Three Phase Biofilter Model for the Removal of Styrene through the Microbial Route

Author(s):  
Chhaya Das ◽  
Ranjana Chowdhury ◽  
Pinaki Bhattacharya

A biofilter of 0.05m diameter and 0.58m height has been studied for the removal of styrene from a simulated air-styrene mixture through the microbial route using Pseudomonas putida. Coconut coir and other waste materials have been used as the immobilization matrix for the microorganisms. Gas flow rate (0.005-0.01kgm-2s-1), micronutrient liquid flow rate (5-10 kgm-2s-1), inlet styrene concentration (0.05-1.20 gm-3) and packing size (de = 0.08 - 0.18cm) have been used as parameters. The kinetic parameters of growth rate equation of bacterial strain have been determined using batch type experimental data. A Monod type reaction model has been observed to be appropriate for the explanation of growth kinetics of the microorganisms. The values of the kinetic parameters used are Ks = 0.8gm-3, µmax = 45h-1. A three-phase deterministic mathematical model has been developed incorporating the synergistic effect of simultaneous reaction and interphase (gas to liquid to biofilm) mass transfer of styrene using experimentally determined kinetic parameters and mass transfer coefficients calculated using standard correlations. Simulated results based on the model have been compared with the experimental ones satisfactorily.

Catalysts ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 490 ◽  
Author(s):  
Rina Mariyana ◽  
Min-Sik Kim ◽  
Chae Lim ◽  
Tae Kim ◽  
Si Park ◽  
...  

The mass transfer performance of a string film reactor (SFR)—a bioreactor design for the aerobic bioconversion of methane—was investigated. The results showed that the SFR could achieve high mass transfer performance of gases, and the highest values of the mass transfer coefficients for oxygen and methane were 877.1 h−1 and 408.0 h−1, respectively. There were similar mass transfer coefficients for oxygen and methane in absorption experiments using air, methane, and air–methane mixed gas under the same liquid flow rate conditions, implying that each gas is delivered into the liquid without mutual interaction. The mass transfer performance of the SFR was significantly influenced by the liquid flow rate and the hydrophilicity of the string material, whereas the magnitude of the gas flow rate effect on the mass transfer performance depended on both the tested liquid flow rate and the gas flow rate. Furthermore, the mass transfer performance of the SFR was compared with those of other types of bioreactors.


2003 ◽  
Vol 57 (7-8) ◽  
pp. 326-329 ◽  
Author(s):  
Srdjan Pejanovic

The hydrodynamic properties of a three phase fluidized bed with low density inert spherical packing, fluidized by the interaction of a gas flowing upwards and a liquid flowing downwards through the column, were investigated. It was found that the pressure drop, liquid hold up and dynamic bed height increase with both increasing liquid and gas flow rate. While the dynamic bed height and minimum fluidization velocity remain unchanged, both the pressure drop and liquid hold up increase with increasing density of the packing. Therefore, an increase in packing density causes more intensive mass transfer between the fluid phases than packed columns. It was shown that increase of the liquid flow rate causes an increase of both the effective liquid and gas velocity through the fluidized bed, which may also improve mass transfer.


2003 ◽  
Vol 57 (7-8) ◽  
pp. 330-334
Author(s):  
Srdjan Pejanovic ◽  
Radmila Garic-Grulovic ◽  
Predrag Bozalo

The absorption of carbon dioxide in aqueous diethanolamine solutions was carried out in a three-phase fluidized bed with inert spherical packing. The rate of absorption was calculated on the basis of measuring the concentration change in the liquid phase on-line by a conductivity probe. It was shown that the Danckwerts plot method might be successfully used to simultaneously determine the effective interfacial area and both the gas and liquid-side mass transfer coefficients. While the gas-side mass transfer coefficient is independent of the liquid flow rate, the effective interfacial area and liquid-side mass transfer coefficient increase with increasing liquid flow rate.


