scholarly journals Uncertainty of Optimal Rain Gauge Coastal Region: Case Study Makassar

2020 ◽  
Vol 1000 (1000) ◽  
Author(s):  
Giarno Arno ◽  
Muflihah Muflihah ◽  
Mujahidin Mujahidin
Keyword(s):  
Standard Deviation ◽  
Relative Standard Deviation ◽  
Water Resource Management ◽  
Coastal Region ◽  
Rain Gauge ◽  
Rainfall Data ◽  
Annual Rainfall ◽  
Error Level ◽  
Rain Gauges ◽  
Relative Standard

The quality of rainfall data is very important in disaster or hazard analysis and water resource management. However, the accuracy and density of rainfall gauges are increasing, especially if related to the increasing amount of rainfall due to extreme events, such as floods that occurred in Makassar City in 2019. The purpose of this study is to analyze the scenario of optimal rainfall measurement measures in Makassar City. Determination number of the optimal rainfall equipment acquired by calculation of the coefficient of variation or relative standard deviation and error level based on the latest rainfall data in several locations in Makassar City. The results showed that the change of the number of optimal rain gauges varies with the level of error schemes. If the rainfall measurement wants to be improved, the number of rain gauges must be added. Moreover, increasing rainfall accumulation requires an additional rain gauge. By comparing the monthly rainfall data obtained from the rain station in Makassar, it takes 10 rain stations so that the error level is 5%. Nevertheless, using a longer rainfall duration causes the number of the optimal rain gauge to increase. The optimal rain gauge for annual rainfall data at an error level of 5% is 55 units, while if the error level is increased to 10% then 14 units and 6 units for error levels of 15%. Based on the calculation of the relative standard deviation (RSD) from 5 locations that measuring rainfall in Makassar, the biggest city in west coast Sulawesi Island obtained the level of error level is 10%. The scenario with combined among the five existing rain gauges showed that needs to be added to the rainfall gauge between Panaikang or Biring Romang and Sudiang. It is also important to add equipment on-site between Paotere and Barombong.

An Automated Procedure for the Determination of Ammonia in Tobacco

1972 ◽  
Vol 6 (4) ◽  
Author(s):  
P.F. Collins ◽  
W.W. Lawrence ◽  
J.F. Williams
Keyword(s):  
Standard Deviation ◽  
Relative Standard Deviation ◽  
Distillation Method ◽  
Relative Standard ◽  
Tobacco Sample ◽  
Automated Determination

AbstractA procedure for the automated determination of ammonia in tobacco has been developed. Ammonia is extracted from the ground tobacco sample with water and is determined with a Technicon Auto Analyser system which employs separation of the ammonia through volatilization followed by colourimetry using the phenate-hypochlorite reaction. The procedure has been applied to a variety of tobaccos containing from 0.02 to 0.5 % ammonia with an overall relative standard deviation of 2 %. The accuracy of the procedure as judged by recovery tests and by comparison to a manual distillation method is considered adequate

How Certain Are the Reported Ionic Conductivities of Thiophosphate-Based Solid Electrolytes? an Interlaboratory Study

2020 ◽  
Author(s):  
Saneyuki Ohno ◽  
Tim Bernges ◽  
Johannes Buchheim ◽  
Marc Duchardt ◽  
Anna-Katharina Hatz ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Ionic Conductivity ◽  
Relative Standard Deviation ◽  
Solid Electrolytes ◽  
Ionic Conductivities ◽  
Ionic Conductors ◽  
Energy Storage Devices ◽  
Activation Barriers ◽  
Storage Devices ◽  
Relative Standard

<p>Owing to highly conductive solid ionic conductors, all-solid-state batteries attract significant attention as promising next-generation energy storage devices. A lot of research is invested in the search and optimization of solid electrolytes with higher ionic conductivity. However, a systematic study of an <i>interlaboratory reproducibility</i> of measured ionic conductivities and activation energies is missing, making the comparison of absolute values in literature challenging. In this study, we perform an uncertainty evaluation via a Round Robin approach using different Li-argyrodites exhibiting orders of magnitude different ionic conductivities as reference materials. Identical samples are distributed to different research laboratories and the conductivities and activation barriers are measured by impedance spectroscopy. The results show large ranges of up to 4.5 mScm<sup>-1</sup> in the measured total ionic conductivity (1.3 – 5.8 mScm<sup>-1</sup> for the highest conducting sample, relative standard deviation 35 – 50% across all samples) and up to 128 meV for the activation barriers (198 – 326 meV, relative standard deviation 5 – 15%, across all samples), presenting the necessity of a more rigorous methodology including further collaborations within the community and multiplicate measurements.</p>

scholarly journals Indirect and Direct Determination of the Casein Content of Milk by Kjeldahl Nitrogen Analysis: Collaborative Study

1998 ◽  
Vol 81 (4) ◽  
pp. 763-774 ◽  
Author(s):  
Joanna M Lynch ◽  
David M Barbano ◽  
J Richard Fleming
Keyword(s):  
Standard Deviation ◽  
Nitrogen Content ◽  
Relative Standard Deviation ◽  
Collaborative Study ◽  
Direct Determination ◽  
Raw Milk ◽  
Method Performance ◽  
Relative Standard ◽  
Milk Casein

