scholarly journals Modelling of Two-Stage Methane Digestion With Pretreatment of Biomass

2018 ◽  
Vol 55 (2) ◽  
pp. 37-44
Author(s):  
A. Dychko ◽  
N. Remez ◽  
I. Opolinskyi ◽  
S. Kraychuk ◽  
N. Ostapchuk ◽  
...  

Abstract Systems of anaerobic digestion should be used for processing of organic waste. Managing the process of anaerobic recycling of organic waste requires reliable predicting of biogas production. Development of mathematical model of process of organic waste digestion allows determining the rate of biogas output at the two-stage process of anaerobic digestion considering the first stage. Verification of Konto’s model, based on the studied anaerobic processing of organic waste, is implemented. The dependencies of biogas output and its rate from time are set and may be used to predict the process of anaerobic processing of organic waste.

Energies ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5423
Author(s):  
Margarita Andreas Dareioti ◽  
Aikaterini Ioannis Vavouraki ◽  
Konstantina Tsigkou ◽  
Michael Kornaros

The growing interest in processes that involve biomass conversion to renewable energy, such as anaerobic digestion, has stimulated research in this field in order to assess the optimum conditions for biogas production from abundant feedstocks, like agro-industrial wastes. Anaerobic digestion is an attractive process for the decomposition of organic wastes via a complex microbial consortium and subsequent conversion of metabolic intermediates to hydrogen and methane. The present study focused on the exploitation of liquid cow manure (LCM) and cheese whey (CW) as noneasily and easily biodegradable sources, respectively, using continuous stirred-tank reactors for biogas production, and a comparison was presented between single- and two-stage anaerobic digestion systems. No significant differences were found concerning LCM treatment, in a two-stage system compared to a single one, concluding that LCM can be treated by implementing a single-stage process, as a recalcitrant substrate, with the greatest methane production rate of 0.67 L CH4/(LR·d) at an HRT of 16 d. On the other hand, using the easily biodegradable CW as a monosubstrate, the two-stage process was considered a better treatment system compared to a single one. During the single-stage process, operational problems were observed due to the limited buffering capacity of CW. However, the two-stage anaerobic digestion of CW produced a stable methane production rate of 0.68 L CH4/(LR·d) or 13.7 L CH4/Lfeed, while the total COD was removed by 76%.


2017 ◽  
Vol 166 ◽  
pp. 519-529 ◽  
Author(s):  
Mario Panjičko ◽  
Gregor D. Zupančič ◽  
Lijana Fanedl ◽  
Romana Marinšek Logar ◽  
Marina Tišma ◽  
...  

2017 ◽  
pp. 130 ◽  
Author(s):  
Margarita A. Dareioti ◽  
Spyros N. Dokianakis ◽  
Constantina Zafiri ◽  
Michael Kornaros

Cheese making companies have a specific product that is seasonally produced and, like most other agro-industries, generate wastewaters characterized by a high organic loading. Cheese whey is the most important waste stream produced having a high organic content (up to 70 g COD/L), which is highly biodegradable, and low alkalinity (50 meq/L). Cheese production industries worldwide generate more than 145 million tones of liquid whey per year. Because of these characteristics, cheese whey may cause serious environmental problems on the local municipal sewage treatment systems or water receptors if disposed untreated. Anaerobic digestion is a particularly attractive treatment solution for high strength wastewaters due to the operational economy and generation of biogas and therefore is considered as a promising solution for energy production from cheese whey, in this case. In this work, a comparative study between single and two-stage anaerobic treatment of cheese whey was conducted in order to enhance biogas production. Our experiments were carried out using one reactor for the single-stage process (operated at a HRT of 20 d), and two reactors connected in series, from which the first one was used for acidogenesis (operated at a HRT of 3 d) and the other for methanogenesis (operated at a HRT of 20 d). The single-stage process presented many operational problems, as a result of little or no buffering capacity of whey, which caused the pH of the anaerobic digester to drop drastically and the process being inhibited. This kind of inhibition proved to be irreversible and the digester was not able to recover even though it was operated batchwise and the value of the pH was restored to 7.0. On the contrary, the two-stage process exhibited a stable biogas production rate of 1.57 L/Lreactor/d with the composition of methane in the biogas reaching 54.3%. The dissolved COD and total carbon concentration removal was 70.5% and 77.2% respectively.


