scholarly journals Chlorine As a Disinfectant in Water Treatment

Author(s):  
Rifahat Muntaha

Abstract: Disinfection of treated water is a necessary process. For this, chlorine and its products are widely used. During the treatment process, chlorine is added to drinking water as elemental chlorine, sodium hypochlorite solution or dry calcium hypochlorite. When applied to water, each of these forms “free chlorine”, which destroys pathogenic organisms. If adequate water treatment is not readily available, the impact on public health can be devastating. Worldwide, about 1.2 billion people lack access to safe drinking water, and about 2.4 billion people lack sanitation. As per WHO, 3.4 million people die from waterrelated diseases. Drinking water chlorination will remain a cornerstone of disinfection. This is because of the wide range of benefits provided by chlorine. However, alternative disinfectants including ozone and UV radiation are available, all disinfection methods have unique benefits, limitations and costs. So, an engineer has to consider all the pros and cons of a disinfectant method properly before deciding the one to adopt. Keywords: Disinfection, Gaseous Chlorination, Sodium Hypochlorite, Calcium Hypochlorite, Ultraviolet, Ozone, Chlorine dioxide

Author(s):  
Tamara Krasnova ◽  
Yuri Skolubovich ◽  
Elena Gogina ◽  
Dmitry Volkov

Introduction. Effectiveness and applicability of chlorine-containing disinfectants used in the practice of water treatment were studied for the purpose of solving urgent environmental problems associated with the formation of secondary pollutants generated during the chlorination of natural water. Such contaminations are mostly represented by organohalogen compounds producing strong negative effect on the physiological state of living organisms, including human beings. To solve this problem, it is proposed to use technical grade sodium hypochlorite instead of traditional liquid chlorine when selecting disinfectants for natural water. Technical grade sodium hypochlorite is obtained by saturating solutions of diaphragmatic sodium hydroxide with chlorine gas at the stage of liquefaction of chlorine and caustic soda production. Sodium hypochlorite solution is significantly less toxic, non-flammable and not explosive. Materials and methods. A comparative study was conducted as to changes in the content of organohalogen compounds and heavy metals in water treated with sodium hypochlorite and liquid chlorine of one year duration. Analyses of water samples of water treated with liquid chlorine and sodium hypochlorite were made to measure concentrations of heavy metals, organohalogen compounds and other drinking water quality indicators, as specified by current regulations. Results. The obtained data demonstrate that the use of sodium hypochlorite for disinfection provides a higher quality of drinking water, therefore, it is advisable to replace liquid chlorine with technical grade sodium hypochlorite in the process of water treatment as potable water. Conclusions. The results of the study formed the basis for numerous industrial tests and subsequent implementation in existing water treatment plants in many large cities of Russia.


Agriculture ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 86
Author(s):  
Regina Böger ◽  
Karl Rohn ◽  
Nicole Kemper ◽  
Jochen Schulz

Poor drinking water quality can affect pigs’ health and performance. The disinfection of water may enhance microbial water quality. In this study, bacteria and endotoxins in sodium hypochlorite-treated and -untreated water from one pig nursery were analyzed. Water samples were taken from incoming water and from compartments with treated and untreated water at the beginning and end of pipes and from nipples. The farm was visited 14 times to measure total bacteria counts and concentrations of Pseudomonas spp. and endotoxins. Additionally, the occurrence of coliform bacteria was analyzed. A mixed model analysis revealed significant reductions in total bacteria counts and Pseudomonas spp. in treated water at the beginning of pipes and at nipple drinkers. The differences between bacteria concentrations at the end of pipes had no clear trend. Endotoxin concentrations were approximately equal at the beginning of pipes and at nipple drinkers but were found to have differences at the end of pipes. The occurrence of coliform bacteria was significantly reduced in treated water. The application of sodium hypochlorite can significantly reduce bacteria in water pipes. Endotoxin concentrations were mostly unaffected by water treatment. Disinfection of the dead-end pipe sections failed, and thus these parts should be regarded as potential contamination sources.


2000 ◽  
Vol 46 (6) ◽  
pp. 565-576 ◽  
Author(s):  
Pierre Payment ◽  
Aminata Berte ◽  
Michèle Prévost ◽  
Bruno Ménard ◽  
Benoît Barbeau

A 300-km portion of the Saint Lawrence hydrological basin in the province of Québec (Canada) and 45 water treatment plants were studied. River water used by drinking water treatment plants was analyzed (6-L sample volumes) to determine the level of occurrence of bacterial indicators (total coliforms, fecal coliforms, and Clostridium perfringens) and pathogens (Giardia lamblia, Cryptosporidium, human enteric viruses). Pathogens and bacterial indicators were found at all sites at a wide range of values. Logistic regression analysis revealed significant correlations between the bacterial indicators and the pathogens. Physicochemical and treatment practices data were collected from most water treatment plants and used to estimate the level of removal of pathogens achieved under cold (0°C-4°C) and warm (20°C-25°C) water temperature conditions. The calculated removal values were then used to estimate the annual risk of Giardia infection using mathematical models and to compare the sites. The estimated range of probability of infection ranged from 0.75 to less than 0.0001 for the populations exposed. Given the numerous assumptions made, the model probably overestimated the annual risk, but it provided comparative data of the efficacy of the water treatment plants and thereby contributes to the protection of public health.Key words: public health, drinking water, health risk, pathogen occurrence.