Abstract The classic method for determination of milk casein is based on precipitation of casein at pH 4.6. Precipitated milk casein is removed by filtration and the nitrogen content of either the precipitate (direct casein method) or filtrate (noncasein nitrogen; NCN) is determined by Kjeldahl analysis. For the indirect casein method, milk total nitrogen (TN; Method 991.20) is also determined and casein is calculated as TN minus NCN. Ten laboratories tested 9 pairs of blind duplicate raw milk materials with a casein range of 2.42- 3.05℅ by both the direct and indirect casein methods. Statistical performance expressed in protein equivalents (nitrogen ⨯ 6.38) with invalid and outlier data removed was as follows: NCN method (wt%), mean = 0.762, sr = 0.010, SR = 0.016, repeatability relative standard deviation (RSDr) = 1.287℅, reproducibility relative standard deviation (RSDR) = 2.146%; indirect casein method (wt℅), mean = 2.585, repeatability = 0.015, reproducibility = 0.022, RSDr = 0.560℅, RSDR = 0.841; direct casein method (wt℅), mean = 2.575, sr = 0.015, sR = 0.025, RSDr = 0.597℅, RSDR = 0.988℅. Method performance was acceptable and comparable to similar Kjeldahl methods for determining nitrogen content of milk (Methods 991.20, 991.21,991.22, 991.23). The direct casein, indirect casein, and noncasein nitrogen methods have been adopted by AOAC INTERNATIONAL.

scholarly journals A computer-controlled potentiometric/spectrophotometric titrator

1988 ◽  
Vol 10 (2) ◽  
pp. 95-100
Author(s):  
John D. Stong
Keyword(s):  
Standard Deviation ◽  
Relative Standard Deviation ◽  
Bromophenol Blue ◽  
System Control ◽  
Data Format ◽  
Relative Standard ◽  
Spectrophotometric Titrations ◽  
Computer Controlled ◽  
Major Attention ◽  
Diode Array Spectrophotometer

A laboratory computer controlled potentiometric titrator interfaced to a diode array spectrophotometer is described. The titrator consists of widely used, commercially available components; therefore, major attention is given to modes of interconnection and software implementation in data format and system control. Replicate potentiometric titrations of glycines gave a relative standard deviation in titre of 1.035% and a relative standard deviation in pH of 0.745%. Replicate spectrophotometric titrations of bromophenol blue were analysed at three wavelengths to yield pKa= 3.898 ± 0.075 (1.9% rsd).Methods of data presentation and manipulation are presented.

scholarly journals Performance of TRMM TMPA 3B42 V7 in Replicating Daily Rainfall and Regional Rainfall Regimes in the Amazon Basin (1998–2013)

2018 ◽  
Vol 10 (12) ◽  
pp. 1879 ◽  
Author(s):  
Véronique Michot ◽  
Daniel Vila ◽  
Damien Arvor ◽  
Thomas Corpetti ◽  
Josyane Ronchail ◽  
...  
Keyword(s):  
Amazon Basin ◽  
Daily Rainfall ◽  
Rain Gauge ◽  
Rainfall Data ◽  
Annual Rainfall ◽  
Spatial Coverage ◽  
Rainfall Regimes ◽  
Trmm 3B42 ◽  
Good Agreement

Knowledge and studies on precipitation in the Amazon Basin (AB) are determinant for environmental aspects such as hydrology, ecology, as well as for social aspects like agriculture, food security, or health issues. Availability of rainfall data at high spatio-temporal resolution is thus crucial for these purposes. Remote sensing techniques provide extensive spatial coverage compared to ground-based rainfall data but it is imperative to assess the quality of the estimates. Previous studies underline at regional scale in the AB, and for some years, the efficiency of the Tropical Rainfall Measurement Mission (TRMM) 3B42 Version 7 (V7) (hereafter 3B42) daily product data, to provide a good view of the rainfall time variability which is important to understand the impacts of El Nino Southern Oscilation. Then our study aims to enhance the knowledge about the quality of this product on the entire AB and provide a useful understanding about his capacity to reproduce the annual rainfall regimes. For that purpose we compared 3B42 against 205 quality-controlled rain gauge measurements for the period from March 1998 to July 2013, with the aim to know whether 3B42 is reliable for climate studies. Analysis of quantitative (Bias, Relative RMSE) and categorical statistics (POD, FAR) for the whole period show a more accurate spatial distribution of mean daily rainfall estimations in the lowlands than in the Andean regions. In the latter, the location of a rain gauge and its exposure seem to be more relevant to explain mismatches with 3B42 rather than its elevation. In general, a good agreement is observed between rain gauge derived regimes and those from 3B42; however, performance is better in the rainy period. Finally, an original way to validate the estimations is by taking into account the interannual variability of rainfall regimes (i.e., the presence of sub-regimes): four sub-regimes in the northeast AB defined from rain gauges and 3B42 were found to be in good agreement. Furthermore, this work examined whether TRMM 3B42 V7 rainfall estimates for all the grid points in the AB, outgoing longwave radiation (OLR) and water vapor flux patterns are consistent in the northeast of AB.