2014 ◽  
Vol 908 ◽  
pp. 277-281
Author(s):  
Fei Wu ◽  
Jie Wu ◽  
Mei Jin ◽  
Fang Wang ◽  
Ping Lu

Based on acetone-H2O system, the influence of the gas-liquid distribution inducer on the mass transfer coefficient in the rotating packed bed with the stainless steel packing was investigated. Furthermore, the absorption performance was also obtained under the experimental condition of the rotational speed of 630 rpm, the gas flow rate of 2 m3/h and the liquid flow rate of 100 L/h in the rotating packed bed with different types and different installation ways of the distribution inducer. The experimental results showed that the volumetric mass transfer coefficient Kyα per unit contact length of gas-liquid was increased by 8.6% for the forward-curved fixed blade, by 19.8% for the backward-curved rotor blade and by 33.2% with the combination of the straight radial rotor blade and the backward-curved fixed blade, respectively. Furthermore, when the gas flow rate was 2.5 m3/h, Kyα per unit contact length of gas-liquid was increased by 2.9% for the forward-curved fixed blade, by 25.3% for the backward-curved rotor blade, by 42.7% for the combination of the straight radial rotor blade and the backward-curved fixed blade, respectively. The results indicated that the distribution inducer play an important role on the improvement of the mass transfer coefficient in acetone-H2O system.


2015 ◽  
Vol 6 (8(78)) ◽  
pp. 50
Author(s):  
Артур Юрьевич Рачинский ◽  
Михаил Константинович Безродный ◽  
Николай Никифорович Голияд ◽  
Петр Алексеевич Барабаш

Konversi ◽  
2019 ◽  
Vol 7 (1) ◽  
pp. 6
Author(s):  
Erlinda Ningsih ◽  
Abas Sato ◽  
Mochammad Alfan Nafiuddin ◽  
Wisnu Setyo Putranto

Abstract- One of the most widely used processes for CO2 gas removal is Absorption. Carbon dioxide is the result of the fuel combustion process which of the hazardous gases. The aim of this research is to determine the total mass transfer coefficient and analyze the effect of the absorbent flow rate of the absorbent solution with the promoter and the gas flow rate to the total mass transfer coefficient value. The variables consisted of liquid flow rate: 1, 2, 3, 4, 5 liter/min, gas flow rate: 15, 25, 30, 40, 50 liter/min and MSG concentration: 0%, 1%, 3% and 5% by weight. The solution of Pottasium Carbonate as absorbent with MSG promoter is flowed through top column and CO2 gas flowed from bottom packed column. Liquids were analyzed by titration and the gas output was analyzed by GC. From this research, it is found that the flow rate of gas and the liquid flow rate is directly proportional to the value of KGa. The liquid flow rate variable 5 liters / minute, gas flow rate 15 l / min obtained value of KGa 11,1102 at concentration of MSG 5%. Keywords:  Absorption, CO2,  K2CO3, MSG. 


2021 ◽  
Author(s):  
Yongjia Zhu

The spatial variations of liquid distribution and local mass transfer coefficient in a 0.30-m column of 25.4-m Pall rings were investigated. The data of liquid distribution was collected with a 39-cell liquid collector and a wall-flow tube from a doubled-wall section in the column at the packing-support level. The local mass transfer coefficients were measured via the electrochemical technique by individual cathodic nickel-coated Pall rings placed at various spatial positions. Both measurements were conducted at various fluid flow rates with three liquid distributor designs at different bed heights. Liquid distribution and local mass transfer coefficients observed were far from uniform in the column. The wall flow developed along the packed bed until a fully developed flow pattern was reached. With more uniform initial liquid distribution, the less packing height needed to reach the fully developed flow pattern along with higher the mass transfer efficiency in the column. Ladder-type liquid distributor (LLD) showed less angular effect in measurements. Increasing the liquid flow rate slightly improved the uniformity of liquid distribution and enhanced the mass transfer. No influence of gas flow rate on liquid distribution and mass transfer coefficient was found at the range of gas flow rates used. These gas flow rates were much lower than the loading point. Liquid maldistribution factor and mass transfer maldistribution factor decreased with increases in the uniformity of the initial liquid distribution. These values were 0.21(0.48). 0.16(0.26) and 0.14(0.22) for single-point liquid distributor (SPLD), cross-type liquid distributor (CLD) and LLD, respectively. By comparison, a good agreement was observed on the relation of liquid maldistribution factor and mass transfer maldistribution factor.


