scholarly journals Geoquímica de lantánidos de los yacimientos de fluorita de los distritos mineros de Taxco y Zacualpan, sur de México: implicaciones sobre el origen y la evolución de los fluidos

2017 ◽  
Vol 34 (3) ◽  
pp. 199 ◽  
Author(s):  
Teresa Pi ◽  
Jesús Solé ◽  
Ofelia Morton-Bermea ◽  
Yuri Taran ◽  
Elizabeth Hernández-Álvarez
Keyword(s):  
Inductively Coupled Plasma ◽  
Early Stage ◽  
Volcanic Rocks ◽  
Wall Rock ◽  
Mining District ◽  
Strontium Content ◽  
Inductively Coupled ◽  
Eu Anomaly ◽  
Plasma Mass Spectrometry ◽  
Ree Patterns

We present and evaluate lanthanide contents measured by inductively coupled plasma mass spectrometry (ICP-MS) in fluorite samples from the fluorite deposits in Zacualpan and Taxco mining districts in the south of Mexico. The information is used to distinguish different generations of fluorite, to establish a correlation between mineralization episodes and the wall rock nature, and to identify postdepositional processes.The total lanthanide content of the fluorites are variable, and early- stage fluorite samples are usually enriched in LREE. The concentration of REE in fluorite is low in comparison with the volcanic and metamorphic rocks (∑REE > 100 ppm) and is generally high respect the carbonates (∑REE < 30 ppm). There is host rock influence. The higher REE concentra- tions are in fluorites hosted by volcanic rocks. The fluorite that replaced carbonate is characterized by low REE to very low concentrations. Fluorite samples associated with sulfurs are typically enriched in HREE. Nearly all fluorites show a negative Eu anomaly similar to the REE anomaly observed in the volcanic rock. Only some early stage dark, uranium rich fluorites, from la Azul deposit, have a strong positive Eu anomaly. Direct correlation between color and REE patterns is observed in some samples.In the Zacualpan mining district, only an episode of mineralization has been discriminated, where fluorite presents flat to HREE- enriched chondrite-normalized REE patterns.In the Taxco mining district and particularly in the “Mina la Azul”, multiple hydrothermal events of mineralization have been determined. The first generation of fluorite is formed by replacement of carbonates and is characterized by very low contents of lanthanides, chondrite- normalized REE patterns similar to the limestone, high strontium content and primary textures (e.g. massive fluorite and rhythmites). The second generation of fluorite is related to the entry of new fluid to the system and has higher REE concentrations, chondrite-normalized REE patterns similar to volcanic rocks, low strontium content and secondary textures (i.e. breccias, nodules). Most of the samples show a genetic relationship between fluorite and fluids of magmatic origin.

scholarly journals The Vesuvianite Gems of the Val d’Ala (Piedmont, Italy)

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 535
Author(s):  
Franca Piera Caucia ◽  
Luigi Marinoni ◽  
Maurizio Scacchetti ◽  
Maria Pia Riccardi ◽  
Omar Bartoli
Keyword(s):  
Inductively Coupled Plasma ◽  
Major Elements ◽  
Western Alps ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Gran Paradiso ◽  
Dark Green ◽  
Ree Patterns

In Val d’Ala (Western Alps in Piedmont, Italy), the most interesting rocks for mineralogical research are represented by rodingite (rich in mineralized veins and fractures) associated with serpentinite in the eclogitized oceanic crust of Piedmont Zone, south of Gran Paradiso Massif. Among the vein-filling minerals, vesuvianite is well appreciated for its potential as gem-quality materials, even though it has never been characterized in detail. This study provides a gemological characterization of eleven vesuvianite crystals from different localities of the Val d’Ala. The refractive index (1.717–1.708) and density (1.705–1.709) values of our vesuvianite are in the range of those in the literature. Scanning electron microscopy with energy-dispersive spectroscopy (SEM/EDS) and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) established that the samples are pretty compositionally homogeneous in terms of major elements, while trace and rare earth elements (REE) contents are more variable. All REE patterns are characterized by pronounced positive Eu anomalies. The variations in color (from olive green to dark green with chocolate (reddish-brown color shades and polychrome bands) are due to the relevant presence of Fe and, to a lesser extent, Ti and Cr. The X-ray powder diffraction (XRPD) analyses and SEM/EDS quantitative study indicate that the other phases associated with vesuvianite are represented by diopside, garnet, clinochlore.

