scholarly journals Application of central composite design for the optimization of photo-destruction of a textile dye using UV/S2O82- process

2009 ◽  
Vol 11 (4) ◽  
pp. 38-45 ◽  
Author(s):  
A. Khataee
Keyword(s):  
Reaction Time ◽  
Central Composite Design ◽  
Electrical Energy ◽  
Textile Dye ◽  
Operational Parameters ◽  
Destruction Efficiency ◽  
Uv Lamp ◽  
Electrical Energy Per Order ◽  
Experimental Values ◽  
Central Composite

Application of central composite design for the optimization of photo-destruction of a textile dye using UV/S2O82- process The photooxidative destruction of C. I. Basic Red 46 (BR46) by UV/S2O82- process is presented. Central Composite Design (CCD) was employed to optimize the effects of operational parameters on the photooxidative destruction efficiency. The variables investigated were the initial dye and S2O82- concentrations, reaction time and distance of the solution from UV lamp. The predicted values of the photodestruction efficiency were found to be in good agreement with the experimental values (R2 = 0.9810, Adjusted R2 = 0.9643). The results of the optimization predicted by the model showed that the maximum decolorization efficiency (>98%) was achieved at the optimum conditions of the reaction time 10 min, initial dye concentration 10 mg/l, initial peroxydisulfate concentration 1.5 mmol/l and distance of UV lamp from the solution 6 cm. The figure-of-merit electrical energy per order (EEo) was employed to estimate the electrical energy consumption and related treatment costs.

Optimization and Modeling of Photooxidative Process for the Degradation of Reactive Red223

2020 ◽  
Vol 42 (1) ◽  
pp. 42-42
Author(s):  
Abdul Rauf Shah Abdul Rauf Shah ◽  
Hajira Tahir and Tahira Yasmeen Hajira Tahir and Tahira Yasmeen
Keyword(s):  
Figure Of Merit ◽  
Irradiation Time ◽  
Electrical Energy ◽  
Order Kinetic ◽  
Operational Parameters ◽  
Contour Plots ◽  
Pseudo Second Order ◽  
Electrical Energy Per Order ◽  
The Cost ◽  
Central Composite

The optimization of the photooxidative process was carried out with the application of Response Surface Methodology (RSM) to degrade Reactive Red 223 (RR223) dye. Operational parameters of U.V/H2O2 process such as irradiation time, initial [dye], initial [H2O2] and distance between U.V lamp and the solution were optimized with Central Composite Design (CCD). Correlation coefficient value of the CCD was obtained to be 79 %, showing the correctness of the model and the successful utilization of CCD in getting desired levels of the factors of the process. Moreover, the optimum points were located with the graphical surface and contour plots. At the optimal conditions, the photooxidative removal of the color and COD were observed to be 68%, 81%, respectively. Furthermore, the pseudo-second order kinetic was guiding the removal of the dye in the process. Subsequently, the electrical energy consumption was estimated in term of the merit electrical energy per order (EEO). The figure of merit of the process was found to be 252 kWhm−3 order−1. The cost of the treatment was also calculated to be US$ 25/m3.

scholarly journals A Field Pilot Study on Treating Groundwater Contaminated with Sulfolane Using UV/H2O2

Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1200 ◽  
Author(s):  
Linlong Yu ◽  
Sobhan Iranmanesh ◽  
Ian Keir ◽  
Gopal Achari
Keyword(s):  
Water Flow ◽  
Cost Model ◽  
Electrical Energy ◽  
Pilot Scale ◽  
Process Efficiency ◽  
Contaminated Groundwater ◽  
Operational Parameters ◽  
Flow Rates ◽  
Electrical Energy Per Order ◽  
H2o2 System

