1,7′-dimethyl-2′-propyl-1H,3′H-2,5′-bibenzo[d]imidazole as a corrosion inhibitor of mild steel in 1 M HCl

2010 ◽  
Vol 64 (1) ◽  
Author(s):  
Niketan Patel ◽  
Smita Jauhari ◽  
Girishkumar Mehta
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Mass Loss ◽  
Corrosion Inhibitor ◽  
Electrochemical Impedance ◽  
Protective Layer ◽  
Charge Transfer Resistance ◽  
Active Centers ◽  
Transfer Resistance

AbstractInhibition effect of imidazole derivative 1,7′-dimethyl-2′-propyl-1H,3′H-2,5′-bibenzo[d]imidazole (DPBI) against mild steel corrosion in 1 M HCl solutions was evaluated using the conventional mass loss method, potentiodynamic polarization, linear polarization, and electrochemical impedance spectroscopy. The mass loss results showed that DPBI is an excellent corrosion inhibitor; electrochemical polarizations data revealed the mixed mode of inhibition; and the results of electrochemical impedance spectroscopy showed that the change in the impedance parameters, charge transfer resistance, and double layer capacitance with the change in the concentration of the inhibitor is due to the adsorption of the molecule leading to the formation of a protective layer on the surface of mild steel. The inhibition action of this compound was assumed to occur via adsorption on the steel surface through the active centers of the molecule.

scholarly journals Charge Transfer Resistance and Adsorption performance of a New Pyrrole Derivative on Mild steel in Acidic media: Antibacterial studies

2021 ◽  
Vol 37 (4) ◽  
pp. 779-790
Author(s):  
G. Pandimuthu ◽  
P. Muthukrishnan ◽  
S. Rameshkumar ◽  
K. Paramasivaganesh ◽  
A. Sankar
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Inhibition Efficiency ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Pyrrole Derivatives ◽  
Tafel Polarization ◽  
Influence Of Temperature On

In the present work, Pyrrole derivatives containing oxygen, nitrogenand aromatic rings namely,N-(1H-Pyrrol-2-ylmethylidene)-2,3-dihydro-1,4-benzodioxin-6-amine (BPS) was synthesized and its anticorrosion potential was studied applying the gravimetric, polarization and AC impedance methods on the mild steel (MS) corrosion in corrodent (0.5M H2SO4 and 1 M HCl). It is observed that in the acidic environments, the inhibition efficiency (IE) of the BPS raised with the enhance in the concentration and it resulted in greater inhibition efficiency in1 M HCl solution than in 0.5M H2SO4 solution. The inhibition efficiency assessed by Electrochemical Impedance Spectroscopy reaches about 81.6% in 0.5 M H2SO4 and 84.2% in 1.0 M HCl solutions at 600 ppm of BPS.The studied BPS being mixed type inhibitor was shown by the Tafel polarization curves. And it was noticed that over the MS surface, the adsorption of the BPS obeyed Langmuirisotherm. In order to ascertain the inhibitor mechanism, the potential of zero charge (PZC) was measured. Electrochemical Impedance spectroscopy was applied to assess the influence of temperature on corrosion inhibition.The surface morphology of MS surface was analyzed using SEM and AFM techniques. The anti-bacterial activity for the BPS was studied as a divergent analysis.

scholarly journals Corrosion Inhibitive Properties of 5-(4-Aminophenyl)-1,3,4-oxadiazole-2-thiol and 5-(4-Methylphenyl)-1,3,4-oxadiazole-2-thiol on Mild Steel in 1.0 M HCl Solution

2021 ◽  
Vol 33 (12) ◽  
pp. 2953-2964
Author(s):  
Vikas Kalia ◽  
Pradeep Kumar ◽  
Suresh Kumar ◽  
Hariom Dahiya
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Polarization Measurement ◽  
Weight Loss Measurement ◽  
Transfer Resistance ◽  
Loss Measurement