2020 ◽  
Vol 6 (11) ◽  
pp. 2993-3023
Author(s):  
Tyler A. Malkoske ◽  
Pierre R. Bérubé ◽  
Robert C. Andrews

Coagulation/flocculation has been grouped into three typical configurations and the impact of each examined in terms of floc properties and membrane fouling.


2019 ◽  
Vol 19 (8) ◽  
pp. 2330-2337
Author(s):  
Susumu Hasegawa ◽  
Yasuhiro Tanaka ◽  
Naokazu Wake ◽  
Ryosuke Takagi ◽  
Hideto Matsuyama

Abstract Recently, membrane filtration systems have become increasingly common in drinking water treatment plants. In this industry, preventing membrane fouling is of utmost importance. Many studies on the relationship between raw water components and membrane fouling have been performed in laboratory conditions. However, very few studies have analyzed the components of foulants on the fouled membrane as operated in actual drinking water treatment plants. By analyzing these components in plant-conditions, membrane fouling will be more effectively prevented. In this study, we analyzed the components of foulants extracted with 0.1 N NaOH from a fouled membrane operated in a drinking water treatment plant in Japan. Our analysis revealed that the main foulants were humic substances. In order to dissolve the accumulated humic substances, additional chemical cleaning was attempted with 500 ppm sodium hypochlorite. As a result, it was found that humic substances were dissolved and filtration resistance significantly decreased. Additionally, the removal of inorganic foulants was also greater after chemical cleaning with 500 ppm sodium hypochlorite, as inorganic foulants trapped within humic substances were released to the membrane surface as hydroxides by the additional sodium hypochlorite cleaning and were dissolved by the periodic citric acid cleaning.


1918 ◽  
Vol 28 (6) ◽  
pp. 681-699
Author(s):  
Glenn E. Cullen ◽  
Herbert D. Taylor

1. The use of the ears of rabbits is proposed in testing the irritant effect of antiseptics. 2. It is necessary, because of individual variations, to use solutions having definite irritant actions as controls. 3. 0.5 per cent sodium hypochlorite solutions have minimum irritant effects over a range of alkalinity of from about 100 to 1,000 times that of water (pH about 9 to 10). Solutions may be adjusted within these limits by use of the end-points of powdered phenolphthalein, of alcoholic solutions of either o-cresolphthalein or phenolphthalein. 4. Sodium hypochlorite solutions kept within the above range of alkalinity by either borate or carbonate buffer salts, i.e. Dakin's solution, show the same irritative properties whether made from bleaching powder and sodium carbonate, or from chlorine and sodium carbonate. 5. Electrolytically prepared solutions of the same concentration have similar irritant action. 6. Solutions, however, that have an alkalinity less than that indicated by the end-point of alcoholic phenolphthalein solutions (pH of 8.5 to 8.8) or greater than that indicated by the end-point to powdered phenolphthalein (pH of 10.2) are intensely irritating. 7. 0.5 per cent sodium hypochlorite solution from which most of the calcium has been precipitated and calcium hypochlorite solution of equivalent hypochlorite concentration are only slightly irritating. 8. 2 per cent chloramine-T solution has no irritant action. 9. 5 per cent dichloramine-T in chlorcosane and chlorcosane alone irritate rabbit ears to a slight degree only.


2010 ◽  
Vol 77 (3) ◽  
pp. 1041-1048 ◽  
Author(s):  
Frederik Hammes ◽  
Nico Boon ◽  
Marius Vital ◽  
Petra Ross ◽  
Aleksandra Magic-Knezev ◽  
...  

ABSTRACTPellet softening reactors are used in centralized and decentralized drinking water treatment plants for the removal of calcium (hardness) through chemically induced precipitation of calcite. This is accomplished in fluidized pellet reactors, where a strong base is added to the influent to increase the pH and facilitate the process of precipitation on an added seeding material. Here we describe for the first time the opportunistic bacterial colonization of the calcite pellets in a full-scale pellet softening reactor and the functional contribution of these colonizing bacteria to the overall drinking water treatment process. ATP analysis, advanced microscopy, and community fingerprinting with denaturing gradient gel electrophoretic (DGGE) analysis were used to characterize the biomass on the pellets, while assimilable organic carbon (AOC), dissolved organic carbon, and flow cytometric analysis were used to characterize the impact of the biological processes on drinking water quality. The data revealed pellet colonization at concentrations in excess of 500 ng of ATP/g of pellet and reactor biomass concentrations as high as 220 mg of ATP/m3of reactor, comprising a wide variety of different microorganisms. These organisms removed as much as 60% of AOC from the water during treatment, thus contributing toward the biological stabilization of the drinking water. Notably, only a small fraction (about 60,000 cells/ml) of the bacteria in the reactors was released into the effluent under normal conditions, while the majority of the bacteria colonizing the pellets were captured in the calcite structures of the pellets and were removed as a reusable product.


Sign in / Sign up

Export Citation Format

Share Document