Distribution of gallium between phenocrysts and melt in peralkaline salic volcanic rocks, Kenya Rift Valley

2010 ◽  
Vol 74 (2) ◽  
pp. 351-363 ◽  
Author(s):  
R. Macdonald ◽  
N. W. Rogers ◽  
B. Bagiński ◽  
P. Dzierżanowski
Keyword(s):  
Rift Valley ◽  
Inductively Coupled Plasma ◽  
Magma Mixing ◽  
Volcanic Rocks ◽  
Alkali Feldspar ◽  
Volcanic Complex ◽  
Kenya Rift ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Kenya Rift Valley

AbstractGallium abundances, determined by laser ablation-inductively coupled plasma-mass spectrometry, are presented for phenocrysts and glassy matrices from a metaluminous trachyte and five peralkaline rhyolites from the Greater Olkaria Volcanic Complex, Kenya Rift Valley. Abundances in the glasses range from 28.9 to 33.3 ppm, comparable with peralkaline rhyolites elsewhere. Phenocryst Ga abundances (in ppm) are: sanidine 31.5–45.3; fayalite 0.02–0.22; hedenbergite 3.3–6.3; amphibole 12; biotite 72; ilmenite 0.56–0.72; titanomagnetite 32; chevkinite-(Ce) 364. The mafic phases and chevkinite-(Ce) are enriched in Ga relative to Al, whereas Ga/Al ratios in sanidine are smaller than in coexisting glass. Apparent partition coefficients range from <0.01 in fayalite to 12 in chevkinite-(Ce). Coefficients for hedenbergite, ilmenite and titanomagnetite decrease as melts become peralkaline. The sharp increase in Ga/Al in the more fractionated members of alkaline magmatic suites probably results from alkali feldspar-dominated fractionation. Case studies are presented to show that the Ga/Al ratio may be a sensitive indicator of such petrogenetic processes as magma mixing, interaction of melts with F-rich volatile phases, mineral accumulation and volatile-induced crustal anatexis.

scholarly journals Hydrogeochemistry and lead contamination of groundwater in the north part of Esfahan province, Iran

2018 ◽  
Vol 16 (4) ◽  
pp. 622-634 ◽  
Author(s):  
Kaveh Pazand ◽  
Davoud Khosravi ◽  
Mohammad Reza Ghaderi ◽  
Mohammad Reza Rezvanianzadeh
Keyword(s):  
Inductively Coupled Plasma ◽  
Arid Regions ◽  
Volcanic Rocks ◽  
Primary Source ◽  
Lead Contamination ◽  
Inductively Coupled ◽  
The North ◽  
Icp Ms ◽  
North Part ◽  
Plasma Mass Spectrometry

Abstract Geochemical and hydrogeochemical studies were conducted to assess the origin and geochemical mechanisms driving lead enrichment in groundwaters of semi-arid regions in Central Iran. In this study, 149 water samples were analyzed using inductively coupled plasma mass spectrometry (ICP-MS). Concentrations of Pb and As in about 68% and 27% of the samples, respectively, exceeded WHO guidelines. Analyzing the results of ICP-MS of parental rocks and aquifer sediments shows that unweathered volcanic rocks were the primary source for lead mobilizing to groundwaters.

scholarly journals Trace and Rare Earth Elements Compositional Change on Andesite Alteration in Kaligesing, Purworejo

2020 ◽  
Vol 21 (1) ◽  
pp. 17
Author(s):  
Joko Subandrio ◽  
Ronaldo Irzon
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Hydrothermal Alteration ◽  
Inductively Coupled Plasma ◽  
Microscopic Analysis ◽  
Inductively Coupled ◽  
Fine Grained ◽  
Central Java ◽  
Eu Anomaly ◽  
Plasma Mass Spectrometry

