, the first near-degenerated levels (subset 1); all the successive excited Z-ion levels up to n=5 (subset 2); a finite number of higher Rydberg levels (because of the limitation of the series in the plasmas) which are assumed in LTE with the Z+l−ion ground-level (subset 3, called the thermal band); and the Z+l ion ground-level (subset 4).The physical processes explicitly considered are the radiative cascades and the transitions between the Z-ion bound levels induced by electron-ion collisions. The radiative-transition probabilities are given by ab-initio calculations using a modified Hartree-Fock method including the spin-orbit interaction (Sureau et al., 1984). The collision rates are derived by the Van Regemorter formula multiplied by an adjustable parameter Fc.

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