Sulfolane is an emerging contaminant in the groundwater and soil nearby gas plants, which has attracted much attention from many researchers and regulatory agencies in the past ten years. In this paper, a field pilot-scale ultraviolet (UV)/hydrogen peroxide (H2O2) system was investigated for treating sulfolane contaminated groundwater. Different groundwater, as well as different operational parameters such as influent sulfolane concentration, H2O2 dosage, and water flow rates, were studied. The results showed that a pilot-scale UV/H2O2 system can successfully treat sulfolane contaminated groundwater in the field, although the presence of iron and other groundwater limited the process efficiency. The lowest electrical energy per order of reduction for treating sulfolane in groundwater by using the pilot-scale UV/H2O2 system was 1.4 kWh m−3 order−1. The investigated sulfolane initial concentrations and the water flow rates did not impact the sulfolane degradation. The enhancement of sulfolane degradation in an open reservoir by adding ozone was not observed in this study. Furthermore, an operational cost model was formulated to optimize the dosage of H2O2, and a stepwise procedure was developed to determine the power necessary of the UV unit.

Optimization of Linoleic Acid Monoepoxidation Condition from Malaysian Jatropha curcas Using Central Composite Design (CCD)

2015 ◽  
Vol 754-755 ◽  
pp. 1107-1112
Author(s):  
Rozaini Abdullah ◽  
Jumat Salimon ◽  
Anis Atikah Ahmad
Keyword(s):  
Linoleic Acid ◽  
Reaction Time ◽  
Experimental Design ◽  
Central Composite Design ◽  
Reaction Temperature ◽  
Jatropha Curcas ◽  
Catalyst Loading ◽  
Time Saving ◽  
Independent Variable ◽  
Central Composite

The aim of this study was to optimize the monoepoxidation process of linoleic acid obtained from Malaysian Jatropha curcas oil using central composite design (CCD). There were four independent variable factors had been studied which involved reaction temperature (X1), reaction time (X2), catalyst loading (X3) and H2O2 concentration (X4). Thirty experiments were carried out based on the experimental design responses obtained. The results showed that the optimum condition was obtained at catalyst loading of 0.11% (w/w) methyltrioxorhernium (VII) (MTO), H2O2 mole of 99%, reaction temperature of 58.41oC for 5 hours. The central composite design was proven to be simpler method, time saving and required less samples compared to the conventional method.

Application of the central composite design for condition optimization for semi-aerobic landfill leachate treatment using electrochemical oxidation

2010 ◽  
Vol 61 (5) ◽  
pp. 1257-1266 ◽  
Author(s):  
Soraya Mohajeri ◽  
Hamidi Abdul Aziz ◽  
Mohamed Hasnain Isa ◽  
Mohammad Ali Zahed ◽  
Mohammed J. K. Bashir ◽  
...  
Keyword(s):  
Reaction Time ◽  
Central Composite Design ◽  
Electrochemical Oxidation ◽  
Current Density ◽  
Landfill Leachate ◽  
Electrolyte Concentration ◽  
Process Conditions ◽  
Leachate Treatment ◽  
Condition Optimization ◽  
Central Composite

In the present study, Electrochemical Oxidation was used to remove COD and color from semi-aerobic landfill leachate collected from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. Experiments were conducted in a batch laboratory-scale system in the presence of NaCl as electrolyte and aluminum electrodes. Central composite design (CCD) under Response surface methodology (RSM) was applied to optimize the electrochemical oxidation process conditions using chemical oxygen demand (COD) and color removals as responses, and the electrolyte concentrations, current density and reaction time as control factors. Analysis of variance (ANOVA) showed good coefficient of determination (R2) values of >0.98, thus ensuring satisfactory fitting of the second-order regression model with the experimental data. In un-optimized condition, maximum removals for COD (48.77%) and color (58.21%) were achieved at current density 80 mA/cm2, electrolyte concentration 3,000 mg/L and reaction time 240 min. While after optimization at current density 75 mA/cm2, electrolyte concentration 2,000 mg/L and reaction time 218 min a maximum of 49.33 and 59.24% removals were observed for COD and color respectively.

scholarly journals Application of Electrocoagulation for the Removal of Color from Institutional Wastewater: Analysis with Response Surface Methodology

