scholarly journals Development of a 3D Printable and Highly Stretchable Ternary Organic-Inorganic Nanocomposite Hydrogel

Author(s):  
Chen Hu ◽  
Malik Salman Haider ◽  
Lukas Hahn ◽  
Mengshi Yang ◽  
Robert Luxenhofer

This work describes the synthesis and detailed characterization of a ternary hybrid hydrogel comprising a thermogelling hydrogel containing laponite clay nanoparticles, in which an additional polymer network is polymerized by free radical polymerization. The precursor hydrogel can be effectively 3D printed and after curing, interesting mechanical properties are obtained.<br>

2021 ◽  
Author(s):  
Chen Hu ◽  
Malik Salman Haider ◽  
Lukas Hahn ◽  
Mengshi Yang ◽  
Robert Luxenhofer

This work describes the synthesis and detailed characterization of a ternary hybrid hydrogel comprising a thermogelling hydrogel containing laponite clay nanoparticles, in which an additional polymer network is polymerized by free radical polymerization. The precursor hydrogel can be effectively 3D printed and after curing, interesting mechanical properties are obtained.<br>


Author(s):  
Chen Hu ◽  
Malik Haider ◽  
Lukas Hahn ◽  
Mengshi Yang ◽  
Robert Luxenhofer

Hydrogels that can be processed with additive manufacturing techniques and concomitantly possess favorable mechanical properties are interesting for many advanced applications. However, the development of novel ink materials with high...


Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1952
Author(s):  
Benedict Rothammer ◽  
Kevin Neusser ◽  
Max Marian ◽  
Marcel Bartz ◽  
Sebastian Krauß ◽  
...  

Diamond-like carbon (DLC) coatings have the potential to reduce implant wear and thus to contribute to avoiding premature failure and increase service life of total knee replacements (TKAs). This two-part study addresses the development of such coatings for ultrahigh molecular weight polyethylene (UHMWPE) tibial inlays as well as cobalt–chromium–molybdenum (CoCr) and titanium (Ti64) alloy femoral components. While a detailed characterization of the tribological behavior is the subject of part II, part I focusses on the deposition of pure (a‑C:H) and tungsten-doped hydrogen-containing amorphous carbon coatings (a‑C:H:W) and the detailed characterization of their chemical, cytological, mechanical and adhesion behavior. The coatings are fabricated by physical vapor deposition (PVD) and display typical DLC morphology and composition, as verified by focused ion beam scanning electron microscopy and Raman spectroscopy. Their roughness is higher than that of the plain substrates. Initial screening with contact angle and surface tension as well as in vitro testing by indirect and direct application indicate favorable cytocompatibility. The DLC coatings feature excellent mechanical properties with a substantial enhancement of indentation hardness and elastic modulus ratios. The adhesion of the coatings as determined in modified scratch tests can be considered as sufficient for the use in TKAs.


Metals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 646 ◽  
Author(s):  
Zehui Hao ◽  
Jinxu Liu ◽  
Jin Cao ◽  
Shukui Li ◽  
Xingwei Liu ◽  
...  

Due to its negligible solubility, it is difficult to obtain a W-30Cu composite with a homogenous microstructure. However, with a selected W skeleton, a homogeneous phase distribution was achieved for a W-30Cu composite in the present study. By detailed characterization of the mechanical performance and microstructure of the W-30Cu composite, as well as the stress distribution state under a loading condition, the effects of microstructure homogeneity on the mechanical properties and failure mechanisms are identified. The mechanisms by which the ductility and strength depend on microstructure homogeneity contain the effects on plastic deformation and stress coordination of the Cu phase network. The dominant factors for the high ductility and strength of W-30Cu composites are proposed.