The change of chemical composition because of hydrothermal alteration process is related to the modification on mineralogy and elements mobility. Different alteration conditions could lead to dissimilar geochemical character. This study aims to discuss the alteration effect on trace and rare earth elements composition of an andesite outcrop with hydrothermal alteration in Kaligesing, Purworejo, Central Java Province. Microscopic analysis at Central for Geological Survey was applied to determine the modal mineral composition of the selected samples whilst trace and rare earth elements abundances was measured using Inductively Coupled Plasma – Mass Spectrometry. Plagioclase is the major phenocryst embedded in the fine-grained feldspar and glass groundmass of relatively fresh andesite. On the other hand, sericite, chlorite, epidote, and iron oxide are detected in the altered rock. The more Sr and Rb compositions on unaltered sample exhibit their common existence in plagioclase. The bigger Rb/Sr and the lower Ba/Sr ratios inward to the center of alteration might indicate the more degree of K-bearing mineral formation than Ca-rich mineral alteration. The Ba/Zr escalation and Zr/Y reduction from relatively fresh rock through to the vein of the studied samples are parallel to the previous investigation about andesite alteration. Chondrite-normalized rare-earth elements (REE) pattern of unaltered, altered, and vein samples depicts similar patterns: strong enrichment of Low REE, positive Eu anomaly, and relatively flat high REE. The decrease of Eu anomaly may reflect the reduction of plagioclase modal composition because of alteration and might indicate a reductive alteration state.Keywords: Alteration, andesite, geochemistry, trace and rare earth elements.

Geological Significance of Rare Earth Elements in Chinese Mount Huaying and their Applications

2012 ◽  
Vol 268-270 ◽  
pp. 637-641
Author(s):  
Wei Yi ◽  
Hong Jun Wang ◽  
Ting Zhou
Keyword(s):  
Inductively Coupled Plasma ◽  
World Economy ◽  
Green Energy ◽  
High Tech ◽  
Late Permian ◽  
Terrigenous Material ◽  
Inductively Coupled ◽  
Eu Anomaly ◽  
Wide Range ◽  
Plasma Mass Spectrometry

Analyses of REEs in 25 bulk samples collected from the Late Permian Longtan Formation in Mount Huaying district of Sichuan Province were determined useing Inductively Coupled Plasma Mass Spectrometry. The results indicate that REEs patterns are not controlled by materials from the sea, whereas the contribution of land plants is less than 0.5%. The ultimate sources of REEs are from terrigenous material as indicated by negative Eu anomaly. The Mount Emei basalt contributes to REEs enrichment of study area and all samples belong to the LREE-rich type and are enriched in LREEs relative to HREEs. So the sources of REEs are controlled by terrigenous material of Mount Emei basalt. Rare earths are an interesting group of metals that have recently become quite useful in high tech, and today they are strategic materials in the world economy. Besides, REEs play a key role in the green energy sector, REEs wide range of uses.

scholarly journals Early Paleozoic Adakitic Granitoids from the Xingshuping Gold Deposit of East Qinling, China: Petrogenesis and Tectonic Significance

Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1032
Author(s):  
Pei Zan ◽  
Shouyu Chen ◽  
Jinduo Chen ◽  
Shengli Li
Keyword(s):  
Gold Deposit ◽  
Inductively Coupled Plasma ◽  
Volcanic Rocks ◽  
Major And Trace Elements ◽  
Biotite Granite ◽  
Early Paleozoic ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Monzonitic Granite ◽  
Plasma Mass Spectrometry

This study discussed the pertrological classification, geochronology, petrogenesis and tectonic evolution of early Paleozoic granites from the Xingshuping gold deposit in the East Qinling orogenic belt. In order to achieve this target, we carried out an integrated study of zircon U–Pb age, whole-rock major and trace elements, as well as Sr–Nd–Hf isotope compositions for the Xingshuping granites (part of the Wuduoshan pluton) from the Erlangping unit. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating constrains the emplacement age of the Xingshuping granites at 446.2 ± 1.2 Ma. The rocks at Xingshuping can be divided into two types: mainly biotite granite and monzonitic granite. The biotite granites are typical adakitic rocks, while the monzonitic granites show characteristics similar to normal arc volcanic rocks. The geochemical compositions reveal that they were derived from a clay-rich, plagioclase-rich and biotite-rich psammitic lower continental crust source, with contributions of mantle-derived magmas. The distinction is that the biotite granites were primarily derived from partial melting in a syn-collision extension setting, whereas the monzonitic granite went through a fractional crystallization process in an intraplate anorogenic setting.