2021 ◽  
Vol 9 (2) ◽  
pp. 470-479
Keyword(s):  
Response Surface Methodology ◽  
Reaction Time ◽  
Response Surface ◽  
The Other ◽  
Quadratic Model ◽  
Operational Parameters ◽  
Electrode Combination ◽  
Electrocoagulation Process ◽  
Percentage Removal ◽  
Central Composite

The removal percentage of color from institutional wastewater was studied using an electrocoagulation process with different electrode combination at the anode and cathode. This was done by considering operational parameters such as pH at (3, 6 and 9), current at (0.03A, 0.06A and 0.09A) and reaction time at (20, 40 and 60 minutes). When electrode combined in the form of Al-Al (anode-Cathode/Cathode-Anode) and Fe-Fe (anode-Cathode/Cathode-Anode) the percentage removal of color was up to 95.50% and 97.24% respectively. On the other hand around 98.03% and 91.95% of color was removed when Al-Fe (Anode-Cathode) and Fe-Al (Anode-Cathode) combined at pH 9 and 60 minutes of reaction time respectively. Central composite design from response surface methodology was used up to analysis the statistical and mathematical data based on experimental results such as the model was significant for all electrode combinations. Similarly a quadratic model was used for further study of operational effects on the removal (%) of color from institutional wastewater. The value of coefficient of the determination (R2) also indicated the model was a good fit as well as optimization was done by Response Surface Methodology.

scholarly journals Optimization of chlorite and talc flotation using experimental design methodology: Case study of the MCG plant, Morocco

2020 ◽  
Vol 120 (12) ◽  
Author(s):  
K. Boujounoui ◽  
A. Abidi ◽  
A. Baçaoui ◽  
K. El Amari ◽  
A. Yaacoubi
Keyword(s):  
Response Surface Methodology ◽  
Central Composite Design ◽  
Response Surface ◽  
Desirability Functions ◽  
Sulphide Ore ◽  
Experimental Values ◽  
Experimental Design Methodology ◽  
Central Composite ◽  
Good Agreement

SYNOPSIS Response surface methodology (RSM), central composite design (CCD), and desirability functions were used for modelling and optimization of the operating factors in chlorite and talc (collectively termed 'mica') flotation. The influence of pulp pH, cyanide (NaCN) consumption, and particle size was studied with the aim of optimizing ssilicate flotation while minimizing recoveries of galena, chalcopyrite, and sphalerite. Flotation tests were carried out on a representative sample of a complex sulphide ore from Draa Sfar mine (Morocco). The model predictions for the flotation of each of the minerals concerned were found to be in good agreement with experimental values, with R2 values of 0.91, 0.98, 0.99, and 0.90 for mica, galena, chalcopyrite, and sphalerite recoveries, respectively. RSM combined with desirability functions and CCD was successfully applied for the modelling of mica flotation, considering simultaneously the four flotation responses to achieve the maximum recovery of mica and minimal loss of Pb, Cu, and Zn to the flotation concentrate. Keywords: chlorite, talc, flotation, response surface methodology, central composite design, optimization.

scholarly journals MODELING AND OPTIMIZATION FOR PRODUCTION OF STAINLESS STEEL CORROSION INHIBITORS FORMULATED WITH 1,3-DIPHENYL-3-PHENYLSULFANYL-PROPAN-1-ONE: A CLEAN PROCESS CATALYSED BY FLUORAPATITE

2017 ◽  
Vol 19 (4) ◽  
Author(s):  
ABROUKI YOUNES ◽  
ANOUZLA ABDELKADER ◽  
LOUKILI HAYAT ◽  
LOTFI RABIAÂ ◽  
RAYADH AHMED ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Reaction Time ◽  
Central Composite Design ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibitors ◽  
Steel Corrosion ◽  
Environmental Problems ◽  
Ease Of Use ◽  
Modeling And Optimization ◽  
Central Composite

The optimization for process production of stainless steel corrosion inhibitor formulated with 1.3-Diphenyl-3-phenylsulfanyl-propan-1-one was studied using a 2 block central composite design including 3 factors (weight of catalyst, reaction time, and quantity of solvent). This process catalyzed by Fluorapatite coupled with their ease of use and reduced environmental problems makes them attractive alternatives to homogeneous basic reagents.