2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Karol Postawa ◽  
Jerzy Szczygieł ◽  
Marek Kułażyński

Abstract Background Increasing the efficiency of the biogas production process is possible by modifying the technological installations of the biogas plant. In this study, specific solutions based on a mathematical model that lead to favorable results were proposed. Three configurations were considered: classical anaerobic digestion (AD) and its two modifications, two-phase AD (TPAD) and autogenerative high-pressure digestion (AHPD). The model has been validated based on measurements from a biogas plant located in Poland. Afterward, the TPAD and AHPD concepts were numerically tested for the same volume and feeding conditions. Results The TPAD system increased the overall biogas production from 9.06 to 9.59%, depending on the feedstock composition, while the content of methane was slightly lower in the whole production chain. On the other hand, the AHPD provided the best purity of the produced fuel, in which a methane content value of 82.13% was reached. At the same time, the overpressure leads to a decrease of around 7.5% in the volumetric production efficiency. The study indicated that the dilution of maize silage with pig manure, instead of water, can have significant benefits in the selected configurations. The content of pig slurry strengthens the impact of the selected process modifications—in the first case, by increasing the production efficiency, and in the second, by improving the methane content in the biogas. Conclusions The proposed mathematical model of the AD process proved to be a valuable tool for the description and design of biogas plant. The analysis shows that the overall impact of the presented process modifications is mutually opposite. The feedstock composition has a moderate and unsteady impact on the production profile, in the tested modifications. The dilution with pig manure, instead of water, leads to a slightly better efficiency in the classical configuration. For the TPAD process, the trend is very similar, but the AHPD biogas plant indicates a reverse tendency. Overall, the recommendation from this article is to use the AHPD concept if the composition of the biogas is the most important. In the case in which the performance is the most important factor, it is favorable to use the TPAD configuration.


Water ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 590
Author(s):  
Aiban Abdulhakim Saeed Ghaleb ◽  
Shamsul Rahman Mohamed Kutty ◽  
Gasim Hayder Ahmed Salih ◽  
Ahmad Hussaini Jagaba ◽  
Azmatullah Noor ◽  
...  

Man-made organic waste leads to the rapid proliferation of pollution around the globe. Effective bio-waste management can help to reduce the adverse effects of organic waste while contributing to the circular economy at the same time. The toxic oily-biological sludge generated from oil refineries’ wastewater treatment plants is a potential source for biogas energy recovery via anaerobic digestion. However, the oily-biological sludge’s carbon/nitrogen (C/N) ratio is lower than the ideal 20–30 ratio required by anaerobic digestion technology for biogas production. Sugarcane bagasse can be digested as a high C/N co-substrate while the oily-biological sludge acts as a substrate and inoculum to improve biogas production. In this study, the best C/N with co-substrate volatile solids (VS)/inoculum VS ratios for the co-digestion process of mixtures were determined empirically through batch experiments at temperatures of 35–37 °C, pH (6–8) and 60 rpm mixing. The raw materials were pre-treated mechanically and thermo-chemically to further enhance the digestibility. The best condition for the sugarcane bagasse delignification process was 1% (w/v) sodium hydroxide, 1:10 solid-liquid ratio, at 100 °C, and 150 rpm for 1 h. The results from a 33-day batch anaerobic digestion experiment indicate that the production of biogas and methane yield were concurrent with the increasing C/N and co-substrate VS/inoculum VS ratios. The total biogas yields from C/N 20.0 with co-substrate VS/inoculum VS 0.06 and C/N 30.0 with co-substrate VS/inoculum VS 0.18 ratios were 2777.0 and 9268.0 mL, respectively, including a methane yield of 980.0 and 3009.3 mL, respectively. The biogas and methane yield from C/N 30.0 were higher than the biogas and methane yields from C/N 20.0 by 70.04 and 67.44%, respectively. The highest biogas and methane yields corresponded with the highest C/N with co-substrate VS/inoculum VS ratios (30.0 and 0.18), being 200.6 mL/g VSremoved and 65.1 mL CH4/g VSremoved, respectively.


Author(s):  
Kai Schumüller ◽  
Dirk Weichgrebe ◽  
Stephan Köster

AbstractTo tap the organic waste generated onboard cruise ships is a very promising approach to reduce their adverse impact on the maritime environment. Biogas produced by means of onboard anaerobic digestion offers a complementary energy source for ships’ operation. This report comprises a detailed presentation of the results gained from comprehensive investigations on the gas yield from onboard substrates such as food waste, sewage sludge and screening solids. Each person onboard generates a total average of about 9 kg of organic waste per day. The performed analyses of substrates and anaerobic digestion tests revealed an accumulated methane yield of around 159 L per person per day. The anaerobic co-digestion of sewage sludge and food waste (50:50 VS) emerged as particularly effective and led to an increased biogas yield by 24%, compared to the mono-fermentation. In the best case, onboard biogas production can provide an energetic output of 82 W/P, on average covering 3.3 to 4.1% of the total energy demand of a cruise ship.