The corrosion inhibition consequence of 5-(4-aminophenyl)-1,3,4-oxadiazole-2-thiol (APOT) and 5-(4-methylphenyl)-1,3,4-oxadiazole-2-thiol (MPOT) were accomplished by employing weight loss measurement, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization measurement and scanning electron microscope (SEM). An impact of immersion time 12.0 h and different temperatures (298, 308 and 318 K) with solution of 1.0 M HCl, which include various concentration of inhibitor at the corrosion of mild steel were designed. Weight loss measurement showed that with enhancing the concentration of these studied inhibitors the percentage inhibition efficiency (IE%) enhances, but corrosion rate (CR) diminishes while reverse condition in case of temperatures change. The electrochemical impedance spectroscopy examine pointed out that the charge transfer resistance (Rct) values enhances and consequently the double layer capacitance (Cdl) values diminishes with rising each inhibitor concentration in 1.0 M HCl and also there is a formation of adsorption coating at the metal surface. Polarization measurement showed that both APOT and MPOT perform as mixed type corrosion inhibitors. Furthermore, the adsorption behaviour on surface of mild steel for each studied inhibitor results the Langmuir adsorption isotherm. Surface conduct of mild steel also designed through the SEM and energy dispersive X-ray (EDX) analysis and concludes that there is evolution of inhibitive film of APOT and MPOT on the surface of mild steel.

scholarly journals Deciphering the Disaggregation Mechanism of Amyloid Beta Aggregate by 4-(2-Hydroxyethyl)-1-Piperazinepropanesulfonic Acid Using Electrochemical Impedance Spectroscopy

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 788
Author(s):  
Hien T. Ngoc Le ◽  
Sungbo Cho
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Binding ◽  
Amyloid Β ◽  
Electrochemical Measurement ◽  
Charge Transfer Resistance ◽  
Chemical Agent ◽  
Transfer Resistance ◽  
K Value

Aggregation of amyloid-β (aβ) peptides into toxic oligomers, fibrils, and plaques is central in the molecular pathogenesis of Alzheimer’s disease (AD) and is the primary focus of AD diagnostics. Disaggregation or elimination of toxic aβ aggregates in patients is important for delaying the progression of neurodegenerative disorders in AD. Recently, 4-(2-hydroxyethyl)-1-piperazinepropanesulfonic acid (EPPS) was introduced as a chemical agent that binds with toxic aβ aggregates and transforms them into monomers to reduce the negative effects of aβ aggregates in the brain. However, the mechanism of aβ disaggregation by EPPS has not yet been completely clarified. In this study, an electrochemical impedimetric immunosensor for aβ diagnostics was developed by immobilizing a specific anti-amyloid-β (aβ) antibody onto a self-assembled monolayer functionalized with a new interdigitated chain-shaped electrode (anti-aβ/SAM/ICE). To investigate the ability of EPPS in recognizing AD by extricating aβ aggregation, commercially available aβ aggregates (aβagg) were used. Electrochemical impedance spectroscopy was used to probe the changes in charge transfer resistance (Rct) of the immunosensor after the specific binding of biosensor with aβagg. The subsequent incubation of the aβagg complex with a specific concentration of EPPS at different time intervals divulged AD progression. The decline in the Rct of the immunosensor started at 10 min of EPPS incubation and continued to decrease gradually from 20 min, indicating that the accumulation of aβagg on the surface of the anti-aβ/SAM/ICE sensor has been extricated. Here, the kinetic disaggregation rate k value of aβagg was found to be 0.038. This innovative study using electrochemical measurement to investigate the mechanism of aβagg disaggregation by EPPS could provide a new perspective in monitoring the disaggregation periods of aβagg from oligomeric to monomeric form, and then support for the prediction and handling AD symptoms at different stages after treatment by a drug, EPPS.

scholarly journals Investigation of Temperature and Aging Effects in Nanostructured Dye Solar Cells Studied by Electrochemical Impedance Spectroscopy

2009 ◽  
Vol 2009 ◽  
pp. 1-15 ◽  
Author(s):  
Minna Toivola ◽  
Janne Halme ◽  
Lauri Peltokorpi ◽  
Peter Lund
Keyword(s):  
Solar Cells ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Aging Effects ◽  
Transfer Resistance ◽  
Deterioration Rate ◽  
Dye Solar Cells ◽  
Effects Of Aging

Effects of aging and cyclically varying temperature on the electrical parameters of dye solar cells were analyzed with electrochemical impedance spectroscopy. Photoelectrode total resistance increased as a function of time due to increasing electron transport resistance in theTiO2film. On the other hand, photoelectrode recombination resistance was generally larger, electron lifetimes in theTiO2were film longer, and charge transfer resistance on the counter electrode was smaller after the temperature treatments than before them. These effects correlated with the slower deterioration rate of the temperature-treated cells, in comparison to the reference cells.

scholarly journals Yeast Propagation Control: Low Frequency Electrochemical Impedance Spectroscopy as an Alternative for Cell Counting Chambers in Brewery Applications