2021 ◽  
Author(s):  
Yongjia Zhu

The spatial variations of liquid distribution and local mass transfer coefficient in a 0.30-m column of 25.4-m Pall rings were investigated. The data of liquid distribution was collected with a 39-cell liquid collector and a wall-flow tube from a doubled-wall section in the column at the packing-support level. The local mass transfer coefficients were measured via the electrochemical technique by individual cathodic nickel-coated Pall rings placed at various spatial positions. Both measurements were conducted at various fluid flow rates with three liquid distributor designs at different bed heights. Liquid distribution and local mass transfer coefficients observed were far from uniform in the column. The wall flow developed along the packed bed until a fully developed flow pattern was reached. With more uniform initial liquid distribution, the less packing height needed to reach the fully developed flow pattern along with higher the mass transfer efficiency in the column. Ladder-type liquid distributor (LLD) showed less angular effect in measurements. Increasing the liquid flow rate slightly improved the uniformity of liquid distribution and enhanced the mass transfer. No influence of gas flow rate on liquid distribution and mass transfer coefficient was found at the range of gas flow rates used. These gas flow rates were much lower than the loading point. Liquid maldistribution factor and mass transfer maldistribution factor decreased with increases in the uniformity of the initial liquid distribution. These values were 0.21(0.48). 0.16(0.26) and 0.14(0.22) for single-point liquid distributor (SPLD), cross-type liquid distributor (CLD) and LLD, respectively. By comparison, a good agreement was observed on the relation of liquid maldistribution factor and mass transfer maldistribution factor.


Vestnik MEI ◽  
2021 ◽  
pp. 37-43
Author(s):  
Vasiliy Ya. Gubarev ◽  
◽  
Aleksey G. Arzamastsev ◽  
Aleksey I. Sharapov ◽  
Yuliya O. Moreva ◽  
...  

In the channels of mechanical-draft cooling tower sprinklers, a saturated air flow section may appear under certain initial conditions, the mass transfer intensity in which is limited by the steam content in the saturated air. For correctly calculating the heat and mass transfer processes in the cooling tower channel, it is necessary to have a method for determining the unsaturated air flow section length. Publications devoted to studying water cooling processes in the channels of mechanical-draft cooling tower sprinklers do not contain an assessment of the unsaturated air flow section length. A method for determining the unsaturated humid air flow section length in the mechanical-draft cooling tower sprinkler channels is proposed, which is based on the well-known criterion equations for calculating the heat transfer and mass transfer coefficients. The effect the initial air parameters have on the unsaturated air section length is studied, and graphic dependences of the unsaturated air section length are drawn up for each of the analyzed parameters. It is shown that the unsaturated humid air flow section length increases with increasing the initial air temperature. It is also found that the unsaturated air flow section length decreases with a growth in the relative air humidity. An increase in the air flow rate with a constant water flow rate leads to an increase in the unsaturated air flow section length. For the considered sprinkler channel, the saturated air region exists at an air temperature of 15°C and below, and for air temperatures above 25°C there is no saturated air flow section. It is shown that the conclusions drawn about the effect the initial air parameters have on the relative change in the unsaturated air flow section length are valid for channels of various shapes and geometric sizes. The proposed methodology and the results obtained can be used in designing mechanical-draft cooling towers and estimating their efficiency.


2021 ◽  
pp. 1-14
Author(s):  
T. G. Ahmed ◽  
P. A. Russell ◽  
N. Makwashi ◽  
F. Hamad ◽  
S. Gooneratne

Summary In the first part of this work, the development of a capital cost optimization model for sizing three-phase separators was described. The developed model uses generalized reduced gradient nonlinear algorithms to determine the minimum cost associated with the construction of horizontal separators subject to four sets of constraints. In the second part, an experimental test rig was designed and used to investigate the effect of gas flow rate, liquid flow rate, and slenderness ratio (L/D) on the separation performance of horizontal three-phase separators. The results indicated an inverse relationship between an increase in gas and liquid flow rate and the separator outlet quality. It also indicated a direct relationship between an increase in slenderness ratio and separator outlet quality. The results also showed that the gradient change of the percentage of water in the oil outlet with respect to slenderness ratio decreased to ratios of 6:1. Hence, the separation rate increased. At ratios greater than 6:1, the separation still increases, but the gradient change in separation drops off, implying that the benefit in terms of separation is diminishing beyond this point. Therefore, the optimal slenderness ratio for technical reasons is 6:1.


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