scholarly journals Central composite design for the optimization of removal of the azo dye, methyl orange, from waste water using fenton reaction

2012 ◽  
Vol 77 (2) ◽  
pp. 235-246 ◽  
Author(s):  
Mahsa Azami ◽  
Morteza Bahram ◽  
Sirous Nouri ◽  
Abdolhosein Naseri
Keyword(s):  
Reaction Time ◽  
Methyl Orange ◽  
Central Composite Design ◽  
Response Surface ◽  
Fenton Reaction ◽  
Dye Degradation ◽  
Polynomial Equation ◽  
Initial Concentration ◽  
Model Response ◽  
Central Composite

In this study the degradation of Methyl Orange, using Fenton reaction was studied and optimized using central composite design as a response surface methodology. The effects of various experimental parameters in this reaction were investigated using central composite design. 28 experiments, with 4 factors and 5 levels for each factor were designed. These factors (or variables) were: initial concentration of Fe (II), initial concentration of H2O2, initial concentration of oxalate and the reaction time. A full-quadratic polynomial equation between the percentage of dye degradation (as a response) and the studied parameters was established. After removing the non-significant variables from the model, response surface method was used to obtain the optimum conditions. The optimum ranges of variables were: 0.25 - 0.35 mM for initial concentration of Fe (II), 5-17 mM for initial concentration of H2O2, 4-9 mM for initial concentration of oxalate, and 50-80 min for the reaction time. Also the results of extra experiments showed that these optimized values can be used for real samples and yield to a high value for the response.

scholarly journals Optimization of the adsorption of a textile dye onto nanoclay using a central composite design

2015 ◽  
Vol 39 ◽  
pp. 734-749 ◽  
Author(s):  
Aydin HASSANI ◽  
Murat KIRANŞAN ◽  
Reza DARVISHI CHESHMEH SOLTANI ◽  
Alireza KHATAEE ◽  
Semra KARACA
Keyword(s):  
Central Composite Design ◽  
Textile Dye ◽  
Central Composite

scholarly journals Paracetamol degradation by photo-activated peroxydisulfate process (UV/PDS): kinetic study and optimization using central composite design

2020 ◽  
Vol 82 (7) ◽  
pp. 1404-1415 ◽  
Author(s):  
Karima Dibene ◽  
Idris Yahiaoui ◽  
Lamia Yahia Cherif ◽  
Salima Aitali ◽  
Abdeltif Amrane ◽  
...  
Keyword(s):  
Reaction Time ◽  
Central Composite Design ◽  
Degradation Rate ◽  
Degradation Efficiency ◽  
Order Kinetic ◽  
Optimal Conditions ◽  
Order Kinetic Model ◽  
Pseudo Second Order ◽  
Central Composite ◽  
Optimal Ph

Abstract In this study, peroxydisulfate (PDS) was successfully activated by UV-irradiation for the degradation of paracetamol (PCT) frequently detected in the environment. Results showed that increasing the initial PDS concentration from 5 to 20 mM promote the removal of PCT from 49.3% to 97.5% after 240 min of reaction time. As the initial PCT concentration increased from 0.066 to 0.132 mM, the degradation efficiency of PCT decreased from 98% to 73% after 240 min of reaction time, while the optimal pH was found to be 6. It is apparent that the degradation rate of PCT was favored by the lamp power regardless of the initial PCT concentration, for 0.132 mM of PCT, the degradation efficiency increased from 73% to 95% when the lamp power increased from 9 to 30 W, respectively. The kinetic of degradation of the PCT was described by a pseudo-second order kinetic model. The model obtained by central composite design led to the following optimal conditions for PCT degradation: 0.132 mM initial PCT concentration, 20 mM PDS dose, pH solution 6 and lamp power 30 W led to the removal of 92% of PCT at 25 °C within 240 min of reaction time.

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