Chemosensors ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 27
Author(s):  
Georg Christoph Brunauer ◽  
Oliver Spadiut ◽  
Alfred Gruber ◽  
Christoph Slouka
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Pathogen Detection ◽  
Electrochemical Impedance ◽  
Low Frequency ◽  
Charge Transfer Resistance ◽  
Cell Counting ◽  
Delayed Response ◽  
Transfer Resistance ◽  
Cell Counts

Electrochemical impedance spectroscopy is a powerful tool in life science for cell and pathogen detection, as well as for cell counting. The measurement principles and techniques using impedance spectroscopy are highly diverse. Differences can be found in used frequency range (β or α regime), analyzed quantities, like charge transfer resistance, dielectric permittivity of double layer capacitance and in off- or online usage. In recent contributions, applications of low-frequency impedance spectroscopy in the α regime were tested for determination of cell counts and metabolic burden in Escherichia coli and Saccharomyces cerevisiae. The established easy to use methods showed reasonable potential in the lab scale, especially for S. cerevisiae. However, until now, measurements for cell counts in food science are generally based on Thoma cell counting chambers. These microscopic cell counting methods decelerate an easy and quick prediction of yeast viability, as they are labor intensive and result in a time delayed response signal. In this contribution we tested our developed method using low frequency impedance spectroscopy locally at an industrial brewery propagation site and compared results to classic cell counting procedures.

scholarly journals Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4507 ◽  
Author(s):  
Yusuke Abe ◽  
Natsuki Hori ◽  
Seiji Kumagai
Keyword(s):  
Charge Transfer ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Performance Degradation ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Charge Discharge

Lithium-ion batteries (LIBs) using a LiFePO4 cathode and graphite anode were assembled in coin cell form and subjected to 1000 charge-discharge cycles at 1, 2, and 5 C at 25 °C. The performance degradation of the LIB cells under different C-rates was analyzed by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The most severe degradation occurred at 2 C while degradation was mitigated at the highest C-rate of 5 C. EIS data of the equivalent circuit model provided information on the changes in the internal resistance. The charge-transfer resistance within all the cells increased after the cycle test, with the cell cycled at 2 C presenting the greatest increment in the charge-transfer resistance. Agglomerates were observed on the graphite anodes of the cells cycled at 2 and 5 C; these were more abundantly produced in the former cell. The lower degradation of the cell cycled at 5 C was attributed to the lowered capacity utilization of the anode. The larger cell voltage drop caused by the increased C-rate reduced the electrode potential variation allocated to the net electrochemical reactions, contributing to the charge-discharge specific capacity of the cells.

scholarly journals Inhibitive Effect by Acid Extract of Ficus Exasperata Leaves on the Sulphuric Acid Corrosion of Mild Steel

2009 ◽  
Vol 6 (s1) ◽  
pp. S189-S194 ◽  
Author(s):  
N. S. Patel ◽  
S. Jauhari ◽  
G. N. Mehta
Keyword(s):  
Weight Loss ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Mild Steel ◽  
Corrosion Inhibitor ◽  
Electrochemical Impedance ◽  
Electron Microscopic ◽  
Scanning Electron Microscopic ◽  
Microscopic Studies ◽  
Scanning Electron

Extract ofFicus exasperataleaves was investigated as corrosion inhibitor of mild steel in 1 N H2SO4using conventional weight loss, electrochemical polarizations, electrochemical impedance spectroscopy and scanning electron microscopic studies. The weight loss results showed that the extract ofFicus exasperatais excellent corrosion inhibitor. Electrochemical polarizations data revealed the mixed mode of inhibition. The results of electrochemical impedance spectroscopy shows that the change in the impedance parameters, charge transfer resistance and double layer capacitance, with the change in concentration of the extract is due to the adsorption of active molecules leading to the formation of a protective layer on the surface of mild steel. Scanning electron microscopic studies provided the confirmatory evidence of improved surface condition, due to the adsorption, for the corrosion protection.

Thermal transitions in hydrated layer-by-layer assemblies observed using electrochemical impedance spectroscopy

Soft Matter ◽  
2014 ◽  
Vol 10 (34) ◽  
pp. 6467-6476 ◽  
Author(s):  
Choonghyun Sung ◽  
Katelin Hearn ◽  
Jodie Lutkenhaus
Keyword(s):  
Charge Transfer ◽  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Electrochemical Impedance ◽  
Charge Transfer Resistance ◽  
Thermal Transition ◽  
Layer By Layer ◽  
Thermal Transitions ◽  
Transfer Resistance ◽  
Hydrated Layer

Layer-by-layer assemblies exhibit increased conductivity and decreased charge transfer resistance upon heating through the thermal transition.

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