scholarly journals Morphology and Elemental Analysis of Freshly Emitted Particles from Packed-bed Domestic Coal Combustion

2019 ◽  
Author(s):  
Masilu Daniel Masekameni ◽  
Tafadzwa Makonese ◽  
Isaac Tebogo Rampedi
Keyword(s):  
Elemental Analysis ◽  
Coal Combustion ◽  
Inductively Coupled Plasma ◽  
Early Stage ◽  
Particle Diameter ◽  
Packed Bed ◽  
Spherical Particles ◽  
Inductively Coupled ◽  
Combustion Particles ◽  
Plasma Mass Spectrometry

This study was conducted in a laboratory-controlled environment aiming at studying the physical properties and elemental composition of coal combustion particles in a brazier. Particles were sampled ~1 m above the stove using a partector, where particles were collected on gold Transmission Electron Microscopy (TEM) grids and polycarbonate filters for TEM and inductively coupled plasma mass spectrometry (ICP-MS) analysis, respectively. Particles for elemental analysis collected on a 37 &micro;m polycarbonate filters whereby a Gillian pump was used to draw in air. During sampling, a 2.5 &micro;m cyclone was attached to the sampling cassette to isolate larger particles. The results have shown that combustion particles emitted during the early stage of combustion where single spherical particles with a diameter of around 450 nm. As the combustion progresses, the particle diameter gradually decreases and the morphology changes to accretion chain and fluffy bead structure for the flaming and char-burning phase, respectively.

scholarly journals A Study of Cathodoluminescence and Trace Element Compositional Zoning in Natural Quartz from Volcanic Rocks: Mapping Titanium Content in Quartz

2012 ◽  
Vol 18 (6) ◽  
pp. 1322-1341 ◽  
Author(s):  
William P. Leeman ◽  
Colin M. MacRae ◽  
Nick C. Wilson ◽  
Aaron Torpy ◽  
Cin-Ty A. Lee ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Volcanic Rocks ◽  
Quantitative Information ◽  
Titanium Content ◽  
Natural Quartz ◽  
Compositional Zoning ◽  
Quartz Crystals ◽  
Element Abundances ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

AbstractThis article concerns application of cathodoluminescence (CL) spectroscopy to volcanic quartz and its utility in assessing variation in trace quantities of Ti within individual crystals. CL spectroscopy provides useful details of intragrain compositional variability and structure but generally limited quantitative information on element abundances. Microbeam analysis can provide such information but is time-consuming and costly, particularly if large numbers of analyses are required. To maximize advantages of both approaches, natural and synthetic quartz crystals were studied using high-resolution hyperspectral CL imaging (1.2–5.0 eV range) combined with analysis via laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Spectral intensities can be deconvolved into three principal contributions (1.93, 2.19, and 2.72 eV), for which intensity of the latter peak was found to correlate directly with Ti concentration. Quantitative maps of Ti variation can be produced by calibration of the CL spectral data against relatively few analytical points. Such maps provide useful information concerning intragrain zoning or heterogeneity of Ti contents with the sensitivity of LA-ICPMS analysis and spatial resolution of electron microprobe analysis.

Pre-concentration of trace levels of rare-earth elements in high purity uranium samples for nuclear forensic purposes

2016 ◽  
Vol 104 (7) ◽  
Author(s):  
Judit Krajkó ◽  
Zsolt Varga ◽  
Maria Wallenius ◽  
Klaus Mayer
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
High Purity ◽  
Inductively Coupled Plasma ◽  
Fuel Cycle ◽  
Chemical Recovery ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry ◽  
Ree Patterns ◽  
Nuclear Forensic

AbstractThis paper describes the development of a method for the pre-concentration and analysis of trace-level amounts of rare-earth elements (REE) in high purity uranium (U) samples. The method comprises pre-concentration and subsequent group separation of REEs from the uranium matrix followed by their quantitative determination using inductively coupled plasma mass spectrometry. The achieved detection limit of the method (in the low pg/g range) in combination with the high chemical recovery (around 90%) enabled the investigation of REE patterns in high purity refined uranium oxides. Applying this method one could follow the REE pattern along the entire front-end of the nuclear fuel cycle.