Determination of Nitrate in Water by HPLC

2013 ◽  
Vol 448-453 ◽  
pp. 406-408
Author(s):  
Jing Liu ◽  
Xiao Na Ji ◽  
Qing Kai Ren ◽  
Sheng Shu Ai ◽  
Li Jun Wan ◽  
...  
Keyword(s):  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
Standard Deviation ◽  
Relative Standard Deviation ◽  
Recovery Rate ◽  
High Performance ◽  
Separation Efficiency ◽  
Fast Analysis ◽  
Relative Standard

We established a method fordetermination of nitrate in water by High Performance Liquid Chromatography(HPLC). The sample was analysed by HPLC-ADA and was quantitated by externalstandard method after being simply processed. This methd has the advantages ofhigh separation efficiency and fast analysis. The experiment result showed thatthe linearly dependent coefficient was0.994, the recovery rate was between 98.7%～105.7%,the relative standard deviation（RSD）wasless than 2.1 %, and the lowest detectable limit is 0.01ng (S/N=1.6).

scholarly journals Determination of 1,3-Dichloropropanol in Soy Sauce and Related Products by Headspace Gas Chromatography with Mass Spectrometric Detection: Interlaboratory Study

2005 ◽  
Vol 88 (5) ◽  
pp. 1404-1412 ◽  
Author(s):  
Sarah Hasnip ◽  
Colin Crews ◽  
Nicholas Potter ◽  
Paul Brereton ◽  
Henri Diserens ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Standard Deviation ◽  
Relative Standard Deviation ◽  
Internal Standard ◽  
Mass Spectrometric ◽  
Soy Sauce ◽  
Headspace Gas Chromatography ◽  
Relative Standard ◽  
Headspace Gas

Abstract An interlaboratory study was performed to evaluate the effectiveness of a headspace gas chromatography (GC) method for the determination of 1,3-dichloro-propan-2-ol (1,3-DCP) in soy sauce and related products at levels above 5 ng/g. The test portion is mixed with an internal standard (d5-1,3-DCP) and ammonium sulfate in a sealed headspace vial. After achieving equilibrium, the headspace is sampled either by gas-tight syringe or solid-phase microextraction (SPME) and analyzed by GC with mass spectrometric detection. 1,3-DCP is detected in the selected-ion mode (monitoring m/z 79 and 81 for 1,3-DCP and m/z 82 for the deuterated internal standard) and quantified by measurement against standards. Test materials comprising soy, dark soy, mushroom soy, and teriyaki sauces, both spiked and naturally contaminated, were sent to 9 laboratories in Europe, Japan, and the United States; of these, 5 used SPME and 4 used syringe headspace analysis. Test portions were spiked at 5.0, 10.0, 20.0, 100.0, and 500.0 ng/g. The average recovery for spiked blank samples was 108% (ranging from 96–130%). Based on results for spiked samples (blind pairs at 5, 10, 20, 100, and 500 ng/g) as well as a naturally contaminated sample (split-level pair at 27 and 29 ng/g), the relative standard deviation for repeatability (RSDr) ranged from 2.9–23.2%. The relative standard deviation for reproducibility (RSDR) ranged from 20.9–35.3%, and HorRat values of between 1.0 and 1.6 were obtained.

scholarly journals A Novel Process for Manufacturing High-Friction Rings with a Closely Defined Coefficient of Static Friction (Relative Standard Deviation 3.5%) for Application in Ship Engine Components

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 448
Author(s):  
Wojciech S. Gora ◽  
Jesper V. Carstensen ◽  
Krystian L. Wlodarczyk ◽  
Mads B. Laursen ◽  
Erica B. Hansen ◽  
...  
Keyword(s):  
Standard Deviation ◽  
Friction Coefficient ◽  
Relative Standard Deviation ◽  
Static Friction ◽  
Laser Surface ◽  
Laser Surface Texturing ◽  
Textured Surface ◽  
Fibre Lasers ◽  
Static Friction Coefficient ◽  
Relative Standard

In recent years, there has been an increased uptake for surface functionalization through the means of laser surface processing. The constant evolution of low-cost, easily automatable, and highly repeatable nanosecond fibre lasers has significantly aided this. In this paper, we present a laser surface-texturing technique to manufacture a surface with a tailored high static friction coefficient for application within driveshafts of large marine engines. The requirement in this application is not only a high friction coefficient, but a friction coefficient kept within a narrow range. This is obtained by using nanosecond-pulsed fibre lasers to generate a hexagonal pattern of craters on the surface. To provide a suitable friction coefficient, after laser processing the surface was hardened using a chromium-based hardening process, so that the textured surface would embed into its counterpart when the normal force was applied in the engine application. Using the combination of the laser texturing and surface hardening, it is possible to tailor the surface properties to achieve a static friction coefficient of ≥0.7 with ~3–4% relative standard deviation. The laser-textured and hardened parts were installed in driveshafts for ship testing. After successfully performing in 1500 h of operation, it is planned to adopt the solution into production.

Sign in / Sign up

Export Citation Format

Share Document