2005 ◽  
Vol 13 ◽  
pp. 760-760
Author(s):  
Jean-Luc Margot

The first detailed characterization of a near-Earth binary (2000 DP107) provided significant insights into the formation mechanism, orbital evolution, and physical properties of the system. Near-Earth Asteroid (NEA) binaries are tidally evolved with synchronously rotating secondaries, providing constraints on asteroid mechanical properties (tidal Q and rigidity). It is expected that radar observations will permit measurements of orbital precession, with corresponding implications for the distribution of mass within asteroids.


Author(s):  
Peyman Honarmandi ◽  
Hongbin Xu

Abstract Additive manufacturing (AM) is an innovative technology that creates parts by adding small portions of materials layer by layer, which frees designers to create parts that were not possible to manufacture with subtractive manufacturing processes previously. This led to wide-spread popularity of 3D-printing technology. In this technology. fused deposition modeling (FDM) is the most affordable one in the market now. Therefore, it is vital to understand how the print orientation, which can be customized very easily, affects the mechanical properties of the prints to maximize the strength of the product. This paper aims to present the methodology and results of the experimental characterization of the acrylonitrile butadiene styrene (ABS) 3D-printed part. Tensile characterization of ABS was performed to analyze anisotropic nature of 3D-printed parts caused by its unique manufacturing process. Specimens were printed with six different configurations: four raster ([45/−45], [30/−60], [15/−75] and [0/90]) and three build orientations (0 or flat, 45, and 90 degrees with respect to the build plate, all printed in [45/−45] raster orientation). Dogbone tensile specimens were printed and pulled using the tensile test machine. The young’s modulus, yield strength, ultimate strength, strain at failure, breaking strength were found for each configuration. As the build orientation angle increased and the raster orientation goes from [45/−45] to [0/90], mechanical properties decreased steadily except the Young’s modulus. For build orientation, Young’s modulus decreased first then increased as angle increased, and for the raster orientation, there was no statistically significant difference as raster changed from [45/−45] to [0/90]. Overall, [45/−45] flat configuration is the strongest and the most stable configuration.


2014 ◽  
Vol 86 (11) ◽  
pp. 1707-1721 ◽  
Author(s):  
Ecaterina Stela Dragan

Abstract Interpenetrating polymer network (IPN) hydrogels brought distinct benefits compared to single network hydrogels like more widely controllable physical properties, and (frequently) more efficient drug loading/release. However, IPN strategy is not sufficient to design hydrogels with enhanced mechanical properties required for regenerative medicine like replacement of natural cartilage or artificial cornea. Some of the novel techniques promoted last decade for the preparation of IPN hydrogels which fulfill these requirements are discussed in the review. Among them, “double network” strategy had a strong contribution in the development of a large variety of hydrogels with spectacular mechanical properties at water content up to 90 %. Using cryogelation in tandem with IPN strategy led to composite cryogels with high mechanical properties and high performances in separation processes of ionic species. Highly stretchable and extremely tough hydrogels have been obtained by combining a covalently cross-linked synthetic network with an ionically cross-linked alginate network. IPN hydrogels with tailored mesh size have been also reported.


2021 ◽  
Author(s):  
Ching Hang Bob Yung ◽  
Lung Fung Tse ◽  
Wing Fung Edmond Yau ◽  
Sze Yi Mak

The long-established application of rapid prototyping in additive manufacturing (AM) has inspired a revolution in the medical industry into a new era, in which the clinical-driven development of the customized medical device is enabled. This transformation could only be sustainable if clinical concerns could be well addressed. In this work, we propose a workflow that addresses critical clinical concerns such as translation from medical needs to product innovation, anatomical conformation and execution, and validation. This method has demonstrated outstanding advantages over the traditional manufacturing approach in terms of form, function, precision, and clinical flexibility. We further propose a protocol for the validation of biocompatibility, material, and mechanical properties. Finally, we lay out a roadmap for AM-driven customized medical device innovation based on our experiences in Hong Kong, addressing problems of certification, qualification, characterization of three dimensional (3D) printed implants according to medical demands.


Sign in / Sign up

Export Citation Format

Share Document