Diagenetic and Epigenetic Mineralizing Events in the Kalahari Copperbelt, Botswana: Evidence from Re-Os Sulfide Dating and U-Th-Pb Xenotime Geochronology

2021 ◽  
Author(s):  
Wesley S. Hall ◽  
Holly J. Stein ◽  
Andrew R.C. Kylander-Clark ◽  
Murray W. Hitzman ◽  
Yvette D. Kuiper ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Wall Rock ◽  
Rock Fragment ◽  
Northern Margin ◽  
Inductively Coupled ◽  
Central African Copperbelt ◽  
Plasma Mass Spectrometry ◽  
History Of ◽  
Depositional Age ◽  
Host Rocks

Abstract The ages of sedimentation and copper-silver mineralization in the late Meso- to Neoproterozoic Kalahari Copperbelt in Botswana, an economically significant copper province, have previously been poorly constrained within a ~600 m.y. period that spans the Neoproterozoic from the assembly and breakup of Rodinia to the assembly of Gondwana. Rhenium-osmium geochronology of molybdenite and copper sulfide minerals and U-Th-Pb laser ablation split-stream inductively coupled plasma-mass spectrometry (LASS ICP-MS) analysis of xenotime grains are utilized to provide absolute and relative age data on the host rocks and mineralizing events within the Ghanzi Ridge region of the Kalahari Copperbelt. The data reveal a prolonged history of events, which is partially comparable with depositional and mineralizing events in the neighboring Central African Copperbelt. Abundant disseminated molybdenite is located within a shale layer near the base of the Proterozoic D’Kar Formation at the Northeast Mango Two deposit. Unusual molybdenite textures suggest organic matter may have been a precursor. Two molybdenite separates from a small calcite-molybdenite stringer in a wall-rock fragment that is enclosed within an epigenetic quartz-calcite-chalcopyrite vein with ill-defined and mismatched margins yielded Re-Os ages of 981 ± 3 and 981 ± 7 Ma. These ages indicate an early hydrothermal mineralizing event in the basin. A xenotime inclusion intergrown with molybdenite and chalcopyrite within the epigenetic vein yielded a younger U-Th-Pb age of 538 ± 8 Ma, suggesting two mineralizing events are preserved in a complex 6-cm-wide vein. Based on vein texture and alteration, the ages represent an ~981 Ma calcite-molybdenite mineralization event overprinted by an ~538 Ma quartz-chalcopyrite-molybdenite mineralization event, perhaps during reopening of the vein. Re-Os and U-Th-Pb geochronology were utilized at the Zone 6 deposit on minerals associated with a hydrothermal quartz-calcite-chalcocite-idaite-bornite vein. Several authigenic xenotime grains that occur along the margin of the vein yielded three concordant U-Th-Pb ages that indicate xenotime growth at ~950 to 925 Ma while other xenotime grains in a similar position yielded mostly discordant data, suggesting disturbance of the isotopic system in the xenotime grains. A coprecipitated chalcocite-idaite mixture within the hydrothermal vein produced an Re-Os age of 549.0 ± 11.2 Ma. Re-Os analysis obtained from a coprecipitated molybdenite-bornite mixture at the Northeast Fold deposit yielded an age of 515.9 ± 2 Ma. Together, the earliest Neoproterozoic Re-Os molybdenite and U-Th-Pb xenotime ages provide both a minimum depositional age constraint for the lowermost D’Kar Formation and clear evidence that diagenetic hydrothermal mineralizing events took place within the Ghanzi basin. The timing of this mineralizing event corresponds with a poorly documented regional thermal event that affected the northern margin of the Kalahari craton during the final stages of the assembly of Rodinia at ~980 Ma. The lower to middle Ghanzi Group of the Kalahari Copperbelt is at least 100 m.y. older than the host rocks within the neighboring Central African Copperbelt, which are associated with the breakup of Rodinia. The latest Neoproterozoic to Cambrian Re-Os and U-Th-Pb ages indicate that hydrothermal copper-silver mineralizing events occurred during the Pan-African (~600–480 Ma) fold-thrust evolution of the Ghanzi-Chobe zone and were broadly synchronous with widespread epigenetic hydrothermal copper-cobalt mineralizing events in the adjacent Central African Copperbelt.

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