Author(s):  
Pranas Baltrėnas ◽  
Mindaugas Kvasauskas

The paper presents the findings of experimental investigation of biogas production using hen manure and sewage sludge with fatty waste (from margarine production). The following mixtures were made using this organic waste: hen manure and sewage sludge were mixed with fatty waste at 75% : 25%, 50% : 50% and 25% : 75% in volume. The paper analyses quantitative and qualitative composition of biogas: gas emission content, the concentrations of methane, sulphuretted hydrogen and oxygen in it as well as temperature and pH change during the experiment. Mixing hen manure with fatty waste at 75% : 25% and maintaining psychrophilic temperature mode, the highest biogas output (0.09 m3) from 0.2 m3 substrate in 32 days was recorded. When using the mixture of sewage sludge and fatty waste at 75% : 25% and maintaining psychrophilic temperature mode, the highest biogas output (0.10 m) from 0.2 m substrate in 32 days was recorded. When using these mixtures, the concentration of methane was also the highest, and the average values reached 58.5% (with hen manure) and 61.7% (with sewage sludge). The evaluation of gas emissions and methane concentration in gas shows that the most efficient use of biogas could be obtained using biogas emitted from the mixture of hen manure and sewage sludge with fatty waste mixed at 75% : 25%. The concentration of sulphuretted hydrogen in biogas did not exceed 3%, the concentration of oxygen decreased from 4.9 % to 1.8%. pH indicator was decreasing when more fatty waste was added to the mixture. When using hen manure, the average value of pH changed from 6.4 to 6.3, when using sewage sludge ‐ from 6.6 to 6.3. Santrauka Pateikiami eksperimentinių biodujų gamybos tyrimų, naudojant vištų mėšlą ir nuotekų valymo dumblą su riebalinėmis (margarino gamybos) atliekomis, rezultatai. Iš šių organinių atliekų buvo paruošti mišiniai: vištų mėšlas bei nuotekų valymo dumblas buvo maišomas su riebalinėmis atliekomis 75 % : 25 %, 50 % : 50 % ir 25 % : 75 %. Darbe nagrinėjama biodujų kiekybinė ir kokybinė sudėtis: išsiskyrusių dujų kiekis, metano, sieros vandenilio ir deguonies koncentracija jose, temperatūros bei pH pokytis eksperimento metu. Eksperimentų metu bioreaktoriuose buvo palaikomas psichrofilinis temperatūrinis režimas. Nustatyta, kad didžiausias biodujų kiekis (0,09 m3 ) išsiskiria vištų mėšlą maišant su riebalinėmis atliekomis santykiu 75 % : 25 %. Naudojant nuotekų valymo dumblo ir riebalinių atliekų mišinį (75 % : 25 %), taip pat gauta didžiausia biodujų išeiga per visą eksperimento laikotarpį – 0,10 m3 . Metano koncentracija naudojant šiuos mišinius taip pat buvo didžiausia. Vidutinė reikšmė siekė 58,5 % (su vištų mėšlu) bei 61,7 % (su nuotekų dumblu). Įvertinus išsiskyrusių dujų kiekį ir metano koncentraciją jose, nustatyta, kad efektyviausiai būtų galima naudoti biodujas, išsiskyrusias iš vištų mėšlo ir nuotekų valymo dumblo su riebalinėmis atliekomis, kurių santykis 75 % : 25 %. Sieros vandenilio koncentracija biodujose neviršijo 3 %, deguonies koncentracija mažėjo nuo 4,9 % iki 1,8 %. pH rodiklis mažėjo į biomasės mišinį įdedant daugiau riebalinių atliekų. Naudojant vištų mėšlą vidutinė pH reikšmė kito nuo 6,4 iki 6,3, naudojant nuotekų valymo dumblą – nuo 6,6 iki 6,3. Резюме Представлены результаты экспериментальных исследований по производству биогаза с использованием куриного помета и ила сточных вод с жировыми отходами (от производства маргарина). Были исследованы следующие смеси из органических отходов: куриный помет и ил сточных вод были смешаны с жировыми отходами в объеме 75% : 25%, 50% : 50% и 25% : 75%. Проанализирован количественный и качественный состав биогаза: газовое содержание эмиссии, концентрации метана, сероводорода и кислорода, а также изменение температуры и фактора pH в течение эксперимента. Во время эксперимента в биореакторе поддерживался психрофильный температурный режим. Было установлено, что при смешивании куриного помета с жировыми отходами в соотношении 75% : 25% и поддерживании психрофильного температурного режима наибольший выпуск биогаза (от 0,09 м3 до 0,2 м3 субстрата) обнаружен спустя 32 дня. При использовании смеси из ила сточных вод и жировых отходов в соотношении 75% : 25% и поддерживании психрофильного температурного режима был установлен наибольший выпуск биогаза (от 0,10 м3 до 0,2 м3 субстрата) спустя 32 дня. При использовании этих смесей концентрация метана также была самая большая, ее средние значения составляли 58,5% (с куриным пометом) и 61,7% (с илом сточных вод). В результате оценки газовой эмиссии и концентрации метана в эмиссии установлено, что наиболее эффективным будет использование биогаза, получаемого от смеси куриного помета и ила сточных вод с жировыми отходами в соотношении 75% : 25%. Концентрация сероводорода в биогазе не превышала 3%, концентрация кислорода уменьшилась от 4,9% до 1,8%. Индикатор фактора pH уменьшался, когда к смеси добавлялось больше жировых отходов. При использовании только куриного помета среднее значение фактора pH менялось от 6,4 до 6,3, при использовании ила сточных вод – от 6,6 до 6,3.


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