DETECTION OF IN-SITU GENERATED GLYCEROL AT A LIQUID-LIQUID INTERFACE BY ELECTROCHEMICAL METHODS

Author(s):  
Etienne Sampaio Oliveira
2014 ◽  
Vol 53 (14) ◽  
pp. 5858-5865 ◽  
Author(s):  
Vedapriya Pandarinathan ◽  
Kateřina Lepková ◽  
Stuart I. Bailey ◽  
Thomas Becker ◽  
Rolf Gubner

Author(s):  
Yujie Li ◽  
Jie Wang ◽  
Shijie Wang ◽  
Di Li ◽  
Shan Song ◽  
...  

The immiscible two-phase flow behaves nonlinearly, and it is a challenging task to control and stabilize the liquid-liquid interface. Parallel flow forms under a proper balance between the driving force, the friction resistance, and the interfacial tension. The liquid-solid interaction as well as the liquid-liquid interaction plays an important role in manipulating the liquid-liquid interface. With vacuum-driven flow, long and stable parallel flow is possible to be obtained in oil-water systems and can be used for fabricating micro- and nanomaterials. Ultra-small Cu nanoparticles of 4~10 nm were synthesized continuously through chemical reactions taking place on the interface. This makes it possible for in situ synthesis of conductive nanoink avoiding oxidation. Well-controlled interface reactions can also be used to produce ultra-long sub-micro Cu wires up to 10 mm at room temperature. This method provided new and simple additive fabrication methods for making integrated microfluidic devices.


2019 ◽  
Vol 5 (1) ◽  
pp. 152-160 ◽  
Author(s):  
Yanyan Cui ◽  
Jianwei Yu ◽  
Ming Su ◽  
Zeyu Jia ◽  
Tingting Liu ◽  
...  

A novel advanced oxidation process (AOP) based on plasma in gas–liquid interface discharge was evaluated for humic acid removal. Much better performance was obtained compared to ozonation. The OH˙ radicals generated by reaction of in situ produced ozone and H2O2 during discharge process were mainly responsible for the removal.


2020 ◽  
Vol 10 (16) ◽  
pp. 5362-5385
Author(s):  
Leila Negahdar ◽  
Christopher M. A. Parlett ◽  
Mark A. Isaacs ◽  
Andrew M. Beale ◽  
Karen Wilson ◽  
...  

Many industrially important chemical transformations occur at the interface between a solid catalyst and liquid reactants. In situ and operando spectroscopies offer unique insight into the reactivity of such catalytically active solid–liquid interfaces.


1991 ◽  
Vol 237 ◽  
Author(s):  
Richard D. Robinson ◽  
Ioannis N. Miaoulis

ABSTRACTThis paper presents a new experimental method to investigate solid-liquid interface morphologies during Zone-Melting-Recrystallization at lower than the typical processing temperatures. Gallium films were used as a substitute for silicon films. In situ preliminary investigation identified three phenomena typically occurring during ZMR of silicon films: a) Transition from planar to dendritic to cellular morphologies was observed for different processing conditions; b) cell period proved to be dependant on scanning velocity; c) instabilities at the solidification interface at low heating strip temperatures were caused by supercooling and optical property variations as the material changed phase.


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